钢丝软轴是怎样传递扭矩的

 详细分析了钢丝软轴传递扭矩的原理,结果表明: 包轴的套管的协同工作起着至关重要的作用.     

Transition-metal redox evolution and its effect on thermal stability of LiNixCoyMnzO2 based on synchrotron soft X-ray absorption spectroscopy

Based on the synchrotron soft X-ray absorption spectroscopy experiments,the fundamental electronic structures of layered LiNixCoyMnzO2 (NCM) are investigated sy...     

Repairing the Thiol‐Ene Coupling Reaction

Thiol‐ene coupling (TEC) reactions emerged as one of the most useful processes for coupling different molecular units under reaction mild conditions. However, TEC reactions involving weak C? H bonds (allylic and benzylic fragments) are difficult to run and often low yielding. Mechanistic studies demonstrate that hydrogen‐atom transfer processes at allylic and benzylic positions are responsible for the lack of efficiency of the radical‐chain process. These competing reactions cannot be prevented, but reported herein is a method to repair the chain process by running the reaction in the presence of triethylborane and catechol. Under these reaction conditions, a unique repair mechanism leads to an efficient chain reaction, which is demonstrated with a broad range of anomeric O‐allyl sugar derivatives including mono‐, di‐, and tetrasaccharides bearing various functionalities and protecting groups.     

外周天线LHCⅡ的荧光光谱特性

外周天线LHC在光合作用过程中,担负着吸收和传递光能的作用.我们采用扫描成象荧光光谱技术对菠菜中外周天线LHC的荧光光谱特性进行了研究,在514.5nm的激光激励下获取了积分荧光谱,认为从类胡萝卜素分子到叶绿素分子间存在有能量传递.采用高斯组分光谱解析的方法,解析出LHC的荧光发射有七个谱带:656.7、664.6、671.5、677.2、683.5、689.6、695.3nm,各自所占的比例分别为3.0%、13.1%、13.3%、21.1%、13.2%、33.3%、3.0%,其中658.7nm的发射谱是由叶绿素b分子所发射的,其余的发射谱分别是由吸收峰为662、670/671、676、680nm以及吸收大于690nm的叶绿素a分子所发射.3.0%的叶绿素b分子的荧光发射说明在能量平衡过程中绝大部分能量被叶绿素a分子所禁锢,689.6nm处的荧光所占的比例最大,可能与LHC的一种自保护机制有关     

Diffusion of Li ion on graphene: A DFT study

Density functional theory investigations show that the Li⁺ ion is stabilized at the center of hexagonal carbon ring with the distance of 1.84 Å from graphene surface. The potential barrier of Li⁺ ion diffusion on the graphene surface, about 0.32 eV, is much lower than that of Li⁺ ion penetrating the carbon ring which is 10.68 eV. When a vacancy of graphene exists, potential barrier about 10.25 eV for Li⁺ ion penetrating the defect is still high, and the ability of the vacancy to sizing the Li⁺ ion is also observed. Electronic densities of states show that the formation of a localized bond between Li atom and edge carbon of vacancy is the main reason for high potential barrier when Li⁺ ion penetrate a vacancy. While Coulomb repulsion is the control factor for high potential barrier in case of Li⁺ ion penetrating a carbon ring.     

核心天线CP43、CP47的荧光光谱特性

采用快速扫描成象光谱技术对核心天线CP43和CP47的荧光光谱特性进行研究,获取了它们的积分荧光谱,通过积分荧光谱的组分光谱解析,并结合吸收光谱分析认为CP43和CP47具有这样的Chla的光谱特性,CP43:Chla₆₆₀^662.43、Chla₆₆₉^670.23、Chla₆₈₂^684.02,CP47:Chla₆₆₀^664.91、Chla₆₆₉^671.71、Chla₆₈₀^681.35、(Chla_a^e,a代表吸收峰;e代表发射峰);另外长波长组分694.86nm、702.34nm(CP43)、696.02nm(CP47)可能是由吸收>690nm的Chla分子所产生;CP43与CP47相比还存在有Chla₆₇₅^676.32,但是还没有看到CP43具有675nm吸收谱带的报道.对CP43和CP47的荧光光谱分析,认为CP47中的Chla669nm分子团和Chla680nm分子团间的能量传递比CP43中Chla669nm和Chla682nm分子团的能量传递更为有效;β-Car与Chla分子结合状态在CP47中要比CP43中紧密.     

Effect of Eu contents on the structure and properties of BaLa2ZnO5:Eu phosphors

A series of Eu³⁺ doped BaLa₂ZnO₅ was prepared by a Pechini-type sol-gel method. The effect of Eu³⁺ concentration on the structure and the luminescent properties of the samples BaLa_2−xEu_xZnO₅ were investigated by powder X-ray diffraction (XRD) and photoluminescence (PL) spectra. The sample adopts the tetragonal or orthorhombic structure as the Eu³⁺ concentration reaches below 1.2 or over 1.6, respectively. The sample is a mixture of tetragonal and orthorhombic phases as the contents of dopants lie between 1.2 and 1.6. The phosphor offers the strongest red light as content of Eu³⁺ is 0.4. In addition, the crystallization processes of the complex precursors were examined by simultaneous thermogravimetry and differential thermal analysis (TG-DTA), and also the optimal heating temperature was investigated.     

Photoluminescence of double-color-emitting phosphor Ca5(PO4)3Cl:Eu, Mn for near-UV LED

Eu²⁺ activated Ca₅(PO₄)₃Cl blue-emitting phosphors were prepared by the conventional solid state method using CaCl₂ as the chlorine source and H₃BO₃ as flux. The structure and luminescent properties of phosphors depend on the concentrations of Eu²⁺, the amount of CaCl₂ and the usage of the H₃BO₃ flux were investigated systematically. Eu²⁺ and Mn²⁺ Co-doped Ca₅(PO₄)₃Cl with blue and orange double-band emissions were also researched based on the optimal composition and synthesis conditions. The energy transfer between Eu²⁺ and Mn²⁺ was found in the phosphor Ca₅(PO₄)₃Cl:Eu²⁺, Mn²⁺, and the Co-doped phosphor can be efficiently excited by near-UV light, indicating that the phoshor is a potentional candidate for n-UV LED used phosphor.     

氧原子在钨低指数表面及(211)高指数表面上的吸附和振动

 应用原子和表面簇合物相互作用的5参数Morse势方法研究了氧原子在W低指数表面及(211)高指数表面上的吸附和振动. 计算结果表明,低覆盖度下,在W(100)面氧原子吸附在四重洞位,随着覆盖度增加,(100)面发生缺行重构,膺式三重位为稳定吸附位; 在W(110),(111)及(211)面,氧原子均趋向于吸附在膺式三重位. 该计算结果和实验符合得很好.     

价夸克分布与海夸克分布的核效应

提出了一个由轻子-核深度非弹性散射和核Drell-Yan过程的实验数据得到价夸克分布和海夸克分布的核效应函数RvA(x_t)和RsA(x_t)的方法. 由这两个函数可以检验解释核效应的理论模型. 以铁核为例求出了RvFe(x_t)和Rs(Fe)(x_t).