Investigation of the correlation between internal gradients and dephasing effect in inhomogeneous field

Internal magnetic gradient plays a significant role in Nuclear Magnetic Resonance (NMR) measurements of fluid saturated porous media. The quantitative characterization and application of this physical phenomenon could effectively improve the accuracy of NMR measurements and interpretations. In this paper, by using the equivalent magnetic dipole method, the three-dimensional distribution of internal induced magnetic field and its gradients in the randomly packed water saturated glass beads are quantitatively characterized. By simulating the diffusive motion of water molecules in porous media with random walk method, the computational dephasing effects equation related to internal gradients is deduced. Thereafter, the echo amplitudes are obtained and the corresponding T ₂-G spectrum is also inverted. For the sake of verifying the simulation results, an experiment is carried out using the Halbach core analyzing system (B ₀=0.18 T, G=2.3 T/m) to detect the induced internal field and gradients. The simulation results indicate the equivalent internal gradient is a distribution of 0.12–0.3 T/m, which matched well with the experimental results.     

Effects of flux on crystal structure and luminescent properties of nitroxides phosphors

Yellow-green-emitting Sr Si2O2N2:Eu2+phosphors were synthesized with Sr2Si O4:Eu2+as precursor.The effects of flux and the concentration of Eu2+on the crystal structure and luminescent properties of the phosphors were investigated.Results suggested that the optimal content of flux Na2CO3 was 1 wt%and the optimal doping concentration of Eu2+was 0.05 mol.The emission spectra showed the most intense peaks located at 535 nm which corresponded to the 4f65d→4f7 transition of Eu2+.The excitation spectra showed that these phosphors could be effectively excited by near-ultraviolet and blue light,whichwas consistent with the widely applied output wavelengths of near-ultraviolet and blue-white light-emitting diode(LED)chips.When the influence of flux on the luminescent properties of Sr Si2O2N2:Eu2+phosphor was analyzed,the X-ray diffraction(XRD)patterns indicated that the flux could help the crystallization of the phosphors.No other phases except the triclinic structure of Sr Si2O2N2 were formed.The thermal stability and the emission intensity of synthesized Sr Si2O2N2:Eu2+phosphor were examined and compared with commercial YAG yellow phosphors.All results indicate that the yellow-green-emitting phosphor is a suitable candidate for the fabrication of white LEDs.     

Multilevel Nonvolatile Flexible Organic Field‐Effect Transistor Memories Employing Polyimide Electrets with Different Charge‐Transfer Effects

The electrical memory characteristics of the n‐channel organic field‐effect transistors (OFETs) employing diverse polyimide (PI) electrets are reported. The synthesized PIs comprise identical electron donor and three different building blocks with gradually increasing electron‐accepting ability. The distinct charge‐transfer capabilities of these PIs result in varied type of memory behaviors from the write‐one‐read‐many (WORM) to flash type. Finally, a prominent flexible WORM‐type transistor memory is demonstrated and shows not only promising write‐many‐read‐many (WMRM) multilevel data storage but also excellent mechanical and retention stability.

     

Universal scheme for finite-probability perfect transfer of arbitrary multispin states through spin chains

In combination with the theories of open system and quantum recovering measurement, we propose a quantum state transfer scheme using spin chains by performing two sequential operations: a projective measurement on the spins of ‘environment’ followed by suitably designed quantum recovering measurements on the spins of interest. The scheme allows perfect transfer of arbitrary multispin states through multiple parallel spin chains with finite probability. Our scheme is universal in the sense that it is state-independent and applicable to any model possessing spin–spin interactions. We also present possible methods to implement the required measurements taking into account the current experimental technologies. As applications, we consider two typical models for which the probabilities of perfect state transfer are found to be reasonably high at optimally chosen moments during the time evolution.     

