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51.
文章简要地叙述了法国著名物理学家路易·奈尔的成长历程与生平业绩,其中包括他在磁学领域的诸多重大贡献、成功地创立和领导了一个富有成就的科学研究团体以及他堪称为一位出色的科技开发企业家的风范. 相似文献
52.
Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis.
The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate
activities for ethylene oligomerization.
Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714.
This article was submitted by the authors in English. 相似文献
53.
C. Foces‐Foces M. Lpez‐Rodríguez C. Prez 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(2):o95-o97
The title compound, C12H21NO3, crystallizes in two polymorphic forms, viz. the tetragonal form described here and the monoclinic form described previously [Foces‐Foces, López‐Rodríguez, Pérez, Martín & Pérez‐Hernández (2007). Cryst. Growth Des. 7 , 905–911]. The differences in the conformations of the hydroxymethyl and methylaminocarbonyl substituents have important consequences in the hydrogen‐bond interaction motifs and, therefore, in the packing arrangements. These forms are concomitant polymorphs with melting points differing by 3 K. 相似文献
54.
55.
Guobao Zhang Jianming Zhang Shenguo Wang Deyan Shen 《Journal of Polymer Science.Polymer Physics》2003,41(1):23-30
Blends of amorphous poly(DL‐lactide) (DL‐PLA) and crystalline poly(L‐lactide) (PLLA) with poly(methyl methacrylate) (PMMA) were prepared by both solution/precipitation and solution‐casting film methods. The miscibility, crystallization behavior, and component interaction of these blends were examined by differential scanning calorimetry. Only one glass‐transition temperature (Tg) was found in the DL‐PLA/PMMA solution/precipitation blends, indicating miscibility in this system. Two isolated Tg's appeared in the DL‐PLA/PMMA solution‐casting film blends, suggesting two segregated phases in the blend system, but evidence showed that two components were partially miscible. In the PLLA/PMMA blend, the crystallization of PLLA was greatly restricted by amorphous PMMA. Once the thermal history of the blend was destroyed, PLLA and PMMA were miscible. The Tg composition relationship for both DL‐PLA/PMMA and PLLA/PMMA miscible systems obeyed the Gordon–Taylor equation. Experiment results indicated that there is no more favorable trend of DL‐PLA to form miscible blends with PMMA than PLLA when PLLA is in the amorphous state. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 23–30, 2003 相似文献
56.
Chin‐Ping Yang Ruei‐Shin Chen Kuei‐Hung Chen 《Journal of polymer science. Part A, Polymer chemistry》2003,41(7):922-938
To investigate the position and amount of the CF3 group affecting the coloration of polyimides (PIs), we prepared 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]hexafluoropropane ( 2 ) with four CF3 groups with 2‐chloro‐5‐nitrobenzotrifluoride and 2,2‐bis(4‐hydroxyphenol)hexafluoropropane. A series of soluble and light‐colored fluorinated PIs ( 5 ) were synthesized from 2 and various aromatic dianhydrides ( 3a – 3f ). 5a – 5f had inherent viscosities ranging from 0.80 to 1.19 dL/g and were soluble in amide polar solvents and even in less polar solvents. The glass‐transition temperatures of 5 were 221–265 °C, and the 10% weight‐loss temperatures were above 493 °C. Their films had cutoff wavelengths between 343 and 390 nm, b* values (a yellowness index) ranging from 5 to 41, dielectric constants of 2.68–3.01 (1 MHz), and moisture absorptions of 0.03–0.29 wt %. In a comparison of the PI series 6 – 8 based on 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane, 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]propane, and 2,2‐bis[4‐(4‐aminophenoxy)phenyl]propane, we found that the CF3 group close to the imide group was more effective in lowering the color; this means that CF3 of 5 , 7 , and 8f was more effective than that of 6c . The color intensity of the four PI series was lowered in the following order: 5 > 7 > 6 > 8 . The PI 5f , synthesized from diamine 2 and 4,4′‐hexafluoroisopropylidenediphthalic anhydride, had six CF3 groups in a repeated segment, so it exhibited the lightest color among the four series. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 922–938, 2003 相似文献
57.
本文提出的MMD算法用于提高模型区别错误信息和正确信息的能力.利用该算法在对模型的参数进行重估计时.涉及到复杂的目标函数的梯度运算.击运用矩阵运算使得梯度运算变得简单明了,因此本文给出了MMD算法下的HMM参数重估计的矩阵表示形式并给出了证明. 相似文献
58.
Zhang Meirong 《数学年刊B辑(英文版)》1989,10(3):416-425
This paper considers the following question: Given an Anosov endomorphism f on T~m, whether f is topologically conjugate to some hyperbolic total endomorphism? It is well known that the answer for Anosov diffeomorphisms and expanding endomorphisms is affirmative. Hwever for the remainder Anosov endomorphisms, a quite different answer is obtained in this paper, i. e., for generic Anosov endomorphisms, they are not topologically conjugate to any hyperbolic toral endomorphism. 相似文献
59.
激光晶体YAG中Er3+的辐射跃迁 总被引:2,自引:0,他引:2
本文讨论和分析了激光晶体YAG中Er3+离子的激光上能级的4S3/2、4I11/2和4I13/2辐射跃迁的有关因素。 相似文献
60.
ZhenFengZHANG 《数学学报(英文版)》2005,21(1):155-168
In this paper, we extend a classical result of Hua to arithmetic progressions with large moduli. The result implies the Linnik Theorem on the least prime in an arithmetic progression. 相似文献