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971.
The phase state of dense matter in the intermediate density range (\begin{document}$\sim$\end{document} ![]()
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1-10 times the nuclear saturation density) is both intriguing and unclear and can have important observable effects in the present gravitational wave era of neutron stars. As matter density increases in compact stars, the sound velocity is expected to approach the conformal limit (\begin{document}$c_s/c=1/\sqrt{3}$\end{document} ![]()
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) at high densities and should also fulfill the causality limit (\begin{document}$c_s/c<1$\end{document} ![]()
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). However, its detailed behavior remains a prominent topic of debate. It was suggested that the sound velocity of dense matter could be an important indicator of a deconfinement phase transition, where a particular shape might be expected for its density dependence. In this work, we explore the general properties of the sound velocity and the adiabatic index of dense matter in hybrid stars as well as in neutron stars and quark stars. Various conditions are employed for the hadron-quark phase transition with varying interface tension. We find that the expected behavior of the sound velocity can also be achieved by the nonperturbative properties of the quark phase, in addition to a deconfinement phase transition. Moreover, it leads to a more compact star with a similar mass. We then propose a new class of quark star equation of states, which can be tested by future high-precision radius measurements of pulsar-like objects. 相似文献
972.
By means of collision models(CMs) where the environment is simulated by a collection of ancillas consisting of two entangled qubits, we investigate the effects of entanglement in the environment on the non-Markovianity of an open quantum system. Two CMs are considered in this study, in the first one the open quantum system S directly collides with the environment,while in the second one the system interacts with two intermediate qubits which, in turn, are coupled to the environment. We show that it is possible to enhance the non-Markovianity by environment entanglement in both models. In particular, in the second model, we show that the initial state of the auxiliary qubits can also affect the non-Markovianity of the system and there exists the optimal combination of the initial environmental state and the initial state of auxiliary qubits. In this case, the non-Markovianity can be greatly enhanced. 相似文献
973.
Gongduan Fan Jiuhong Lin Mingqian Xia Jing Luo Banghao Du Heliang Pang Zhongsen Yan 《Particle & Particle Systems Characterization》2021,38(2):2000272
Photocatalysis has attracted much attention as an emerging algae removal technology, but the inactivation performance is inevitably affected by the extracellular polymeric substance (EPS) produced by algae. In this study, a photocatalyst (Ag2O/g-C3N4) with efficient algae inactivation is adopted to investigate the interactions with EPS, and the impact of EPS on photocatalytic algae removal is studied. The results show that EPS can adhere to the surface of Ag2O/g-C3N4 by electrostatic force. The interaction with EPS decreases the surface zeta potential of the Ag2O/g-C3N4 from 7.71 to −22.3 mV with the increase in EPS concentration, and the maximum ratio of particle size increases from 825 to 1281 nm. In addition, the interaction with EPS inhibits the release of Ag+ in Ag2O/g-C3N4 by half, thus, the toxicity of metal ions will be alleviated. Meanwhile, EPS can also be degraded by Ag2O/g-C3N4, indicating that EPS can work as a radical scavenger to protect the algae cells. Without the protection of EPS, 97.8% of algae cells are inactivated after 5 h photocatalysis. Therefore, more attention should be given to the interaction between EPS and photocatalyst to promote the design and application of the photocatalytic. 相似文献
974.
获得覆盖较宽温度和压力范围内的等离子体热力学和输运性质是开展等离子体传热和流动过程数值模拟的必要条件.本文通过联立Saha方程、道尔顿分压定律以及电荷准中性条件求解等离子体组分;采用理想气体动力学理论计算等离子体热力学性质;基于Chapman-Enskog方法求解等离子体输运性质.利用上述方法计算了压力为0.1, 1.0和10.0 atm (1 atm=101325 Pa),电子温度在300—30000 K范围内,非局域热力学平衡(电子温度不等于重粒子温度)条件下氩-氮等离子体的热力学和输运性质.结果表明压力和非平衡度会影响等离子体中各化学反应过程,从而对氩-氮等离子体的热力学及输运性质有较大的影响.在局域热力学平衡条件下,计算获得的氩-氮等离子体输运性质和文献报道的数据符合良好. 相似文献
975.
976.
Reactions between 5‐ferrocenylisophthalic dichloride and 1,2‐bis(o‐aminophenoxy)ethane yield 1:1‐ and 2:2‐cyclization products with amide linkages, which are marked as L1 and L2 , respectively. The crystal structure of the 2:2‐macrocycle L2 is determined by X‐ray single crystal structure analysis. Interestingly, L2 affords a folded conformation due to the intermolecular π–π interaction between two isophthaloyl groups, so as to stabilize the marcocylic conformation. The electrochemical anion sensing studies of L1 and L2 show that they have a good ability to recognize H2PO4–, and the 2:2‐cyclization products ( L2 ) with two ferrocene groups, more anion binding sites, and larger cavities, give better electrochemical anion recognition results than L1 . 相似文献
977.
