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991.
Spin gapless semiconductor like Ti2MnAl film as a new candidate for spintronics application 下载免费PDF全文
Wuwei Feng Xiao Fu Caihua Wan Zhonghui Yuan Xiufeng Han Nguyen Van Quang Sunglae Cho 《固体物理学:研究快报》2015,9(11):641-645
A novel Heusler ferrimagnet Ti2MnAl film has been grown on Si(001) substrate using magnetron sputtering. Characteristics of its magnetic and transport properties reveal the spin‐gapless‐semiconductor (SGS) nature of the stoichiometric Ti2MnAl, in agreement with theoretical prediction. The as‐grown SGS‐like Ti2MnAl film demonstrated high Curie temperature, nearly compensated ferrimagnetic properties with small coercivity and low magnetization. It also showed semiconductor‐like behavior at room temperature allowing good compatibility with commercial Si‐based semiconductor. In this regards, Ti2MnAl film is a potential candidate material for spintronics application, especially for the minimization of energy consumption of device. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
992.
由于超短脉冲激光器的谐振腔大都采用多镜折叠的形式,像散已成为影响锁模激光器性能优劣的重要问题.本文提出了一种基于传播圆补偿像散的被动锁模激光器谐振腔设计方法,该方法简单、直观、高效,容易找到补偿像散的最佳位置.理论研究表明,当SESAM位于子午和弧矢传播圆交汇处附近时,SESAM处的子午光斑和弧矢光斑大小几乎相等,像散得到补偿.该谐振腔对外界干扰引起的腔镜振动和热透镜焦距的变化均不敏感,谐振腔的抗干扰性很强.实验研究表明,当SESAM位于子午和弧矢传播圆交汇处附近时,锁模激光器可获得稳定连续的锁模激光脉冲,且激光器的抗干扰性很强.本文的理论研究与实验结果相一致. 相似文献
993.
Lu Xiao Bo Li Fan Xiao Cong Fu Liang Wei Yanfeng Dang Xiu-Qin Dong Chun-Jiang Wang 《Chemical science》2022,13(17):4801
The development of enantioselective annulation reactions using readily available substrates for the construction of structurally and stereochemically diverse heterocycles is a compelling topic in diversity-oriented synthesis. Herein, we report efficient catalytic asymmetric formal 1,3-dipolar (3 + 4) cycloadditions of azomethine ylides with 4-indolyl allylic carbonates for the construction of azepino[3,4,5-cd]-indoles fused with a challenging seven-membered N-heterocycle, a frequently occurring tricyclic indole scaffold in bioactive compounds and pharmaceuticals. Through cooperative Cu/Ir-catalyzed asymmetric allylic alkylation followed by intramolecular Friedel–Crafts reaction, an array of azepino[3,4,5-cd]-indoles were obtained in good yields with excellent diastereo-/enantioselective control. More importantly, the full stereodivergence of this transformation was established via synergistic catalysis followed by acid-promoted epimerization, and up to eight stereoisomers of the cycloadducts bearing three stereogenic centers could be predictably achieved from the same set of starting materials for the first time. Quantum mechanical computations established a plausible mechanism for the synergistic Cu/Ir catalysis to stereodivergently introduce two vicinal stereocenters whose stereochemical information is remotely delivered across the fused azepine ring to control the third chiral center. Epimerization of the last center involves protonation-enabled reversal of the thermodynamically controlled relative configuration.A stereodivergent synthesis of azepino[3,4,5-cd]-indoles bearing three stereogenic centers was established via synergistic dual-metal catalysis followed by acid-promoted epimerization, and up to all eight stereoisomers could be predictably achieved. 相似文献
994.
995.
500—4250eV电子对CO2的散射全截面绝对测量 总被引:2,自引:0,他引:2
对中能电子与二氧化碳分子碰撞的散射全截面测量,给出500-4250eV电子对CO2的绝对散射全截面。对测量结果作了曲线拟合,并与已有的实验和理论结果进行了比较 相似文献
996.
本文采用第一性原理方法,在100 GPa的压力范围内,计算了GeO_2理想晶体和含锗、氧空位点缺陷晶体的光学性质.吸收谱数据表明,压力诱导的三个结构相变对GeO_2晶体的吸收谱均有影响:第一个相变将导致其吸收边蓝移,而第二和第三相变将使得其吸收边红移.锗和氧空位点缺陷的存在将导致GeO_2的吸收边红移,但氧空位点缺陷引起的红移更明显.尽管如此,分析发现,在100 GPa的压力范围内,压力、相变以及空位点缺陷等因素都不会导致GeO_2晶体在可见光区出现光吸收现象(是透明的).波长在532 nm处的折射率数据显示,在GeO_2的四个相区,其折射率均随压力增加而降低;而且,GeO_2的三个结构相变以及锗、氧空位点缺陷都会导致其折射率有所增大.本文预测,GeO_2有成为冲击光学窗口材料的可能. 相似文献
997.
998.
High entanglement generation and high fidelity quantum state transfer in a non-Markovian environment 下载免费PDF全文
This paper analyses a system of two independent qubits off-resonantly coupled to a common non-Markovian reservoir at zero temperature. Compared with the results in Markovian reservoirs, we find that much higher values of entanglement can be obtained for an initially factorized state of the two-qubit system. The maximal value of the entanglement increases as the detuning grows. Moreover, the entanglement induced by non-Markovian environments is more robust against the asymmetrical couplings between the two qubits and the reservoir. Based on this system, we also show that quantum state transfer can be implemented for arbitrary input states with high fidelity in the non-Markovian regime rather than the Markovian case in which only some particular input states can be successfully transferred. 相似文献
999.
利用基于有效介质理论的介孔硅传热机理,提出一个用于分析氧化介孔硅热导率的理论模型,对影响氧化介孔硅有效热导率的因素进行了理论分析,得出用于计算氧化介孔硅有效热导率的计算公式. 采用双槽电化学腐蚀法制备介孔硅,利用微拉曼光谱技术研究了氧化介孔硅热导率随所制备介孔硅孔隙率的变化规律,比较了经不同温度处理的氧化介孔硅的导热性能差异. 孔隙率为60%,73.4%和78.8%的所制备介孔硅经300℃氧化处理后,其热导率值为8.625W/(m·K),3.846W/(m·K)和1.817W/(m·K);孔隙率为73.4
关键词:
理论模型
氧化介孔硅
微拉曼光谱
有效热导率 相似文献
1000.
Elastic behaviour of an edge dislocation near a sharp crack emanating from a semi-elliptical blunt crack 下载免费PDF全文
The interaction between an edge dislocation and a crack
emanating from a semi-elliptic hole is dealt with. Utilizing the
complex variable method, closed form solutions are derived for
complex potentials and stress fields. The stress intensity factor at
the tip of the crack and the image force acting on the edge
dislocation are also calculated. The influence of the morphology of
the blunt crack and the position of the edge dislocation on the
shielding effect to the crack and the image force is examined in
detail. The results indicate that the shielding or anti-shielding
effect to the stress intensity factor increases acutely when the
dislocation approaches the tip of the crack. The effect of the
morphology of the blunt crack on the stress intensity factor of the
crack and the image force is very significant. 相似文献