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881.
882.
铝(Ⅲ)—桑色素—含氧有机溶剂荧光体系的研究 总被引:4,自引:0,他引:4
本文系统研究了醇、酮等7种含氧有机溶剂对铝-桑色素络合物荧光反应的溶剂化效应。研究发现,上述有机溶剂对荧光体系均有增敏作用,以乙醇的效果最佳,使络合物的荧光强度增加6倍多。据此,本文建立了测定微量铝的高灵敏度荧光分析方法,线性范围为0~1.0μg/10ml,检测限为1.6×10~(-9)g/ml。用所建立的方法对化学试剂中的微量杂质铝进行了测定,结果令人满意。并对有机溶剂化效应的机理作了探讨。 相似文献
883.
884.
885.
Chromatographic behavior of poly(styrene-divinybenzene) encapsulated packing material for capillary electrochromatography 总被引:1,自引:0,他引:1
Poly(styrene-divinylbenzene) encapsulated silica (PS-DES) was synthesized and its characteristics as capillary electrochromatography stationary phase were studied. On capillary columns packed with this stationary phase, the effects of acetonitrile concentration as well as pH values on electroosmotic flow, and the effect of the latter on column efficiency were evaluated. Aromatic hydrocarbons, polar and basic medicinal compounds were successfully separated by using reversed-phase elution. It was evident that selectivity based on pi-pi electronic interaction between solute and stationary phase molecules contributed to the separation. Peaks in the chromatograms obtained were generally symmetrical. At a pH of the mobile phase as high as 11.2, the stationary phase was still stable after more than 160 h of exposure. 相似文献
886.
Six new ent‐abietane diterpenoids, rubescensins I–M ( 1 – 5 ) and P ( 6 ), along with two related acetonide derivatives ( 7 and 8 ), were isolated from Isodon rubescens. Their structures were elucidated by detailed spectroscopic analysis. Compound 5 is the first N‐containing diterpenoid from the genus Isodon, exhibiting notable cytotoxicity against human tumor K562 cells. 相似文献
887.
H R Harke S Bay J Z Zhang M J Rocheleau N J Dovichi 《Journal of chromatography. A》1992,608(1-2):143-150
Polyacrylamide capillary gels were prepared with constant (5% C) cross-linker concentration and with total acrylamide concentration ranging from 2.5 to 6% T. At each acrylamide concentration, peak spacing was constant for DNA sequencing fragments ranging from 25 to 250 nucleotides in length. Peak spacing increased linearly with the total acrylamide concentration. The intercept of the retention time vs. fragment length plot was independent of % T. Ferguson plots were constructed for short DNA fragments; the polyacrylamide pore size falls in the 2.5 to 3.5 nm range for the gels studied. Theoretical plate count is independent of total acrylamide concentration; longitudinal diffusion, and not thermal gradients, limit the plate count. A phenomenological model is presented that predicts retention time, plate count, and resolution for sequencing fragments ranging in size from 25 to 250 bases and gels that range from 2.5 to 6% total acrylamide. 相似文献
888.
制备了不同摩尔比的甲基丙烯酸-磷脂酰乙醇甲基丙烯酰胺共聚物,研究了这种共聚物在水面的表面压力(π)-分子面积(A)曲线、共聚物制成的MOS LB膜的电容(C)-电压(V)特性及此LB膜的相变温度。 相似文献
889.
二维卷积在动力学分析中的应用 总被引:2,自引:0,他引:2
本文用计算机模拟和二维卷积研究了稀土与间乙酰基偶氮氯膦的显色反应,选择不同的模型参数可描述这类反应的细节,二维卷积则增强对叠合二维谱的分辨。 相似文献
890.
Yang Wang Weizhe Gao Kangzhou Wang Xinhua Gao Baizhang Zhang Heng Zhao Qingxiang Ma Peipei Zhang Guohui Yang Mingbo Wu Noritatsu Tsubaki 《Chemical science》2021,12(22):7786
Even though the transformation of syngas into aromatics has been realized via a methanol-mediated tandem process, the low product yield is still the bottleneck, limiting the industrial application of this technology. Herein, a tailor-made zeolite capsule catalyst with Ga doping and SiO2 coating was combined with the methanol synthesis catalyst Cr2O3 to boost the synthesis of value-added aromatics, especially para-xylene, from syngas. Multiple characterization studies, control experiments, and density functional theory (DFT) calculation results clarified that Ga doped zeolites with strong CO adsorption capability facilitated the transformation of the reaction intermediate methanol by optimizing the first C–C coupling step under a high-pressure CO atmosphere, thereby driving the reaction forward for aromatics synthesis. This work not only reveals the synergistic catalytic network in the tandem process but also sheds new light on principles for the rational design of a catalyst in terms of oriented conversion of syngas.The single-pass conversion of syngas into para-xylene was realized using a bifunctional catalyst Cr2O3/Ga-ZSM-5@SiO2. The Ga species facilitates the methanol consumption process by C–C coupling optimization, enhancing the yield of the target aromatics. 相似文献