全文获取类型
收费全文 | 3381篇 |
免费 | 551篇 |
国内免费 | 483篇 |
专业分类
化学 | 2442篇 |
晶体学 | 31篇 |
力学 | 229篇 |
综合类 | 37篇 |
数学 | 405篇 |
物理学 | 1271篇 |
出版年
2024年 | 12篇 |
2023年 | 70篇 |
2022年 | 100篇 |
2021年 | 82篇 |
2020年 | 142篇 |
2019年 | 131篇 |
2018年 | 131篇 |
2017年 | 128篇 |
2016年 | 168篇 |
2015年 | 147篇 |
2014年 | 196篇 |
2013年 | 225篇 |
2012年 | 260篇 |
2011年 | 274篇 |
2010年 | 210篇 |
2009年 | 197篇 |
2008年 | 237篇 |
2007年 | 189篇 |
2006年 | 204篇 |
2005年 | 189篇 |
2004年 | 130篇 |
2003年 | 117篇 |
2002年 | 122篇 |
2001年 | 91篇 |
2000年 | 73篇 |
1999年 | 91篇 |
1998年 | 71篇 |
1997年 | 54篇 |
1996年 | 66篇 |
1995年 | 61篇 |
1994年 | 44篇 |
1993年 | 47篇 |
1992年 | 29篇 |
1991年 | 21篇 |
1990年 | 24篇 |
1989年 | 21篇 |
1988年 | 12篇 |
1987年 | 12篇 |
1986年 | 13篇 |
1985年 | 7篇 |
1984年 | 9篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1936年 | 1篇 |
排序方式: 共有4415条查询结果,搜索用时 31 毫秒
101.
The kinetic study of carbonylation of methanol-acetic acid mixture to acetic acid and acetic anhydride over a cis-dicarbonylrhodium complex (MVM' Rh) coordinated with the ethylene diacrylate (M') crosslinked copolymer of methyl acrylate (M) and 2-vinylpyddine (V)shows that the rate of reaction is zero order with respect to both reactants methanol and carbon monoxide, but first order in the concentrations of promoter methyl iodide and rhodium in the complex. Polar solvents can accelerate the reaction. Activation parameters were calculated from the experimental results, being comparable to that of the homogeneous system. A mechanism similar to that of soluble rhodium catalyst was proposed. 相似文献
102.
One linear template 13 and one cyclophane template 15, both incorporating two electron rich 1,4‐dialkoxybenzene units and one diamide unit, have been synthesized. By utilizing donor‐acceptor interaction and/or intermolecular hydrogen bonding assembling principles, one novel hetero[3]rotazane 22·4Cl, possessing one neutral and one tetracationic ring components, has been synthesized from 13, through neutral [2]rotaxane 21 as intermediate. With 15 as template, tetracationic [2]catenane 23·4PF6 was assembled by using donor‐acceptor interaction, but no neutral [2]rotaxane could be obtained under the typical conditions of hydrogen bonding assembling principle. The interlocked supramolecular compounds have been characterized and their spectral properties are investigated. 相似文献
103.
Si-Tai Zheng Huan-Huan Yin Zhao-Guang Ma Nan-Li Sheng Tian-Guang Zhan Xiao-Yang Yan Jiecheng Cui Li-Juan Liu Kang-Da Zhang 《中国化学快报》2019,30(3):707-709
Photoresponsive supramolecular hydrogel was fabricated from a small azobenzene-bridged dicationic pyridinium salt in the aqueous solution. The UV-vis light triggered reversible gel-sol transformation of such low-molecular-weight supramolecular hydrogel was systematically investigated through various analytical techniques. 相似文献
104.
HongMinMA ZhanZhuLIU ShiZhiCHEN 《中国化学快报》2003,14(5):468-470
A new approach to synthesis of 6,7-dimethoxyisatin is reported.2-nitro-3,4-dimethoxy mandelonitrile in glacial acetic acid was treated with the solution of stannous chloride in hydrochloric acid to give 6,7-dimethoxyisatin in a high yield. 相似文献
105.
Liu JM Hu SR He XM Li XL Zhan FP Zeng LQ Li LD Zhu GH Huang XM 《Analytical and bioanalytical chemistry》2005,382(7):1507-1512
Silicon dioxide nano-particles, diameter 50 nm, containing morin (morin–SiO2) have been synthesized by the sol–gel method. They emit strong and stable room-temperature phosphorescence (SS-RTP) on filter paper as substrate, and bismuth can quench the intensity of the SS-RTP. On this basis a new morin–SiO2 solid-substrate room-temperature phosphorescence-quenching method has been established for determination of traces of bismuth. Reduction of phosphorescence intensity (Ip) is directly proportional to the concentration of bismuth in the working range 0.16–14.4 ag spot–1 (sample volume 0.40 L spot–1, corresponding to the concentration range 0.40–36.0 fg mL–1). The regression equation of the working curve is Ip=14.86+5.279×[Bi3+] (ag spot–1) (n=6, r=0.9982). The detection limit of this method is 0.026 ag spot–1 (corresponding to a concentration of 6.5×10–17 g mL–1).This sensitive, reproducible and accurate method has been used for successful analysis of real samples. 相似文献
106.
Xu X Zhao Z Song P Zhou G Xu J Deng P Bourdet G Chanteloup JC Zou JP Fulop A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(11-12):2444-2447
Infrared (1.2-1.6 microm) luminescence in a ytterbium aluminium garnet (YbAG) crystal, doped with Cr (0.05at.%) ions, was investigated under CW laser diode pumping (lambda=940 nm). The Cr4+ emission band was observed with its peak at 1.34 microm and measured to be about 1.3 times with respect to Yb3+ IR luminescence (lambda=1.03 microm). We demonstrate that for the excitation wavelength of 940 nm Yb3+ ions act as sensitizers of the 3B2(3T2)-3B1(3A2) emission of Cr4+ ions. This crystal is promising as a high-efficient system for tunable laser (1.2-1.6 microm) output. 相似文献
107.
108.
Yizhao Ouyang Miao Zhan Jing Zhou Jiao Jiao Hao Hu Yoichi M. A. Yamada Pengfei Li 《中国化学》2019,37(8):807-810
A rigid C2‐symmetric chiral bipyridine ligand Z‐bpy with a triptycene‐like backbone was designed and synthesized from simple chemicals in a scalable route. Using this new ligand, copper(I) catalyzed cyclopropanation of styrenes with commercial ethyl diazoacetate produced various corresponding cyclopropanes in high yields, diastereoselectivity and enantioselectivity up to 97% ee. 相似文献
109.
110.
Wine has become a commodity of significant commercial value, and the demand for high quality wine by consumers has been increasing. Suitable analytical techniques are needed for its quality control. Ultraviolet, Visible, Near-infrared and infrared spectroscopy is by far one of the most important techniques for determining the wine quality, including its components and characterization. This review will overview the available most recent applications of spectroscopic techniques in the past decade for wine quality prediction and discrimination both quantitatively and qualitatively. The fundamental principles of these techniques will be introduced briefly, and some innovative setups/instrumentations will also be illustrated. At last the limitations and prospects of spectroscopic techniques for wine industry will be discussed. 相似文献