首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   183340篇
  免费   39188篇
  国内免费   27735篇
化学   121645篇
晶体学   2135篇
力学   12200篇
综合类   865篇
数学   22494篇
物理学   90924篇
  2024年   753篇
  2023年   2909篇
  2022年   4562篇
  2021年   4720篇
  2020年   5340篇
  2019年   5516篇
  2018年   5091篇
  2017年   5270篇
  2016年   7459篇
  2015年   7486篇
  2014年   8589篇
  2013年   11994篇
  2012年   13629篇
  2011年   15263篇
  2010年   15585篇
  2009年   15592篇
  2008年   10203篇
  2007年   8977篇
  2006年   8365篇
  2005年   7579篇
  2004年   7221篇
  2003年   5775篇
  2002年   5528篇
  2001年   5373篇
  2000年   4329篇
  1999年   4666篇
  1998年   3925篇
  1997年   3695篇
  1996年   3973篇
  1995年   4089篇
  1994年   3959篇
  1993年   3792篇
  1992年   3315篇
  1991年   2861篇
  1990年   2407篇
  1989年   2369篇
  1988年   2224篇
  1987年   1455篇
  1986年   1525篇
  1985年   1141篇
  1984年   1146篇
  1983年   484篇
  1982年   998篇
  1981年   797篇
  1980年   829篇
  1979年   549篇
  1978年   550篇
  1977年   639篇
  1976年   1054篇
  1972年   541篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
132.
In this paper we will present an overview of the use of photonic crystal fibers as fiber amplifiers. We will describe the basic concepts of optical amplification, and how to do numerical modelling of such components. We will then identify advantages and disadvantages of amplifiers based on PCF technology compared to conventional fibers, and then go into greater detail on some of these specific applications, such as low pump power amplifiers, and high-power double-clad amplifiers and lasers.  相似文献   
133.
In the ever fusion experiments in SWIP, pellet forming process was carried out through adjusting relative devices by staff member in site, which will make every pellet-forming process slight distinction and will result in pellet difference in shape, size and intensity. In the intervals of HL-2A discharges, staff member have to go site to accomplish the pellet-forming process, this wastes human power and increase the potential danger. So it is necessary to develop a remote control system to perform the pellet-forming process. The control system needs have the features of real-time, reliability and be easy to operate and maintain.  相似文献   
134.
In this paper, a very useful numerical technique has been developed for analyzing the transient characteristics of a planar-spiral inductor on-chip. A locally conformal technique and an alternating-direction implicit scheme are applied to the finite-difference time-domain method. A formulation for solving three dimensional Maxwell’s equations is proposed. Using the proposed method, various parameters of the planar-spiral inductors have been analyzed and an equivalent circuit, which includes frequency-independent circuit elements, has been introduced. Highly computational efficiency is implemented. Numerical results show excellent agreement with the measured data over a wide frequency range.  相似文献   
135.
We have conducted a millimeter wave propagation experiment at 103 GHz (2.9 mm) on a propagation path of 390 m. The results were compared with the rain attenuation calculations from the Marshall-Palmer, Best, Joss-Thomas-Waldvogel and Weibull distributions for raindrop-size. It has been shown that the Weibull distribution has a good agreement with the experiments.  相似文献   
136.
137.
The first α‐diimine nickel(I) complex having a chloro bridge is reported. The centrosymmetric dinuclear structure of {[ArN?C(Me)C(Me)?NAr]NiCl}2[Ar?2,6?C6H3(i‐Pr)2] features two chelating α‐diimine ligands and two bridged chlorine atoms, so that a distorted tetrahedral N2Cl2 coordination geometry for nickel results. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
138.
Wang  Qing-Lun  Zhao  Bin  Liao  Dai-Zheng  Yan  Shi-Ping  Cheng  Peng  Jiang  Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer.  相似文献   
139.
We present all-atom molecular dynamics simulations ofn-hexane on the basal plane of graphite at monolayer and multilayer coverages. In keeping with experimental data, we find the presence of ordered adsorbed layers both at single monolayer coverage and when the adsorbed layer coexists with excess liquid adsorbate. Using a simulation method that does not impose any particular periodicity on the adsorbed layer, we quantitatively compare our results to the results of neutron diffraction experiments and find a structural transition from a uniaxially incommensurate lattice to a fully commensurate structure on increasing the coverage from a monolayer to a multilayer. The zig-zag backbone planes of all the alkane molecules lie parallel to the graphite surface at the multilayer coverage, while a few molecules are observed to attain the perpendicular orientation at monolayer coverage. Dedicated to Professor C N R Rao on his 70th birthday  相似文献   
140.
Effects of ion impinging on the microstructure and field electron emission properties of screen-printed carbon nanotube films were investigated. We observed that the plasma treatment modified the microstructure of CNTs along with the remarkable increase of emission site density. With the prolongation of ion impinging time, the emission current falls down first, and then rises up to higher than that of the untreated films. It is proposed that the change of emission characteristics is due to the different emission mechanisms. After the treatment, electrons are emitted predominantly from the nano-nodes on the tube wall instead from the nanotube tips.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号