Synthesis and Biological Activity of Novel 2,3-Dihydro-2-phenylsulfonylhydrazono-3-(2′,3′,4′,6′-tetra-O-acetyl-β-D-glucopyranosyl)thiazoles

A series of novel 2,3-dihydro-2-phenylsulfonylhydrazono-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl) thiazoles were designed and synthesized via the reaction of thiosemicarbazide with chloroaldehyde.Their chemical structures were characterized by 1H and 13C NMR spectroscopy and elemental analysis.The bioassay results indicate that some of these compounds exhibit moderate fungicidal and herbicidal activities.     

氨基酸合成方法研究(Ⅸ)——固液相转移催化下1,4-二乙酰基-2,5-哌嗪二酮与醛的缩合反应

研究了在固液相转移催化条件下,1,4-二乙酰基-2,5-哌嗪二酮(2)与醛(3a-n)的缩合反应。合成了14种(Z)-1-乙酰基-3-亚芳基(亚烷基)-2,5-哌嗪二酮(4a-n),并讨论了产物的构型。     

Some theorems for determining the definiteness and changeability of sign of functions and the application to the conditional stability of the motion of the axis of a sleeping top

This paper gives some theorems for determining the definiteness and changeability of sign of functions as well as the application to the axis of a sleeping top. The necessary and sufficient condition of the conditional stability of the motion is obtained, which coincides with that of the stability of nutation angle and also with that of the stability of total variables in the equations of motion.     

Synthesis and Herbicidal Activity of Novel 5-Substituted Benzenesulfonylureas

Sulfonylurea herbicides have been widely used because of their low application rates,good crop selectivities and low mammalian toxicities.However,some sulfonylureas might persist unfavourably in the environment with residual problems.In order to look for ecologically safer and environmentally benign sulfonylureas,and on keeping the pyrimidine ring being monosubstituted,15 novel C5-monosubstituted benzenesulfonylurea compounds were synthesized.The structures of all the compounds synthesized were confirmed by elemental analysis and 1H NMR.Preliminary herbicidal activities of these new sulfonylurea compounds were determined by ALS screening(in vitro)and pot bioassay experiments(in vivo).The herbicidal results show that some novel sulfonylureas are comparable to commercial Foramsulfuron and Monosulfuron.     

基于小波变换的爆破地震信号能量分析法的应用研究

根据爆破地震信号具有持时短、突变快等特点,结合工程爆破地震监测资料,利用小波包良好的时频局部化性质对爆破地震信号的能量分布特征进行了分析,研究了爆破地震信号的能量在传播过程中的变化规律,得到了爆破地震信号不同频带上的能量分布。根据爆破地震信号不同频带的特征频率与受控建筑物自振频率之间的关系,确定爆破地震对建筑物的影响。并用工程实例说明了该方法比用单一强度因子作为爆破地震的安全判据更加有效。     

偏微分方程在图像去噪中的应用

本文介绍用于图像去噪的偏微分模型、方法的发展历程．从理论上分析了线性模型、简单非线性模型、复杂非线性模型、多步处理模型出现的背景和优缺点，并从空域和频域上对偏微分方程模型的去噪原理进行了分析．最后，指出了偏微分方程去噪与小波去噪结合的途径，据此对偏微分方程未来的发展方向进行了展望．     

YBa_2Cu_3O_7_薄膜热激发磁通蠕动研究

本文选择两块零电阻温度分别为82K 和71K 超导性能不同的簿膜徉品, 同步进行了电阻在外滋场中展宽的测量, 并用Palstra 所提出的Arrhenius 定律研究两样品热激活能的差别。实验发现样品热激活能随磁场增加线性下降. 由测量结果推出的不可逆线仍有B * -(l -T*/T_c_)**3/2形式. 关键词：     

Synthesis and Insecticidal Activities of Novel Analogues of Chlorantraniliprole Containing Nitro Group

Twelve novel analogues of chlorantraniliprole containing nitro group were synthesized,and their structures were characterized by 1H NMR and high-resolution mass spectrometry(HRMS).Their evaluated insecticidal activities against oriental armyworm(Mythimna separata) indicate that the nitro-containing analogues showed favorable insecticidal activities,while the activity of compounds 5g at 0.25mg/L was 40%,but still lower than chlorantraniliprole.     

静电纺丝原理研究进展

纳米纤维具有直径小、比表面积大以及易于实现表面功能化的优点,受到广泛的关注.在众多制备纳米纤维的方法中,静电纺丝是一种高效的技术,其中同轴共纺技术由于能制备芯-壳(core-shell)结构的纳米纤维,也越来越引起人们的关注.本文介绍了基于电流体动力学的静电纺丝原理,讨论了静电纺丝相关原理研究进展,包括Taylor锥与喷射,纳米纤维的弯曲非稳定性,高聚物溶液/熔融体流动非稳定性,两相流流型及其转换,高聚物两相流流型及其转换,非牛顿流体流动非稳定性以及两种非牛顿流体分层流动等,最后指出了尚待解决的一些问题.     

Quantitative Studies on Structure－Activity Relationships （QSAR） of Cytokinin－Active Phenyl Urea Derivatives（PUD）

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