Solvothermal synthesis, cubic structure and multicolor upconversion emission of ultrasmall monodisperse lanthanide-doped BaYF5 nanocrystals

Lanthanide (Ln³⁺) doped BaYF₅ (Ln=Yb³⁺, Er³⁺, Tm³⁺) nanocrystals (NCs) with a mean size of approximately 10 nm are synthesized by a solvothermal method using oleic acid as a stabilizing agent at 210 °C. The size of BaYF₅ NCs can be controlled by simply tuning the reaction parameters such as reaction temperature, reaction time and the molar ratio of F⁻/Y³⁺. The detailed structure investigation reveals that the as-synthesized BaYF₅ NCs are in the cubic structure with space group Fm3¯m instead of the reported tetragonal structure. Ln³⁺ cations occupy crystal lattice positions with lower point symmetry, which may lead to high upconversion efficiency under the excitation of a 980 nm diode laser. By adjusting the dopant concentrations of Yb³⁺, Er³⁺ and Tm³⁺, intense near-infrared, blue, yellow and white upconversion emissions are readily realized, respectively. The desirable property of the ultrasmall monodisperse NCs makes it the promising material for the applications in miniaturized solid-state light sources, multicolor three-dimensional display devices and fluorescent labels for biomedicine imaging.     

Hidden itinerant-spin phase in heavily overdoped La(2-x)Sr(x)CuO4 superconductors revealed by dilute Fe doping: a combined neutron scattering and angle-resolved photoemission study

We demonstrated experimentally a direct way to probe a hidden propensity to the formation of a spin-density wave in a nonmagnetic metal with strong Fermi surface nesting. Substituting Fe for a tiny amount of Cu (1%) induced an incommensurate magnetic order below 20 K in heavily overdoped La(2-x)Sr(x)CuO(4). Elastic neutron scattering suggested that this order cannot be ascribed to the localized spins on Cu or doped Fe. Angle-resolved photoemission revealed a strong Fermi surface nesting inherent in the pristine La(2-x)Sr(x)CuO(4) that likely drives this order. Our finding presents the first example of the long-sought "itinerant-spin extreme" of cuprates, where the spins of itinerant doped holes define the magnetic ordering ground state; it complements the current picture of cuprate spin physics that highlights the predominant role of localized spins at lower dopings.     

电场极化方向对自由空间电场测量的影响

介绍了自主研制的脉冲电场原始波形测量系统的模块组成与基本工作原理。针对在未知被测电场方向及复杂的电场环境下垂直干扰电场对自由空间电场测量产生的影响,通过建立自由空间电场测量系统前端的简化模型,对不同尺寸天线与屏蔽盒进行仿真计算。仿真计算结果与理论分析基本一致,结果表明:干扰电场响应信号与待测电场响应信号相差2个数量级以上,干扰电场的影响可忽略不计。     

Asymptotic solution for the El Nio time delay sea-air oscillator model

A sea-air oscillator model is studied using the time delay theory.The aim is to find an asymptotic solving method for the El Nio -southern oscillation (ENSO) model.Employing the perturbed method,an asymptotic solution of the corresponding problem is obtained.Thus we can obtain the prognoses of the sea surface temperature (SST) anomaly and the related physical quantities.     

High efficiency top-emitting white organic light-emitting devices with a (metal/organic)2 cathode

White top-emitting organic light-emitting devices (TEOLEDs) were fabricated on a glass substrate with metal/organic multilayer of (Ag/Alq₃)₂ (Alq₃ is tris-(8-hydroxyquinoline) aluminum) as cathode. White TEOLEDs with high efficiency were obtained due to the microcavity effects. And the (Ag/Alq₃)₂ cathode, which adjusted the optical characteristics of the devices, played an important role. In addition, Alq₃–Ag–Alq₃ multilayer could work as a buffer layer, which would simplify the process of encapsulation for devices. We also calculated the electroluminescence spectrum of devices encapsulated with Al₂O₃ (150 nm) and Al₂O₃(75 nm)/ZrO₂(75 nm). And the results indicated that the CIE coordinates is almost the same between with and without encapsulating.     

Disturbed solution of the El Ni?no-southern oscillation sea–air delayed oscillator

A class of delayed oscillators of El Ni?o-southern oscillation (ENSO) models is considered. Using the delayed theory, the perturbed theory and other methods, the asymptotic expansions of the solutions for ENSO models are obtained and the asymptotic behaviour of solution of corresponding problem is studied.     

基于盲解卷积的水声信号恢复技术

信号在环境复杂多途严重的水声波导中传输后,接收到的信号时间长度被拉长,信号是失真的。在许多实际应用中,常常希望从已失真的接收信号中把原始信号波形恢复出来。本文利用盲解卷积技术对水声信号恢复进行研究。理论推演表明,在垂直阵条件下用人造的格林函数可成功地代替水声信道真实的格林函数,可以把非线性关系化解为线性关系,从而推导出依靠基阵记录下的信息去确定声源宽带信号原始波形和环境传播特征的公式和步骤。声场数值计算对6种海底类型进行,恢复后的宽带信号与原始信号的归一化相关系数均大于0.945,对硬海底多途严重的情况,收效特别明显,证明该方法的有效性。在青岛海试中恢复后信号的相关系数平均值为0.933,在青岛海试中利用这种解卷积技术去恢复信号是成功的。     

一类厄尔尼诺时滞海-气振子摄动解

研究了一类厄尔尼诺-南方涛动(ENSO)的时滞振子耦合系统. 利用时滞理论, 摄动等方法求出了ENSO模型解的渐近式,并讨论了相应问题的渐近性态. 关键词： 非线性 摄动 ENSO模型     

一类奇摄动薄板弯曲问题的匹配渐近解

研究了一类薄板弯曲问题. 对四阶奇摄动边值问题, 引入伸长变量, 构造边界附近的内层解, 然后与外部解匹配. 最后用合成展开式理论, 得到了原问题的的渐近解. 关键词： 薄板弯曲 挠度 渐近解     

扰动Nizhnik-Novikov-Veselov系统分形孤子渐近解

文章研究了一类扰动Nizhnik-Novikov-Veselov非线性系统, 利用特殊的渐近方法得到了相应系统分形孤子渐近解. 关键词： 孤子 渐近解 扰动