利用重正化群方法推导湍流二阶矩封闭模型

Rubinstein和Barton在他们的原始工作中,利用Yakhot-Orszag湍流重正化群方法对雷诺 应力输运方程中的速度-压力梯度项和各向同性回归过程进行了模拟. 文中分析了 其在理论推导过程中存在的数学物理上不自洽的问题及计算错误,并且利用重正化 群方法重新系统地对雷诺应力输运方程进行了模拟,计算得到的湍流常数理论值和 经验值相接近.     

吲哚与亚胺的Friedel-Crafts反应的研究进展

由于吲哚类化合物具有许多生物特性等优点,在众多天然产物和相应的具有生物活性的化合物中起重要的骨架构筑作用,其合成方法的研究格外令人注目.近年来,关于吲哚与亚胺在催化剂作用下发生Friedel-Crafts反应来制备3-取代吲哚甲胺衍生物的报道剧增.对近年来吲哚与亚胺Friedel-Crafts反应的研究情况进行了综述.     

偏心起爆对战斗部装药能量分配增益的影响

为研究不同方式的偏心起爆对炸药装药能量分配及增益的影响,建立了偏心起爆战斗部的计算模型,通过局部装填比这一变量,给出了偏心起爆战斗部破片的初速计算公式。采用数值模拟与试验验证结合的方法,对六分位条件下不同偏心起爆方式的破片速度增益和能量增益进行了对比,得出以中心起爆为基准,分别以邻位双线、连位三线、间位双线、偏心单线方式起爆,定向方位内破片的速度增益依次增大;邻位双线起爆时,目标方向破片速度增益达25.47%,定向区域破片动能占总能量的24.57%,能量增益超过40%。     

高精度有限差分法模拟Kelvin-Helmholtz不稳定性

 WENO有限差分格式有较高的分辨精度,适合复杂流场的计算,在国际上被广泛采用。本文利用WENO有限差分格式求解2维守恒型欧拉方程,实现了对无粘流体中Kelvin-Helmholtz不稳定性的数值模拟。速度剪切方向采用周期边界条件;扰动增长方向采用嵌边出流边界条件,一个不稳定波长分布64个网格。数值模拟给出的扰动幅值线性增长率与线性稳定性分析给出的结果很好符合,显示了该格式的有效性和精度。数值模拟给出了清晰的密度等值线,表明该方法还具有较好的界面变形捕捉能力。     

CrCl3·6H2O/Hydrogenated Bis‐Schiff Base as a New Efficient Catalyst System for Synthesis of Bis(indoly) Methane

CrCl₃·6H₂O/hydrogenated bis‐Schiff base is found to be an effective catalyst system for synthesis of bis(indoly) methane via electrophilic addition reaction of indoles with aldehydes using acetonitrile as the solvent. The yields of isolated products are from good to excellent.     

A Novel Fluorescent Probe Based on Spiro[chromeno[2,3-c]pyrazole-4,1′-[2]benzofuran]-3′-one for Detecting Copper(II) ions in Aqueous Solution

Russian Journal of Organic Chemistry - A novel fluorescent probe, DHMP {7-(dibutylamino)-3-methyl-1H,3′H-spiro[chromeno[2,3-c]pyrazole-4,1′-[2]benzofuran]-3′-one} was designed and...     

Rapid detection of trace Cu2+ using an l‐cysteine based interdigitated electrode sensor integrated with AC electrokinetic enrichment

Copper is an indispensable trace element for human health. Too much or too little intake of copper ion (Cu²⁺) can lead to its own adverse health conditions. Therefore, detection of Cu²⁺ is always of vital importance. In this work, a simple sensor was developed for rapid detection of trace Cu²⁺ in water, in which L‐cysteine (Cys) as a molecular probe was self‐assembled on a gold interdigital electrode to form a monolayer for specific capture of Cu²⁺. The interfacial capacitance of interdigital electrode was detected to indicate the target adsorption level under an AC signal working as the excitation to induce directed movement and enrichment of Cu²⁺ to the electrode surface. This sensor reached a limit of detection of 4.14 fM and a satisfactory selectivity against eight other ions (Zn²⁺, Hg²⁺, Pb²⁺, Cd²⁺, Mg²⁺, Fe²⁺, As³⁺, and As⁵⁺). Testing of spiked tap water was also performed, demonstrating the sensor's usability. This sensor as well as the detection method shows a great application potential in fields such as environmental monitoring and medical diagnosis.     

Fuzzy space periodic symmetries for polyynes and their cyano-compounds

In our previous papers on the molecular fuzzy symmetry, we analyzed the basic characterization in connection with the fuzzy point group symmetry. In this paper, polyynes and their cyano-derivatives are chosen as a prototype of linear molecules to probe the one-dimensional fuzzy space group of parallel translation. It is notable that the space group is an infinite group whereas the point group is a finite group. For the fuzzy point group, we focus on considering the fuzzy characterization introduced due to the difference of atomic types in the monomer through point symmetry transformation in the beginning; and then we consider the difference between the infinity of space group and the finite size of real molecules. The difference between the point group and the space group lies in the translation symmetry transformation. This is the theme of this work. Starting with a simple case, we will only analyze the one-dimensional translation transformation and space fuzzy inversion symmetry transformation in this paper. The theory of the space group is often used in solid state physics; and some of its conclusions will be referred to. More complicated fuzzy space groups will be discussed in our future papers.     

三氟甲磺酸镱催化吲哚与硝基烯Friedel-Crafts反应的研究

用三氟甲磺酸镱和配体共同催化吲哚与β-硝基烯的Friedel-Crafts反应,从而发展了一条简捷新颖地合成天然产物中广泛存在的3-取代吲哚衍生物的方法.该催化剂有反应条件温和、操作简单和价格较低等优点.