WHOLLY-AROMATIC THERMOTROPIC LIQUID CRYSTALLINE POLYMER AND ITS BLOCK COPOLYMER

A wholly-aromatic thermotropic liquid crystalline polymer (WATLCP) composed ofp-hydroxybenzoic acid (HBA), 4,4'-dihydroxy bisphenyl (BP), terephthalic acid (TPA),m-phthalic acid (MPA) was synthesized. It was symbolized by BP-LCP. Using a simi-lar method, a new copolymer BP-PSF was prepared. BP-PSF has a semi-flexible chainpolysulfone and a rigid-rod chain like BP-LCP. By FT-IR, polarizing microscope and DSCtechnique, the structures and properties of BP-LCP and BP-PSF were studied.     

荧光法研究Ge-132对牛血清白蛋白Maillard反应的抑制作用

人体内氨基酸及蛋白质的非酶糖化反应(Maillard反应)与糖尿病及其并发症的关系已经引起广泛注意[1].有机锗化合物β-羧乙基锗倍半氧化物(Ge-132)具有预防糖尿病及调节糖代谢的作用[2].     

苎麻叶中绿原酸的分光光度法测定

探讨了采用分光光度法测定苎麻叶中绿原酸的含量的方法。12.5%的醋酸用量为0.1mL,7%尿素2.0mL,0.5%亚硝酸钠0.25mL,3min后加入5%氢氧化钠0.5mL,绿原酸与试剂形成鲜红色络合物,通过在510nm处测定溶液的吸光度确定绿原酸的含量。绿原酸浓度在0.01~0.12g/L范围内与吸光度值有良好的线性关系,回收率为95%~107%,相对标准偏差(RSD)为2.4%。该方法简便、快速。     

Photo-and Electro-luminescence of the New Ternary Europium(III) Complex

In recent years, the interest in developing luminescent lanthanide complexes has been greatly stimulated by their potential use in electroluminescent displays1. Europium complexes appear most attractive in view of the high photoluminescent efficiency and the high monochromatic red light that are widely exploited in full-color displays2. It has been approved that the second ligand plays an important role in europium complexes, the synergistic complexation of the second ligand can not only lead …     

Cloning and Expression of Rat Liver S-Adenosylmethionine Synthetase

Introduction S Adenosylmethionine(SAM)isabiologicallyac tivecompoundwidelydistributedinthebodytissues andfluids.Itisinvolvedinanumberofbiochemical reactions.Asamethylgroupdonor,itisimportantin transmethylationreactions,whichcontributestothe synthesesofsuc…     

固体磷酸催化剂的活性相

研究了固体磷酸催化剂活性与其自由磷酸聚合态及磷酸硅晶型的关系，指出高活性磷酸催化剂应具备的条件，即自由磷酸中应为正磷酸和焦磷酸的混合物，结合态磷应具有“Ｃ”晶型。     

司帕沙星软膏的制备与质量控制

为研制司帕沙星软膏，建立其含量测定方法。用差示紫外分光光度法在306nm外测定司帕沙星的含量。平均回收率为99．98％，RSD为0．72％，线性范围15．62－40．14μg/ml。该法简便、准确、快捷。     

不饱和类锗烯H2C=GeNaBr的密度泛函理论研究

应用密度泛函理论DFT方法,在B3LYP/6-311G(d,p)水平上研究了不饱和类锗烯H2C=GeNaBr的结构及异构化反应.结果表明,不饱和类锗烯H2C=GeNaBr有3种平衡构型,其中非平面的p-配合物型构型能量最低,是其存在的主要构型.并对平衡构型间异构化反应的过渡态进行了计算,求得了转化势垒,预言了最稳定构型的振动频率和红外强度.     

Theoretical prediction on vibrational spectra of [Ar…Ar-H]~+

As a special substance between isolated molecules and condensed phase, clusters have drawn more and more attention by theoreticians and experimentalists. The protonated rare gas cluster is one kind of simplest clusters, which can be looked on as the simplest solution composed of the simplest solute, proton, and the simplest solvent, rare gas. The study on such a system can help us to know more about the complex condensed matter. However, the information for the molecular properties of protonat…