Dehydration of Castor Oil over NaHSO4/MCM‐41 Catalyst Modified by n‐Dodecyltriethoxysilane
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Cui‐Xia Yan Jian‐Fei Ding Tian‐Lin Ma Rong Shao Wei Xu Jie He Peng‐Fei Wang 《无机化学与普通化学杂志》2017,643(12):772-779
n‐Dodecyltriethoxysilane (DTEOS) modified NaHSO4/MCM‐41 catalysts (silanized catalysts) were synthesized by different impregnation sequences and evaluated in the liquid‐phase dehydration of castor oil. The samples were evaluated by X‐ray diffraction, nitrogen adsorption‐desorption, SEM, TEM, FT‐IR spectroscopy, XPS, 29Si MAS NMR spectroscopy, contact angle measurements, NH3‐TPD, and pyridine‐FT‐IR spectroscopy. The analyses demonstrated that silanization enhanced the hydrophobicity of the catalysts, and the impregnation sequence of silanized catalysts had a significant effect on the NaHSO4 dispersion, surface area, acid distribution, and hydrophobicity of the silanized catalysts. The catalytic activity of the silanized catalysts was much higher than that of NaHSO4/MCM‐41. Among the silanized catalysts, the catalyst prepared by simultaneous impregnation with DTEOS and NaHSO4 showed the highest iodine value of 141.8 [g(I2) per 100 g] and lowest hydroxyl value of 11.3 [mg(KOH) · g–1]. 相似文献
978.
Homoleptic Zinc(II) Complexes Based on 4′‐(2‐Thienyl)‐terpyridine: Preparation,Structures, and Properties
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The homoleptic complexes ZnII(4′‐(2‐(5‐R‐thienyl))‐terpyridine)2(ClO4)2 [R = hydrogen ( 1 ), bromo ( 2 ), methyl ( 3 ), and methoxy ( 4 )] were prepared. Their structures were determined by single‐crystal X‐ray diffraction analyses, and further characterized by high resolution mass, infrared spectra (IR), and elemental analyses. Single crystal X‐ray diffraction analysis showed that ZnII ions in the complexes are both six‐coordinate with N6 coordination sphere, displaying distorted octahedral arrangements. The absorption and emission spectra of the homoleptic ZnII complexes were investigated and compared to those of the parent complex ZnII(4′‐(2‐thienyl))‐terpyridine)2(ClO4)2. The UV/Vis absorption spectra showed that the complexes all exhibit strong absorption component in UV region, moreover, complex 4 has an absorption component in the visible region. Thus, the photocatalytic activities of the complexes in degradation of organic dyes were investigated under UV and visible irradiation. 相似文献
979.
Synthesis,Crystal Structure,Fluorescent and Antioxidation Properties of Cerium(III) and Europium(III) Complexes with Bis(3‐methoxysalicylidene)‐3‐oxapentane‐1,5‐diamine
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Two aliphatic ether Schiff base lanthanide complexes (Ln = Eu, Ce) with bis(3‐methoxysalicylidene)‐3‐oxapentane‐1,5‐diamine (Bod), were synthesized and characterized by physicochemical and spectroscopic methods. [Eu(Bod)(NO3)3] ( 1 ) is a discrete mononuclear species and [Ce(Bod)(NO3)3DMF]∞ ( 2 ) exhibits an inorganic coordination polymer. In the two complexes, the metal ions both are ten‐coordinated and the geometric structure around the LnIII atom can be described as distorted hexadecahedron. Under excitation at room temperature, the red shift in the fluorescence band of the ligand in the complexes compared with that of the free ligand can be attributed to coordination of the rare earth ions to the ligand. Moreover, the antioxidant activities of the two complexes were investigated. The results demonstrated that the complexes have better scavenging activity than both the ligand and the usual antioxidants on the hydroxyl and superoxide radicals. 相似文献
980.
Pengpeng Jia Penghui Cao Xiao Tong Xia Zhou Tian Lei 《Journal of Coordination Chemistry》2017,70(13):2175-2201
Since the initial discovery of applications of platinum complexes in the clinical treatment of many kinds of cancers, the efficiency of platinum complexes in inhibiting the proliferation of various types of tumors surprised researchers working on the development of anticancer drugs. Meanwhile, despite the potent clinical treatment patients get from platinum complexes, there are also disadvantages including limited solubility in aqueous media and side effects like ototoxicity, myelosuppression, nephrotoxicity, and poor selectivity toward healthy cells. For this reason, efforts have been made to search for novel solutions. Non-platinum complexes (like Fe, Pd, Ru, Cu, Bi, Zn, etc.) were found with potential anticancer activities. We here review the properties of five metal complexes as anticancer agents and make comparisons among them in biological features and cytotoxic activity. Seeking the interrelation between microstructure and mechanism of anticancer, we hope this review provides distinct insights into future study of anticancer agents. 相似文献