首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2936篇
  免费   528篇
  国内免费   426篇
化学   2165篇
晶体学   19篇
力学   160篇
综合类   22篇
数学   337篇
物理学   1187篇
  2024年   10篇
  2023年   61篇
  2022年   115篇
  2021年   79篇
  2020年   131篇
  2019年   123篇
  2018年   126篇
  2017年   102篇
  2016年   156篇
  2015年   142篇
  2014年   183篇
  2013年   202篇
  2012年   229篇
  2011年   244篇
  2010年   180篇
  2009年   176篇
  2008年   219篇
  2007年   151篇
  2006年   159篇
  2005年   160篇
  2004年   113篇
  2003年   106篇
  2002年   111篇
  2001年   79篇
  2000年   63篇
  1999年   72篇
  1998年   58篇
  1997年   32篇
  1996年   45篇
  1995年   44篇
  1994年   39篇
  1993年   40篇
  1992年   25篇
  1991年   20篇
  1990年   19篇
  1989年   16篇
  1988年   11篇
  1987年   13篇
  1986年   11篇
  1985年   7篇
  1984年   8篇
  1983年   4篇
  1982年   1篇
  1981年   3篇
  1980年   1篇
  1936年   1篇
排序方式: 共有3890条查询结果,搜索用时 0 毫秒
51.
Near-field optical trapping can be realized with focused evanescent waves that are excited at the water–glass interface due to the total internal reflection, or with focused plasmonic waves excited on the water–gold interface. Herein, the performance of these two kinds of near-field optical trapping techniques is compared using the same optical microscope configuration. Experimental results show that only a single-micron polystyrene bead can be trapped by the focused evanescent waves, whereas many beads are simultaneously attracted to the center of the excited region by focused plasmonic waves. This difference in trapping behavior is analyzed from the electric field intensity distributions of these two kinds of focused surface waves and the difference in trapping behavior is attributed to photothermal effects due to the light absorption by the gold film.  相似文献   
52.
Rapid industrialization and economic development have led to serious pollution in the form of fine particulate matter(PM2.5,particulate matter with a diameter of less than 2.5 μm). In China, PM2.5 has been one of the most debated topics in councils of government and issues of public concern. Terahertz(THz) radiation was employed to measure the PM2.5 in the atmosphere from September 2014 to April 2015 in Beijing. Comparison of the PM2.5 level from the website with THz absorbance revealed a significant phenomenon: THz radiation can be used to monitor PM2.5 in the atmosphere. During Asia-Pacific Economic Cooperation(APEC) 2014, "APEC Blue" was also recorded in a THz system. The relationship between absorbance and PM2.5 demonstrates that THz radiation is an effective selection for air pollution grading. Based on the absorbance spectra, the elemental compositions were studied by two-dimensional correlation spectroscopy(2 DCOS) in conjunction with X-ray fluorescence.Several single absorption peaks were revealed and caused by sulphate from coal combustion, vehicle exhaust emissions and secondary reactions. Furthermore, mathematical algorithms, such as the BPANN and SVM, can process the THz absorbance data and greatly improve the precision of the estimation of PM2.5 mass. Our results suggest that THz spectroscopy can not only reveal the component information for pollution source determination, but quantitatively monitor the PM2.5 content for pollution level evaluation. Therefore, the use of THz radiation is a new method for future air pollution monitoring and grading systems.  相似文献   
53.
Wine has become a commodity of significant commercial value, and the demand for high quality wine by consumers has been increasing. Suitable analytical techniques are needed for its quality control. Ultraviolet, Visible, Near-infrared and infrared spectroscopy is by far one of the most important techniques for determining the wine quality, including its components and characterization. This review will overview the available most recent applications of spectroscopic techniques in the past decade for wine quality prediction and discrimination both quantitatively and qualitatively. The fundamental principles of these techniques will be introduced briefly, and some innovative setups/instrumentations will also be illustrated. At last the limitations and prospects of spectroscopic techniques for wine industry will be discussed.  相似文献   
54.