基于节点拓扑特征的中国基金公司共持网络持股行为波动相关性

选取2003—2012年期间半年度中国基金公司持上市公司股票份额面板数据为样本数据,以基金公司为节点,以同一时刻共持同一家上市公司股票关系为边,以同一时刻共持的上市公司数量为权重,构建中国基金公司共持关系结构等价加权网络(简称共持网络).结合统计物理学等方法,分析了共持网络的拓扑结构稳定性及具有不同拓扑特征值的节点随时间演变过程中与共持网络中三类节点集合持股行为波动相关性.三类节点集合分别为t-1时刻基于某一股票形成的共持关系完全连通子图节点集合(第一类节点集合)、t-1时刻共持网络中非完全连通子图的节点集合(第二类节点集合)、t时刻新进入共持网络的节点集合(第三类节点集合).分析结果显示:1)节点与第二类节点集合持股行为波动呈正相关,且相关系数随着节点集聚系数的增强而增大;2)只有当节点的度和点强度值较高时,节点与第一类和第二类节点集合的持股行为呈正相关;3)不同拓扑特征条件下的节点与第三类节点集合的持股行为均不存在波动相关性.本文提供了一个研究持股行为相关性的新思路,并为进一步研究股票市场结构等价网络及节点重要性差异提供了基础.     

带时延与丢包的网络化多智能体系统控制器设计

网络时延与数据丢包极大地降低了网络化多智能体系统的控制性能,甚至会破坏稳定性.考虑存在网络时延与数据丢包的网络化多智能体系统,提出了一种基于时延与丢包补偿机制的预测控制器设计方法,来主动地消除网络时延与数据丢包的影响.通过对网络化多智能体预测控制系统的分析,给出了能够保证系统稳定性与一致性的控制器设计步骤.最后的仿真实例表明了该方法的有效性.     

Superconductivity of MgB2: covalent bonds driven metallic

A series of calculations on MgB2 and related isoelectronic systems indicates that the layer of Mg2+ ions lowers the nonbonding B pi ( p(z)) bands relative to the bonding sigma ( sp(x)p(y)) bands compared to graphite, causing sigma-->pi charge transfer and sigma band doping of 0.13 holes/cell. Because of their two dimensionality the sigma bands contribute strongly to the Fermi level density of states. Calculated deformation potentials of gamma point phonons identify the B bond stretching modes as dominating the electron-phonon coupling. Superconductivity driven by sigma band holes is consistent with the report of destruction of superconductivity by doping with Al.     

基于外电场作用氟氯碳酰的光谱特性和解离特性

采用密度泛函方法(DFT)在B3LYP/6-31G(d)水平上优化计算了在不同外电场作用下氟氯碳酰分子的物理性质,包括键长、键角、分子体系总能量、偶极矩、能隙、红外光谱、拉曼光谱以及解离特性.研究表明在外电场(-0.02—0.07 a.u.)作用下,氟氯碳酰分子结构有明显的变化,随着外电场的增强,分子C-O键长、C-Cl键长逐渐增大,C-F键长逐渐减小,分子体系总能量、能隙先增大后减小,偶极矩先减小后增大;分子红外光谱的O p-deform、CCl stretch(str)、CF str振动发生了蓝移,CO str振动发生了红移,CO deform振动先红移后蓝移,分子拉曼光谱的O p-deform、CCl str、CF str、CO str振动移动情况与红外光谱相同,当外电场强度为0.03 a.u.时,分子C-Cl势垒消失,分子发生解离,当外电场强度为-0.005 a.u.时,分子两个键断裂,发生逐步解离.研究工作为进一步研究氟氯碳酰分子的解离特性及臭氧层的保护提供理论依据.     

Feature-Specific CT Measurements for Log Scanning: Theory and Application

Computed Tomography (CT) is extensively used as a medical diagnostic tool, and increasingly adopted for scientific and industrial research. In the wood industry, there is a growing interest in using the CT technique to assess the quality of logs entering a sawmill to enable the material to be appropriately processed into maximum value products. Internal features of interest include knots, heartwood/sapwood boundary, rot and splits. Most commercially available CT scanning systems are modeled on medical designs and provide high spatial and density resolution. They are very complex and delicate devices with correspondingly high cost. However, log scanning has its own distinctive characteristics: specific overall and feature geometries and relatively coarse scanning resolution requirement. To fit these characteristics, the novel geometry-based coarse-resolution CT scanning approach described here has been developed and implemented. The models, algorithms, scanner design and result validation are presented in detail. The resulting CT reconstructions for an example log using the proposed geometry-based coarse-resolution approach compare well with CT reconstructions for same log using the same data with conventional filtered back projection inversion. The good comparison gives confidence in the usefulness and applicability of the proposed CT method for industrial use in sawmills for log quality assessment.