首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   107677篇
  免费   17490篇
  国内免费   10914篇
化学   73246篇
晶体学   1092篇
力学   6989篇
综合类   579篇
数学   12753篇
物理学   41422篇
  2024年   383篇
  2023年   2163篇
  2022年   3678篇
  2021年   3890篇
  2020年   4252篇
  2019年   4057篇
  2018年   3593篇
  2017年   3295篇
  2016年   5035篇
  2015年   4958篇
  2014年   5936篇
  2013年   7544篇
  2012年   9470篇
  2011年   9621篇
  2010年   6446篇
  2009年   6228篇
  2008年   6747篇
  2007年   6134篇
  2006年   5679篇
  2005年   4672篇
  2004年   3637篇
  2003年   2962篇
  2002年   2702篇
  2001年   2245篇
  2000年   2154篇
  1999年   2272篇
  1998年   1990篇
  1997年   1917篇
  1996年   1939篇
  1995年   1636篇
  1994年   1421篇
  1993年   1183篇
  1992年   1097篇
  1991年   911篇
  1990年   803篇
  1989年   619篇
  1988年   530篇
  1987年   429篇
  1986年   392篇
  1985年   350篇
  1984年   252篇
  1983年   179篇
  1982年   144篇
  1981年   104篇
  1980年   82篇
  1979年   49篇
  1978年   32篇
  1977年   44篇
  1976年   37篇
  1973年   32篇
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
31.
The existence, multiplicity and infinite solvability of positive solutions are established for some two-point boundary value problems of one-dimensional p-Laplacian. In this paper, by multiplicity we mean the existence of m solutions, where m is an arbitrary natural number.  相似文献   
32.
物理模型教学与创新能力的培养   总被引:1,自引:0,他引:1  
现代教学以能力培养为重点.学生获得研究问题、探索问题的能力是十分重要的,物理模型的教学过程对培养学生研究问题、探索问题、发展创造思维、培养辩证唯物主义思想方法都极为有利,因此,必须重视物理模型教学.  相似文献   
33.
Effects of ion impinging on the microstructure and field electron emission properties of screen-printed carbon nanotube films were investigated. We observed that the plasma treatment modified the microstructure of CNTs along with the remarkable increase of emission site density. With the prolongation of ion impinging time, the emission current falls down first, and then rises up to higher than that of the untreated films. It is proposed that the change of emission characteristics is due to the different emission mechanisms. After the treatment, electrons are emitted predominantly from the nano-nodes on the tube wall instead from the nanotube tips.  相似文献   
34.
The development of the poly(3‐hydroxybutyrate) (PHB) morphology in the presence of already existent poly(vinylidene fluoride) (PVDF) spherulites was studied by two‐stage solidification with two separate crystallization temperatures. PVDF formed irregular dendrites at lower temperatures and regular, banded spherulites at elevated temperatures. The transition temperature of the spherulitic morphology from dendrites to regular, banded spherulites increased with increasing PVDF content. A remarkable amount of PHB was included in the PVDF dendrites, whereas PHB was rejected into the remaining melt from the banded spherulites. When PVDF crystallized as banded spherulites, PHB could consequently crystallize only around them, if at all. In contrast, PHB crystallized with a common growth front, starting from a defined site in the interfibrillar regions of volume‐filling PVDF dendrites. It formed by itself dendritic spherulites that included a large number of PVDF spherulites. For blends with a PHB content of more than 80 wt %, for which the PVDF dendrites were not volume‐filling, PHB first formed regular spherulites. Their growth started from outside the PVDF dendrites but could later interpenetrate them, and this made their own morphology dendritic. These PHB spherulites melted stepwise because the lamellae inside the PVDF dendrites melted at a lower temperature than those from outside. This reflected the regularity of the two fractions of the lamellae because that of those inside the dendrites of PVDF was controlled by the intraspherulitic order of PVDF, whereas that from outside was only controlled by the temperature and the melt composition. The described morphologies developed without mutual nucleating efficiency of the components. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 873–882, 2003  相似文献   
35.
A new family of photonucleases, naphthalimide-thiazoles was synthesized and evaluated. These compounds intercalated into DNA efficiently and damaged DNA photochemically at concentrations as low as 5 μM. Mechanistic experiment suggests that a novel naphthalimide-thiazole radical produced via an excited triple state might be involved in the DNA photodamage. Different activity may arise from the impact of substituents at 2-phenyl ring of thiazole on the electron population of excited triple state according to AM1 semi-empirical calculation.  相似文献   
36.
New radiative lifetime measurements based on time-resolved laser-induced fluorescence techniques are reported for 18 even-parity levels belonging to the 4f5d26p and 4f 25d 2 configurations of Ce I and 6 even-parity levels belonging to the 5d26s, 4f5d6p, and 4f6s6p configurations of Ce II. Free neutral and singly ionized cerium atoms were produced by laser ablation. The Ce I and Ce II levels range in energy from 26 545 to 29 102 cm-1, and 42 573 to 48 152 cm-1, respectively. Received 25 September 2002 Published online 4 March 2003  相似文献   
37.
A two-step swelling procedure was adopted to synthesize mono-dispersed and highly cross-linked poly (St-divinylbenzene) particles with PSt micro-spheres (1.80 μm in diameter). The PSt micro-spheres were prepared by a dispersion polymerization method and used as seeds. The effects of monomer concentration, ratio of ethanol to water, swelling reagents, crosslinking reagents, swelling temperature and agitation speed on particle size were investigated in detail. The morphologies and size distributions of these micro-spheres were examined by SEM and particle size analysis (PSA). The T g of the micro-spheres was measured by DSC. The results indicate that the particles (6.20 μm in diameter) exhibit excellent mono dispersed property and high crosslinking degree when the concentration of the swelling reagent was 25%, the concentration of the crosslinking reagents was 23%, the swelling temperature was 30°C and the stirring speed was 150 r/min. __________ Translated from Chinese Journal of Applied Chemistry, 2007, 24(11): 1289–1294  相似文献   
38.
A finite-deformation theory is developed to study the mechanics of thin buckled films on compliant substrates. Perturbation analysis is performed for this highly nonlinear system to obtain the analytical solution. The results agree well with experiments and finite element analysis in wavelength and amplitude. In particular, it is found that the wavelength depends on the strain. Based on the accurate wavelength and amplitude, the membrane and peak strains in thin films, and stretchability and compressibility of the system are also obtained analytically.  相似文献   
39.
稀疏过程在破产问题中的应用   总被引:5,自引:0,他引:5  
本讨论一类人寿保险的风险过程,其中保单到达服从齐次Poisson过程。而描述退保及索赔发生的计数过程分别为这一过程的q-稀疏与p-稀疏.对此模型给出其破产概率的具体上界,并与其它一类风险模型进行比较.  相似文献   
40.
The title compound, [Cd(SeCN)2(pyCN)2], adopts an extended one‐dimensional chain structure in which the neighboring cadmium atoms are bridged by two selenocyanate ions. The central cadmium atom has a distorted octahedral geometry defined by two isonicotinonitrile and four selenocyanate ions in a 4N2Se fashion. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号