The dielectric relaxation behaviors of hot pressed poly(vinylidene fluoride) (PVDF) film have been studied using dielectric spectroscopy in the frequency domain from 20 Hz to 5 MHz at temperatures between 20 °C and 200 °C. Crystalline/amorphous interphase is suggested with methods of FTIR, XRD, and DSC. Frequency and temperature dependence of dielectric spectroscopy reveals the relaxation behavior and structural dynamics of the samples, and three types of relaxation processes are suggested, αAc relaxation process contributed by the hopping transport process near the periphery of conduction band or valence zones at Fermi energy, αc relaxation process related to the structure change of crystal lattice trapped dipoles in crystalline regions, and αa relaxation process arising from segmental dipole rearrangement of interphases in amorphous regions. Cole-Cole and Havriliak-Negami experimental equations were utilized to analyze these relaxation processes, and differences of Arrhenius parameters for αAc and αc relaxation processes obtained from Cole-Cole and Havriliak-Negami equations were discussed in detail. Activity energy of different relaxation processes obtained from Arrhenius equation and VFT equation indicates non-single thermal activation mechanism for hot pressed PVDF film.  相似文献   
55.
孟立建  钟国柱 《发光学报》1987,8(3):226-235
采用原子层外延方法(ALE)制备了ZnS:Er3+交流电致发光(ACEL)薄膜,得到了明亮的绿色EL。发现了随Er3+离子浓度增加,对应于4F9/2→4I15/2跃迁的谱线强度增加甚至超过2H11/2→4I15/2跃迁的谱线强度。通过对EL衰减的分析,发现了绿红比随外加电压的变化关系以及EL光谱与温度的关系。在Er3+离子浓度较高时,Er3+离子之间发生明显的能量传递。提出了Er3+离子间的交叉驰豫模型并计算了交叉弛豫速率,同拟合衰减曲线得到的值相比,两者符合得较好。  相似文献   
56.
A hybrid binary subtracted joint transform correlator was constructed using a Bi12SiO12 (BSO) spatial light modulator and a laser scanner. The usefulness of this system was confirmed experimentally using a large number of binary and halL-tone images as the reference patterns.  相似文献   
57.
通过对“可见光区域是否存在Compton效应”的讨论而进一步深化到经典条件下“光的量子理论能否包含光的经典电磁理论”的实验验证,发现了Lorentz-Compton佯谬,并基于逆Compton散射设计了一个敏感而又可行的双赢判决性散射实验来解决此佯谬。  相似文献   
58.
Wu Z  Zhan L  Shen Q  Liu J  Hu X  Xiao P 《Optics letters》2011,36(19):3837-3839
We present an ultrafine tunable single-frequency Brillouin fiber laser in which the fiber Brillouin gain also acts as a high-precision tunable filter. Controlling the strain on the fiber, the Stokes frequency shift may be precisely changed, and thus the lasing frequency can be tuned. Assisted by the frequency pulling effect, this method provides continuous ultrafine tuning ability for ~30% of the free spectral range without mode hopping, and can cover 271 MHz. The experiments showed that the laser achieves tuning step of 60 kHz.  相似文献   
59.
微穿孔板吸声结构是由微穿孔板与板后空腔组成的共振吸声结构,被认为是继多孔吸声材料之后发展起来的最有吸引力的吸声结构,其吸声特性与结构参数孔径d、板厚t、孔距b及空腔深度D有关,如何按需设计一个有效的微穿孔板吸声结构已成为目前研究的热点。本文从微穿孔板吸声结构和吸声特性混合设计的角度出发,使用面向对象的编程语言C++开发了微穿孔板吸声结构设计平台。与以往设计方法不同,本文开发的软件平台综合考虑了结构参数和吸声特性参数两方面的限制,根据实际应用要求平衡微穿孔板吸声结构的最大吸声系数与吸声带宽之间的制约关系,并以饱满的吸声曲线为目标,提供满足混合设计要求的优化结构参数。  相似文献   
60.
We investigate two high frequency Raman overtone and combination modes of graphene named 2D' and 2D + G bands, and located at ~3240 and ~ 4260 cm–1, respectively. The graphene thickness and stacking geometry effects for these two modes are systematically studied. The features of the 2D' band, which arises from intravalley double resonance, are not sensitive to the variation of thickness with single Lorentzian peak and fixed linewidth. We explain it theoretically by calculating the phonon dispersion mode in k‐space and find that the flat band region of longitudinal optical phonon near Γ point is the mechanism leading to the 2D' band nonsplit. With the thickness increasing, the band position exhibits blueshift and the linewidth increases for the 2D + G band. With changing thickness and stacking geometry of graphene, the intensities of these two high‐frequency bands show obvious different evolution compared with that of G band. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号