Implementation of nonlocal quantum swap operation on two entangled pairs

We propose a scheme for the implementation of nonlocal quantum swap operation on two spatially separated entangled pairs and we show that the operation can swap two qubits of these entangled pairs.We discuss the resources of the entangled qubits and classical communication bits required for the optimal implementation of the nonlocal quantum swap operation.We also put forward a scheme for probabilistic implementation of nonlocal swap operation via a nonmaximally entangled quantum channel.The probability of a successful nonlocal swap operation is obtained by introducing a collective unitary transformation.     

Palladium-catalyzed alkenylation of fluoro-substituted furans via C-H activation to form tetrasubstituted furans

A palladium-catalyzed oxidative Heck reaction of fluoro-substituted furans with alkenes was developed to afford tetrasubstituted furans in moderate to good yields.     

一类新的k-次增生型变分包含解的存在性及其具有混合误差项的Ishikawa迭代逼近

在实自反Banach空间中,引入和研究了一类新的k-次增生型变分包含问题,证明了这类变分包含解的存在性、唯一性及其具有混合误差项的Ishikawa迭代程序的收敛性.本文结果本质地改进、发展和统一了张石生和曾六川等人的一系列相关结果.     

One-pot copper-catalyzed synthesis of 2-substituted benzothiazoles from 2-iodoanilines,benzyl chlorides and elemental sulfur

An efficient one-pot three-component reaction of 2-iodoanilines, benzyl chlorides and elemental sulfur to form 2-substituted benzothiazoles in satisfactory yields (up to 98%) has been described. The reaction tolerated a wide range of functional groups on the aromatic ring. And heterocycle methylene chlorides substrates were also found to be compatible.     

Iridium-catalyzed annulation between 1,2-diarylethanone and 3-aminopropanol toward site-specific 2,3-diaryl pyridines

An iridium-catalyzed annulation between 1,2-diarylethanone and 3-aminopropanol was developed, leading to site specific 2,3-diarylpyridines in moderate yields. 3-Aminopropanol served as both a four-atom component and solvent during this procedure, releasing water as a clean by-product. The reaction may proceed with sequential imine formation, alcohol oxidation and intramolecular cyclization by Knoevenagel reaction.     

Suppression of the Charge Density Wave State in Two-Dimensional 1T-TiSe2 by Atmospheric Oxidation

Two-dimensional (2D) metallic transition-metal dichalcogenides (TMDCs), such as 1T-TiSe₂, have recently emerged as unique platforms for exploring their exciting properties of superconductivity and the charge density wave (CDW). 2D 1T-TiSe₂ undergoes rapid oxidation under ambient conditions, significantly affecting its CDW phase-transition behavior. We comprehensively investigate the oxidation process of 2D TiSe₂ by tracking the evolution of the chemical composition and atomic structure with various microscopic and spectroscopic techniques and reveal its unique selenium-assisting oxidation mechanism. Our findings facilitate a better understanding of the chemistry of ultrathin TMDCs crystals, introduce an effective method to passivate their surfaces with capping layers, and thus open a way to further explore the functionality of these materials toward devices.