空气冲击波重复作用的生物效应

实验动物为体重15.2～42.4kg的绵羊和山羊共46只。用TNT化爆和BST-Ⅰ型激波管致伤,伤后6小时进行形态学检查,以确定重复冲击的效应。结果表明多次重复冲击可使损伤显示累加效应,表现为损伤的发生率和程度增加,损伤阈值降低。     

Electrochemical Behavior of Calcein and the Interaction Between Calcein and DNA

The electrochemical behavior of calcein (CA) has been investigated by using a conductive carbon black paste electrode (CCBPE) as working electrode. It exhibits a single well‐defined redox peak in phosphate buffered saline in the range of pH 5.5–8.0, which attributes to the irreversible oxidation with 2 electrons and 2 protons participation. Under the optimized analytical conditions, the proposed linear sweep voltammetry (LSV) method allows the determination of CA in a linear concentration range of 0.64–9.60 µM, with a limit of detection of 0.32 µM. Further, the interaction between CA and DNA were studied by voltammetric and spectrometric methods. Both studies have shown that CA can bind to DNA by the intercalation binding mode. Under the present experimental condition, the binding constant β of CA and dsDNA is 1.10×10⁷. Meanwhile, in the loop‐mediated isothermal amplification (LAMP) reaction mixture there is obvious interaction between CA and dsDNA, resulting in a nonignorable decrease of the indicating sensitivity.     

Green synthesis by diethylene glycol based solution process and characterization of SnS nanoparticles

Uniform near‐spherical SnS nanoparticles were prepared by a hydrazine hydrate‐assisted diethylene glycol solution synthesis based on the reaction of tin dichloride (SnCl₂·2H₂O) with thioacetamide (H₃CCSNH₂). The as‐prepared SnS nanoparticles were characterized by XRD, FETEM, EDS, XPS and UV‐vis‐NIR spectrophotometer. The results showed that the SnS nanoparticles had orthorhombic crystal structure, good stoichiometry and indirect bandgap of ∼1.1 eV. The nanoparticle size could be controlled by changing injection temperature. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Formation of single-crystalline TiO2 nanomaterials with controlled phase composition and morphology and the application in dye-sensitized solar cell

Single-crystalline TiO₂ nanomaterials with controlled phase composition and morphology were synthesized by hydrothermal transformation of H-titanate nanotubes under different pH. Rutile rectangle nanorods with two four-side tapered tips were produced at pH of 0, whereas anatase nanoparticles with mainly of rhombic shape were obtained at pH from 2 to 7 and their average particle size increased with pH. The transformation mechanisms at different pH were discussed. The single-crystalline anatase nanoparticles obtained at pH of 2 had ca. 12 nm in average particle size, and the powder possessed as large as 112 m²/g specific surface areas; the conversion efficiency of the dye-sensitized solar cell based on the nanoparticles was increased by over 40% as compared with that of the cell based on P25.     

碳离子肿瘤治疗中弹核碎裂反应测量系统的研制

为了评估弹核碎裂反应在碳离子肿瘤治疗中产生的影响,中国科学院近代物理研究所建立了一套探测器系统用来测量相关反应产物。这套探测系统包括起始探测器、水靶系统、带电粒子鉴别系统和中子测量系统。利用中国科学院近代物理研究所250 MeV/u 12C6+ 束打50 mm水靶的实验在束测试了这套系统的性能。实验结果表明,通过ΔE-E 和TOF-ΔE 两种粒子鉴别方法这套探测系统清楚地区分了H,He,Li,Be,B和C 等元素。通过计算不同Z 值带电碎片的微分截面得到了这些带电碎片(本工作给出元素H 和He)相应的角分布。这套探测系统中的带电粒子测量系统性能达到了设计的预期目标。For estimating the influence of the projectile breakup reaction on carbon ion tumour therapy, a detector system was built by IMP(Institute of Modern Physics), Chinese Academy of Sciences(CAS), and used to detect the results of the reaction. The system is composed of start detector, water target system, charged fragments detector system and neutron detector system. The performance of the detector system was tested in the experiment of 5 cm thick water target bombarded by 250 MeV/u carbon beam. The results reveal that the charged fragments, such as elements H, He, Li, Be, B and C, were identified clearly by ΔE-E and ΔE-TOF techniques. The angular distributions of some charged fragments were obtained by calculating the charge-changing cross-sections of the fragments(e.g. elements H and He isotopes in our work). The test results prove that the charged fragment detector system achieves the design aim.     

强地震荷载作用下含断层岩质边坡稳定性分析

基于岩石材料的弹塑性损伤理论,引入两个独立的损伤变量分别控制岩石的拉压行为,通过对地震荷载作用下边坡场地响应的有限无数值模拟,总结含裂隙的岩质边坡发生局部损伤软化、破坏的区域的扩展、演化过程和规律.结合对某大型水电坝坝址左岸的岩质边坡在强地震动载荷作用下(百年一遇、超越概率2%)发生破坏的数值模拟,揭示这类边坡滑坡的机理,并根据模拟的结果,对整治边坡破坏提出参考依据.     

Chaotic secure communication based on strong tracking filtering

A scheme for implementing secure communication based on chaotic maps and strong tracking filter (STF) is presented, and a modified STF algorithm with message estimation is developed for the special requirement of chaotic secure communication. At the emitter, the message symbol is modulated by chaotic mapping and is output through a nonlinear function. At the receiver, the driving signal is received and the message symbol is recovered dynamically by the STF with estimation of message symbol. Simulation results of Holmes map demonstrate that when message symbols are binary codes, STF can effectively recover the codes of the message from the noisy chaotic signals. Compared with the extended Kalman filter (EKF), STF has a lower bit error rate.     

Catalytic Synthesis of a Monodisperse Olefin Block Copolymer Using a Living Polymerization System

Polymerization of norbornene has been conducted with [t‐BuNSiMe₂(3,6‐t‐Bu₂Flu)]TiMe₂ ( 1 ) in toluene at 20 °C using modified methylaluminoxane that contained 0.4 mol‐% of triisobutylaluminium (TIBA) (dMMAO(0.4)) or 1.8 mol‐% of TIBA (dMMAO(1.8)). The 1 ‐dMMAO(0.4) catalytic system undergoes a living polymerization of norbornene. The catalysis of norbornene and propylene with the 1 ‐dMMAO(1.8) catalytic system gives markedly different results because of differences in transfer times of the polymers from Ti to TIBA. The successive addition of norbornene and propylene before the complete consumption of the norbornene in the 1 ‐dMMAO(1.8) system gives monodisperse PNB‐block‐poly(propylene‐ran‐norbornene)‐block‐PP terminated with a Ti–PP bond, which is exchanged with TIBA. Hence the repeated addition of the same amount of norbornene and propylene realizes the catalytic synthesis of monodisperse block copolymer in this system.

     

一种新的非线性系统传感器漂移性能退化实时监测方法

随着传感器使用时间的增加,其测量值会发生漂移,且漂移程度会随时间的增加而增大.针对非线性系统中的传感器漂移性退化现象,基于改进的粒子滤波算法,提出了传感器漂移性能退化实时监测方法.该方法通过实时估计漂移量来实现对系统状态的估计,能够检测并跟踪动态系统中传感器性能退化过程,为系统安全运行提供保障.基于三容水箱系统的仿真验证了该方法的有效性.