负载咖啡因-活性炭新吸附材料对钼(VI)的吸附行为的研究

以生物碱（咖啡因）为衍生化试剂，用浸渍法使其负载于活性炭（ＡＣ）上，制成一种新的金属阴离子吸附材料———负载咖啡因－活性炭（ＣＡＣ）。用ＩＣＰ－ＡＥＳ研究了该吸附材料对金属阴离子［Ｍｏ７Ｏ２４］６－的吸附性能；考察了其化学稳定性；还研究了不同浓度硫酸和氨水对待测物吸附率和解脱率的影响及共存离子的干扰影响。     

反胶束笼对纳米氯化银反应性能的微环境限定

研究了反映束中直径为１０￣１７ｎｍ的ＡｇＣｌ微料与亚甲基蓝之间的作用，比较了阴离子型和非离子型表面活性剂组成的反胶束微环境的影响，讨论了亚甲基蓝在粒子上的吸附，二聚体形成的钠米ＡｇＣｌ粒子对亚甲基蓝荧光猝灭机制。     

Development of a modified beta-cyclodextrin based fluorosensor for dipyridamole

2,6-O-diethyl-β-cyclodextrins were prepared and immobilized onto silica gel to develop a fluorosensor for dipyridamole. The analytical performance characteristics of the proposed sensor for analysis of dipyridamole were as follows: the detection limit was 0.8 nmol/L with a relative standard deviation of 1.4% for 10 determinations of 50 nmol/L of dipyridamole. The modification of β-CD improved the sensitivity and selectivity for measuring dipyridamole. The recommended method has been successfully tested for the determination of dipyridamole in clinical samples (urine and pharmaceutical preparations).     

心脑血管病患者头发微量元素铜、锌含量调查

调查了心脑血管病患者头发微量元素铜、锌含量，发现患者发现Cu、Zn含量普通遇低于正常值。     

三价铬与丙二酸形成的配合物的热解过程研究

利用热重分析及原位红外光谱等方法，定性、定量地研究了三价铬和丙二酸形成的配合物［Ｃｒ（Ｃ３Ｈ２Ｏ４）（Ｈ２Ｏ）］［Ｃｒ（Ｃ３Ｈ２Ｏ４）２（Ｈ２Ｏ）２］·４Ｈ２Ｏ的热解过程，提出了室温至４００℃下的详细热解途径．基于多种实验结果，分析了螯合物中六员环的化学键断裂方式，并由配合物的快原子轰击质谱（ＦＡＢ－ＭＳ）加以佐证．     

Homogeneous chemiluminescence system in neutral and near neutral aqueous solution with ClO2 as oxidant and its analytical application

Using ClO₂ as chemiluminescence (CL) oxidant, a novel homogeneous CL system in neutral and near neutral aqueous solution is proposed in this paper. ClO₂ could oxidize sulfite in pH 5.0–8.5 acetate buffer to produce CL emission, and pipemidic acid could sensitize the CL system. The ClO₂–SO₃²⁻–pipemidic acid reaction was used as a model CL system and explored the possibility of highly active and eco-friendly ClO₂ being used as CL oxidant in neutral and near neutral aqueous solution. Combined with flow-injection analysis, the proposed CL system was applied to the automated dissolution testing of pipemidic acid tablet. Compared with the common strong acidic or strong basic CL system, this proposed CL owns its advantages.     

Theoretical investigation of the decarbonylation of acetaldehyde by Fe+ and Cr+.

We report a comprehensive theoretical study on the decarbonylation of acetaldehyde by Fe+ and Cr+. Various intermediates, transition states, and products involved in the decarbonylation reactions are fully optimized at the B3LYP/6-311+G(2df,2pd) level of theory. The potential energy surfaces (PESs) corresponding to [M,O,C2,H4]+(M=Cr and Fe) are examined in detail using B3LYP and CCSD(T) methods, respectively. The validity of these theoretical methods is calibrated with respect to the available thermochemical data. Calculations suggest that the Cr+ mediated decarbonylation of acetaldehyde takes place in four steps on the sextet surface: encounter complexation, C-C activation, aldehyde H-shift, and nonreactive dissociation, in good accordance with the Co+ mediated decarbonylation of acetaldehyde [Zhao, Zhang, Guo, Wu, Lu, Chem. Phys. Lett. 2005, 414, 28], while for the Fe+/acetaldehyde system decarbonylation can occur on both the quartet and the sextet PESs. The quartet pathway, which experiences spin-orbit coupling between the two surfaces, is energetically more favorable; whereas along the sextet decarbonylation coordinate several high-energy barriers are revealed. The theoretical results are compared with the experimental product kinetic energy and angular distributions of decarbonylation of acetaldehyde by Fe+ and Cr+ measured using a crossed-beam technique [Sonnenfroh, Farrar, J. Am. Chem. Soc. 1986, 108, 3521].     

Mesoporous silica nanospheres with the ability of photo-driven releasing sandela 803 for the application to wallpaper

Mesoporous silica nanospheres loaded with sandela 803 (S803@MS-S) are prepared for application to wallpaper. The nano-fragrance has high encapsulation efficiency and property of photo-driven release.     

Study of urinary nucleosides as biological marker in cancer patients analyzed by micellar electrokinetic capillary chromatography

Thirteen normal and modified nucleosides, primarily degradation products of transfer ribonucleic acid (tRNA), were evaluated as potential tumor markers for cancer patients. Their urinary concentrations were determined by means of micellar electrokinetic capillary chromatography (MEKC) in the urine from 54 healthy adults and 70 cancer patients, then quantitatively expressed as a function of creatinine excretion. It was found that urinary nucleosides for cancer patients were on the average significantly higher than those for healthy controls, however, no significant differences were found between male and female or between different ages. Based on 13 urinary nucleoside concentrations, principal component analysis (PCA) could be used to classify 72% of cancer patients from the healthy controls. The present study shows that the precise measurement of urinary nucleosides by MEKC in combining with PCA technique may provide a clinically useful approach for diagnosis of cancer.     

The Study of Anti-tumor Activity of Trichosanthin by Cyclic Voltammogram

IthasbeenreportedthatTrichosanthi11(TCS),isolatedfromrkiI-ilolt)ii,hasanti-tumorI-4andanti-vira1activities5-'.Someanti-tun1orremedies,whicharedesignedfromTCS,arebeingtestedanddeveloped'-.'.StudyingthebioIogicalphenomenonbyelectrochemicalmethodsisanewhotresearchspotemerginginrecentyears".Manyresultsshowedthatnotonlytheenzymesystemsuchassuccinatedehydrogenasedisplayedthediode-likebehaviorduringtheelectrontransferprocess",butalsothehigh1yorganizedorganeIle,forexample,mitochondria,andevenintac…