Butene catalytic cracking to ethylene and propylene on mesoporous ZSM-5 by desilication

Mesopore ZSM-5 was prepared by alkali treatment of parent ZSM-5 zeolite and applied for butene catalytic cracking. The zeolite was treated in the NaOH solutions with different concentrations at 85 °C. XRD showed that the intrinsic MFI structure of ZSM-5 zeolite was preserved and corresponding crystallinity remained unchangeableness when ZSM-5 was treated with low concentration NaOH solutions. However, excessive NaOH led to the destruction of zeolite structure. The BET surface area increased obviously after desilication, and the N₂ adsorption/desorption curves indicated a number of mesopores generation. The experiment of butene catalytic cracking was carried out in a fixed-bed to investigate the influence of mesopores. The results showed that catalytic performances can be greatly improved through introducing the mesopores into parent ZSM-5 by alkali treatment. Highest yield of ethylene plus propylene were obtained when the treated concentration of NaOH solution is 0.1–0.2 M.     

Highly Active Syndiospecific Living Polymerization of Higher 1‐Alkene with ansa‐Fluorenylamidodimethyltitanium Complex

1‐Hexene polymerization was conducted by [t‐BuNSiMe₂(3,6‐t‐Bu₂Flu)]TiMe₂ ( 1 ) using trialkylaluminum‐free modified methylaluminoxane (dMMAO) as a cocatalyst in toluene. The system produced living syndiotactic poly(1‐hexene) with high turnover frequency of propagation (TOF, 98 s⁻¹) at 0 °C. The propagation rate was increased linearly against the 1‐hexene concentration, which indicates that the first‐order dependence of the propagation rate on monomer concentration. Polymerizations of 1‐octene, 1‐decene and 1‐dodecene were also conducted for investigating the effect of chain length of 1‐alkene on propagation rate by means of the livingness of this system. The propagation rate decreased according to the chain length until 1‐decene but almost unchanged in longer 1‐alkene: TOF, 1‐octene (62 s⁻¹)>1‐decene (32 s⁻¹) ≈ 1‐dodecene (31 s⁻¹).

     

具有非线性记忆项的耗散波动方程的整体吸引子

LetΩRn be a bounded domain with a smooth boundary.We consider the longtime dynamics of a class of damped wave equations with a nonlinear memory term utt+αut-△u-∫0t 0μ(t-s)|u(s)| βu(s)ds + g(u)=f.Based on a time-uniform priori estimate method,the existence of the compact global attractor is proved for this model in the phase space H10(Ω)×L2(Ω).     

Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy

Three novel scandium-containing heteropolytungstates[Sc₃(H₂O)₃NO₃(PW₉O₃₄)₂]^10-(1a),[Sc₈(H₂O)₂(GeW₉O₃₄)₂(GeW₆O₂₆)₂]^12-(2a) and[Sc₁₁(W₆O₁₀)₂(OH)₂(H₂O)₁₆(BiW₉O₃₃)₆]^27-(3a) were synthesized by reactions of Sc^III ions with trilacunary Keggin precursors,[A-α-XW₉O₃₄]^n-(X=P, Ge, n=9, 10) or[B-α-BiW₉O₃₃]^9-, in NaOAc/HOAc buffer solution under conventional synthetic condition, respectively. All the three compounds were characterized by means of single-crystal X-ray diffraction(XRD), Fourier transform-infrared(FTIR) spectroscopy ultraviolet-visible(UV-Vis) spectroscopy, elemental analysis, and thermogravimetric analysis. The aqueous solution stability of the sandwich polyanion[Sc₃(H₂O)₃NO₃(PW₉O₃₄)₂]^10- was also verified by electrospray ionization mass spectrometry(ESI-MS) due to its good solubility in water.     

The expression patterns of vascular endothelial growth factor and thrombospondin 2 after corneal alkali burn

The aim of the investigation was to explore the expression patterns of VEGF and TSP2 after corneal alkali burn in vivo. After the model of corneal alkali burn was established in mice, the expression levels of VEGF and TSP2 were determined by immunohistochemistry (IHC), RT-PCR, image analysis and statistical evaluation. Compared with control group, the expression level of VEGF increased significantly at 6h after alkali burn and reached its maximum at 12h. Then, it increased again till the second peak appeared at 96h and 192h. The VEGF-positive reaction mainly gathered in the stroma of cornea. On the other hand, the expression of TSP2 enhanced at 3h and attained two peaks at 6h and 96h, respectively, with the process of wound healing. TSP2 was expressed mainly in the base of epithelial layer. The expression patterns of VEGF and TSP2 reflect the complicated interaction with many factors including promoted and inhibited vascularization in vivo. Moreover, it might provide a novel method for controlling vascular hyperplasia in future clinical work according to the data of VEGF and TSP2.     

生物激波管及动物耐受性的实验研究

在冲击伤研究中,必须针对两种试验方式分别对致伤机理、耐受性和机体瞬时动力学响应等进行研究。只有这样才能得到近真实的研究结果。文中介绍了能够模拟爆炸波波形因素和满足动物冲击伤实验研究物理参数要求的BST-Ⅰ型生物激波管。它是国内第一台用于生物实验的激波管。文中有应用该管开口和端板的两种实验方式,选用51只成年雄性杂种狗作耐受性实验观察。对实验结果作了分析。     

自由基在高速投射物压力波致伤机制中的作用

已发现高速投射物（ＨｉｇｈＶｅｌｏｃｉｔｙＰｒｏｊｅｃｔｉｌｅ，ＨＶＰ）压力波可致培养的内皮细胞等损伤。但到目前为止，压力波引起细胞损伤的机理还不清楚。旨在用压力波于体外致伤培养肝细胞，并用自由基清除剂ＳＯＤ处理受损细胞，以观察自由基在ＨＶＰ压力波致伤机制中的作用。试验结果表明ＨＶＰ压力波可引起培养肝细胞明显损伤，压力波损伤培养细胞的机制与其引起细胞自由基反应等有一定关系，预防性地给予自由基清除剂ＳＯＤ可在一定程度上减轻压力波所引起的细胞损伤。     

崇文门站施工允许地表沉降及三维有限元模拟分析

建设中的北京地铁五号线崇文门站下穿既有地铁一号线区间隧道,为保证既有地下铁道正常运营和地下结构的安全,需严格控制新建车站施工引起的地层位移。结合新建车站暗挖施工及既有线地铁的实际情况,分析和计算穿越既有隧道施工地表允许沉降值。为了控制地表沉降,确保施工安全,拟采用小刚度管棚或大刚度顶管作超前预支护,用3D-S igm a三维有限元软件进行施工效应的计算模拟,掌握大管棚和顶管预支护洞室的力学效应,预测车站施工引起既有隧道的沉降量。最后分析比较两种预支护的支护效果,为选择合理的预支护方案提供参考。