Crystal and Molecular Structure of OMPCTF

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Liquid crystalline hexa-amides and side chain polysiloxanes of azacrown [18]-N6

The hexa-4-dodecyloxybenzoyl derivative 1 of azacrown [18]-N₆ was originally reported to have a 'tubular' mesophase on the basis of its large central ring and 6-fold symmetry. Starting in the mesophase, annealing of 1 under a cover slip results in formation of a new crystalline phase that melts directly to an isotropic liquid at the temperature previously observed for the mesophase to isotropic transition. Thus the phase behaviour of 1 is kinetically controlled. The analogous hexa-3,4-bisdodecyloxybenzoyl derivative 2 of azacrown [18]-N₆ has no kinetic limitations to its phase changes and has an enantiotropic columnar liquid crystalline phase. We have synthesized side chain copolysiloxanes with a (CH₂)₁₁ spacer and 75-84 per cent by weight of the same 4-dodecyloxybenzoyl-[18]-N₆ mesogen. The polysiloxanes also display a liquid crystalline phase.     

HIGH ACCURACY FINITE VOLUME ELEMENT METHOD FOR TWO-POINT BOUNDARY VALUE PROBLEM OF SECOND ORDER ORDINARY DIFFERENTIAL EQUATIONS

1　ＩｎｔｒｏｄｕｃｔｉｏｎＦｉｎｉｔｅｖｏｌｕｍｅｅｌｅｍｅｎｔｍｅｔｈｏｄｏｒＦＶＥＭｕｓｅｓａｖｏｌｕｍｅｉｎｔｅｇｒａｌｆｏｒｍｕｌａｔｉｏｎｏｆｔｈｅｄｉｆ ｆｅｒｅｎｔｉａｌｅｑｕａｔｉｏｎｗｉｔｈａｆｉｎｉｔｅｐａｒｔｉｔｉｏｎｉｎｇｓｅｔｏｆｖｏｌｕｍｅｔｏｄｉｓｃｒｅｔｉｚｅｔｈｅｅｑｕａｔｉｏｎ ,ｔｈｅｎｒｅ ｓｔｒｉｃｔｓｔｈｅａｄｍｉｓｓｉｂｌｅｆｕｎｃｔｉｏｎｓｔｏａｌｉｎｅａｒｆｉｎｉｔｅｅｌｅｍｅｎｔｓｐａｃｅｔｏｄｉｓｃｒｅｔｉｚｅｔｈｅｓｏｌｕｔｉｏｎ ([1 -4 ] ) .…     

High temperature superconducting thin films for microwave filters

YBa₂Cu₃O_7-δ and Tl₂Ba₂CaCu₂O₈ thin films for microwave filters were synthesized by pulsed laser deposition and the two-step thalliation process. Substrate quality requirements and the relation of thin film morphology, microstructure with microwave surface resistance were discussed.     

泛连通图定理和Ore2条件

记Ore2=min{d(y) d(x)|x,y∈V(G),d(x,y)=2}，本得到：若n阶图G的Ore2≥n 1，则G是[5;n]泛连通图。此是比Faudree等人的定理进一步的结果。     

聚乙炔的CH面外振动红外光谱研究

采用从头计算方法，计算了反式和顺式聚乙炔的氢原子在垂直于聚乙炔分子面方向振动的红外光谱，计算表明，Gibson等用红外吸收实验所测得的谱线的确是聚乙炔的CH面外振动产生的谱线，经100℃长时间加热后，顺式聚乙炔变为反式聚炔，但波数为740cm^-1的谱级仍保留5％的强度。     

甲基红染料掺杂的聚乙烯醇薄膜光存储特性的实验研究

用2倍频小型YAG激光(532nm)作为写入光和擦除光,用He-Ne激光器623.8nm线作为读出光,用CCD作为探测器,研究了不同写入光功率下,甲基红/聚乙烯醇(MR/PVA)薄膜光栅生长的动力学过程和不同擦除光功率下,光栅擦除的动力学过程.结合光栅生长曲线的波动现象,对光存储机制进行了新的探讨.实验发现,两写入光和读出光的功率配比为1:1:1时,可获得最大衍射效率,提出读出光对写入过程具有双重作用的物理模型,对此实验结果给出了合理的解释.     

溅射功率对多层膜质量的影响

用磁控溅射技术制备薄膜，用X射线衍射研究在基片和靶间距离固定的情况下不同的溅射功率对薄膜结构的影响。结果表明：过低的溅射功率下淀积的薄膜有畸变的X射线衍射特征峰，特征峰强度小，半峰全宽大。而比较高溅射功率得到的薄膜有比较尖锐的X射线衍射特征峰，强度高和半峰全宽非常窄。研究表明，X射线衍射特征峰强度小和半峰全宽大的薄膜结构疏松，而强度高和半峰全宽非常窄的薄膜结构致密。