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71.
In the conventional scheme of generating strong mechanical squeezing by the joint effect between mechanical parametric amplification and sideband cooling, the resolved sideband condition is required so as to overcome the quantum backaction heating. In the unresolved sideband regime, to suppress the quantum backaction, a χ(2) nonlinear medium is introduced to the cavity. The result shows that the quantum backaction heating effect caused by unwanted counter-rotating term can be completely removed. Hence, the strong mechanical squeezing can be obtained even for the system far from the resolved-sideband regime. 相似文献
72.
Li Zhen Prof. Shuo Tong Prof. Jieping Zhu Prof. Mei-Xiang Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(2):401-405
We report in this article a cascade reaction strategy for the synthesis of complex N-heterocyclic compounds with contiguous and tetrasubstituted stereogenic carbons. Under the sequential catalysis of a chiral binol–Ti complex and BF3, cyclopentanone-derived tertiary enamides undergo an enantioselective enamine addition to ketone carbonyls followed by diastereoselective trapping of the resulting acyliminiums by electron-rich aryl moieties to furnish four- and five-membered ring-fused N-heterocyclic products as the sole diastereomers in high yields with up to 99 % ee. 相似文献
73.
Honghua Zhang Huihong Wang Yi Jiang Fei Cao Weiwei Gao Longqing Zhu Yuhang Yang Xiaodong Wang Yongqiang Wang Jinhong Chen Yiyue Feng Xuemei Deng Yingmei Lu Xiaoling Hu Xiangxiang Li Juan Zhang Tao Shi Prof. Zhen Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(72):17289-17317
Sulfur-containing scaffold, as a ubiquitous structural motif, has been frequently used in natural products, bioactive chemicals and pharmaceuticals, particularly C−S/N−S bonds are indispensable in many biological important compounds and pharmaceuticals. Development of mild and general methods for C−S/N−S bonds formation has great significance in modern research. Iodine and its derivatives have been recognized as inexpensive, environmentally benign and easy-handled catalysts or reagents to promote the construction of C−S/N−S bonds under mild reaction conditions, with good regioselectivities and broad substrate scope. Especially based on this, several new strategies, such as oxidation relay strategy, have been greatly developed and accelerated the advancement of this field. This review focuses on recent advances in iodine and its derivatives promoted hybridized C−S/N−S bonds formation. The features and mechanisms of corresponding reactions are summarized and the results of some cases are compared with those of previous reports. In addition, the future of this domain is discussed. 相似文献
74.
75.
We study the dissipative quantum phase transition(QPT)in a biased Tavis–Cummings model consisting of an ensemble of two-level systems(TLSs)interacting with a cavity mode,where the TLSs are pumped by a drive field.In our proposal,we use a dissipative TLS ensemble and an active cavity with effective gain.In the weak drive-field limit,the QPT can occur under the combined actions of the loss and gain of the system.Owing to the active cavity,the QPT behavior can be much differentiated even for a finite strength of the drive field on the TLS ensemble.Also,we propose to implement our scheme based on the dissipative nitrogen-vacancy(NV)centers coupled to an active optical cavity made from the gainmedium-doped silica.Furthermore,we show that the QPT can be measured by probing the transmission spectrum of the cavity embedding the ensemble of the NV centers. 相似文献
76.
运用分子动力学方法具体模拟研究单个碳纳米管(CNTs)在加热过程中的结构变化.选择多组不同结构的单壁碳纳米管(SWCNTs)和双壁碳纳米管(DWCNTs)作为研究对象,加热温度从室温开始到4000 K,压强保持为1 atm.结果表明单壁碳管中手性型结构热稳定性最好,其次是扶手椅型和锯齿型,当手性角相同时,直径大的热稳定性更高;对于双壁碳管,研究表明当双壁中至少之一为手性结构时其热稳定好,而内外壁均为锯齿结构的稳定性最差,该结果进一步支持了有关单壁碳管的结论;还从理论上探索了描述结构热稳定性的方式,并在键层
关键词:
单壁碳纳米管
双壁碳纳米管
分子动力学方法
热稳定性能 相似文献
77.
78.
研究了利用摩擦空穴注入层3,4-乙撑二氧噻吩:聚苯乙烯磺酸(PEDOT:PSS)作为定向层实现聚芴(PFO)薄膜的偏振电致发光,蓝光的色坐标为(0.20,0.21).从聚合物薄膜的紫外可见吸收和光致发光偏振特性,研究了不同定向层摩擦强度、退火温度以及退火时间下PFO薄膜的二向色性,并证明退火温度是决定器件偏振性能的关键因素.当摩擦强度为25 mm退火温度和时间分别为200℃和30 min时,得到较好的偏振性能,器件的电致发光偏振率约为3.
关键词:
偏振发光
摩擦定向
聚合物电致发光
空穴注入层 相似文献
79.
采用金属有机物化学气相沉积(MOCVD)法在蓝宝石(0001)衬底上制备出了Ga2(1-x)In2xO3(x=01—09)薄膜,研究了薄膜的结构、电学和光学特性以及退火处理对薄膜性质的影响.测量结果表明:当In组分x=02时,样品为单斜β-Ga2O3结构;x=05的样品,薄膜呈现非晶结构,退火处理后薄膜结构得到明显的改善
关键词:
金属有机物化学气相沉积
2(1-x)In2xO3薄膜')" href="#">Ga2(1-x)In2xO3薄膜
蓝宝石衬底
退火 相似文献
80.
导体旋转椭球电学量的一种计算方法 总被引:4,自引:4,他引:4
用一种新方法,计算了孤立导体旋转椭球的面电荷密度、电容、电势和电场强度,并得出相应的解析表达式。 相似文献