Study of low-molecular weight organic acids in maize roots under the stress of cadmium using capillary zone electrophoresis

An indirect CE method was developed for the study of low-molecular weight organic acids (LMWOAs) in maize under the stress of cadmium. The influences of indirect reagents (phthalate, salicylic acid, and benzoic acid), coion concentration, and pH were studied. A buffer composed of 15 mmol/L benzoate and 0.2 mmol/L CTAB (pH 5.7) was used in the organic acid determination. The detection limit ranged between 0.5 and 6 micromol/L. The RSD (n = 14) of the method was found to be in the range of 0.11-0.49% for migration time and 1.25-4.72% for peak area. In the maize roots, obvious increases of LMWOAs were observed when the plants were under the stress of cadmium and/or organic acids. The recovery of standard organic acids added in real samples ranged from 85 to 116%.     

基于直角网格法的单个和阵列布置下柔性水翼绕流数值模拟

研究柔性水翼在不可压缩流体中的水动力特性,对于船舵和减摇鳍等海洋结构物的设计和性能优化具有重要意义.本文将自主开发的径向基函数虚拟网格法求解器扩展到模拟绕单个或多个柔性水翼的不可压缩流动问题.数值模型基于虚拟网格有限差分法考虑浸入边界对流场的影响,引入紧支径向基函数(compact supported radial basis function,CSRBF)以物面Lagrangian质点追踪复杂的柔性动边界.基于该方法,首先模拟了均匀流中主动拍动的柔性水翼,升阻力系数良好的网格收敛性结果验证了本文方法的精度和可靠性.并研究了柔性水翼在不同振荡频率下的水动力特性,阐述了柔性水翼的推力生成机制.然后模拟了绕阵列布置柔性水翼的流动现象,研究了不同间距和不同振荡频率下水翼表面的升阻力系数变化规律和尾涡特性,观察到紧密布置的柔性水翼在高频振荡下推力系数存在显著的放大效应,同时推力为零时的临界频率提前.     

基于有源Fabry-Perot腔的激光脉冲延时自外差研究

对注入有源Fabry-Perot腔内的单纵模脉冲进行了延时理论分析, 计算了Fabry-Perot腔内增益, 并对脉冲输出进行了数值模拟, 结果表明当脉冲能量衰减到一定值时, 新增抽运粒子数提供的增益可以补偿腔内损耗, 延时脉冲的输出可以达到稳态. 然后利用激光二极管侧面抽运Nd: YAG激光器做为Fabry-Perot腔, 对外部入射的单纵模脉冲光进行了延时, 得到了延时时间2 μups、脉冲数量140个的实验结果. 最后利用有源Fabry-Perot腔对参考光进行延时, 声光移频器对信号光产生频移, 进行了外差实验, 实验结果与移频器的设置值相符, 误差在4%以内.     

A green and efficient access to awl nitriles via an electrochemicalanodic oxidation

The nitrile functionality is a key building block in synthetic chemistry, and has wide applications in pharmaceuticals. However, traditional methodologies for the synthesis of nitriles are limited to harsh reaction conditions. Herein, we report a new and efficient access to aryl nitriles by an electrochemical synthesis. Compared with the conventional synthetic methods, this electrochemical synthesis is more environmentally friendly and easier to handle.     

Enantioseparation of Tropic Acid and Its Esters by CEKC Using Sulfated β-Cyclodextrin as a Chiral Selector

Capillary electrokinetic chromatography was successfully applied to the enantioseparation of tropic acid and its four alkyl esters (methyl, ethyl, propyl and butyl), with the same chiral center, Separation was with sulfated β-cyclodextrin (4%, m/v) containing 20 mM phosphate buffer at pH 3.0 as background electrolyte at 20 °C. The results showed that, besides hydrogen-bonding interactions between these compounds with sulfated β-CD, for tropic acid and its methyl ester the steric hindrance effect was also an important factor. However, for the other esters (ethyl, propyl and butyl), the hydrophobicity effect was higher.     

用于太阳向量磁场和视向速度场测量的双折射滤光器

本文阐述了用于太阳磁场测量的一种新的双折射滤光器,它是一种宽视场的单色器,可同时接收许多信号用于实时观测,当应用于望远镜时不会引入附加偏振。 滤光器有两个透过带,一为FeIλ5324,半宽0.15,另一个为H_βλ4861,半宽0.12。透过带的调节范围为±1.2,透过率约为0.06,晶体尺寸为37×37mm²,分辨率约为5″,对望远镜这个分辨率相当于约0″74,工作温度为42℃,恒温精度约为±0.°001C。此滤光器特有三组宽视场电光调制器,可用作分析向量磁场和视向速度场。     

Simultaneous separation of organomercury species by nonaqueous capillary electrophoresis using methanol containing acetic acid and imidazole

A simple and rapid nonaqueous capillary electrophoresis method for simultaneous separation of four kinds of mercury species, namely inorganic mercury, methylmercury, ethylmercury, and phenylmercury, is reported. The effective mobilities of organomercury in aqueous and nonaqueous electrolytes were compared. Imidazole was confirmed not only as a co-ion for the separation but also as an online complexing reagent for mercury species. The optimum conditions for separation were achieved by using methanol solvent containing 0.15 M acetic acid and 15 mM imidazole as electrolyte. The sensitive detection of mercury species was accomplished at 191 nm.     

Ti基化学镀Ni-P和Ni-P-Cg镀层晶化动力学

利用化学镀技术在Ti基体材料表面制备了Ni-P合金镀层和Ni-P-Cg复合镀层。利用SEM、XRD和EDS等分析了镀层的晶化过程,用差热分析仪研究了Ni-P合金镀层和复合镀层的晶化动力学,运用Ozawa、Freeman-Carroll、Achar和Coats-Redfern方法对非等温动力学数据进行了分析和比较。结果发现,复合镀层的特征温度T_m和晶化激活能E均高于Ni-P合金镀层,而热焓值｜ΔH｜却低于Ni-P镀层;计算出Ni-P合金镀层和Ni-P-Cg复合镀层晶化激活能分别为308.9 kJ·mol^-1和412.99 kJ·mol^-1、指前因子A分别为58.03 s^-1和77.84 s^-1,确定了Ni-P合金镀层和复合镀层晶化动力学方程。     

Cds纳米微粒的聚四氟乙烯多孔膜法制备及其表面修饰

硫化镉;Cds纳米微粒的聚四氟乙烯多孔膜法制备及其表面修饰;纳米粒;多孔膜;表面修饰;聚四氟乙烯     

A green and efficient access to aryl nitriles via an electrochemical anodic oxidation

The nitrile functionality is a key building block in synthetic chemistry, and has wide applications in pharmaceuticals. However, traditional methodologies for the synthesis of nitriles are limited to harsh reaction conditions. Herein, we report a new and efficient access to aryl nitriles by an electrochemical synthesis. Compared with the conventional synthetic methods, this electrochemical synthesis is more environmentally friendly and easier to handle.