In this paper, we propose a new application of the adaptive critic methodology for the feedback control of wheeled mobile
robots, based on a critic signal provided by a neural network (NN). The adaptive critic architecture uses a high-level supervisory
NN adaptive critic element (ACE), to generate the reinforcement signal to optimise the associative search element (ASE), which
is applied to approximate the non-linear functions of the mobile robot. The proposed tracking controller is derived from Lyapunov
stability theory and can guarantee tracking performance and stability. A series of computer simulations have been used to
emulate the performance of the proposed solution for a wheeled mobile robot. 相似文献
The first enantioselective methodology for the synthesis of electron-poor 2-hydroxyalkyl- and 2-aminoalkyl furanes is demonstrated in this study. It utilizes a highly stereoselective organocatalytic one-pot reaction cascade: epoxidation or aziridination of α,β-unsaturated aldehydes followed by Feist-Be?nary reaction of various 1,3-dicarbonyl compounds to give the target furanes. This efficient multibond forming reaction cascade benefits from low catalyst loadings and readily available starting materials. Furthermore, the possibility to interrupt the reaction sequence at the stage of the corresponding optically active 2-hydroxyalkyl- and 2-aminoalkyl 2,3-dihydrofuranes with three stereogenic centers is also presented. Finally, models which account for the formation of the optically active 2,3-dihydrofuranes are proposed. 相似文献
We show that the equality m1(f(x))=m2(g(x)) for x in a neighborhood of a point a remains valid for all x provided that f and g are open holomorphic maps, f(a)=g(a)=0 and m1,m2 are Minkowski functionals of bounded balanced domains. Moreover, a polynomial relation between f and g is obtained. 相似文献
We investigate stationary hidden Markov processes for which mutual information between the past and the future is infinite. It is assumed that the number of observable states is finite and the number of hidden states is countably infinite. Under this assumption, we show that the block mutual information of a hidden Markov process is upper bounded by a power law determined by the tail index of the hidden state distribution. Moreover, we exhibit three examples of processes. The first example, considered previously, is nonergodic and the mutual information between the blocks is bounded by the logarithm of the block length. The second example is also nonergodic but the mutual information between the blocks obeys a power law. The third example obeys the power law and is ergodic. 相似文献
Hydrogen electrosorption into Pd-rich (>80 at.% Pd in the bulk) Pd–Rh alloys has been studied in acidic solutions (0.5 M H2SO4) using cyclic voltammetry and chronoamperometry. The influence of temperature (in the range between 283 and 328 K), electrode potential and alloy bulk composition on hydrogen electrosorption properties of Pd–Rh alloys is presented. It has been found that the additive of Rh to Pd–Rh alloys increases the maximum hydrogen solubility (for Rh bulk content below 10 at.%), decreases the potential of absorbed hydrogen oxidation peak and decreases the potential of the α → β phase transition. Increasing temperature decreases the potential of absorbed hydrogen oxidation peak, the maximum hydrogen solubility, and the potential of the α → β phase transition. The amounts of electrosorbed hydrogen for α- and β-phase boundaries, i.e., αmax and βmin, have been determined from the integration of the initial parts of current–time responses in hydrogen absorption and desorption processes. The H/M ratio corresponding to αmax increases with increasing Rh content, while for βmin a maximum of H/M ratio is observed for the alloys containing ca. 95% Rh.
The microwave-assisted Cannizzaro reaction was studied in order to develop fully reproducible synthetic protocols for transformation of aldehydes to carboxylic acid and alcohols. Optimised were the following process parameters: power, temperature, and time. Aromatic, heteroaromatic and aliphatic aldehydes were used in the studies. It was found that furfural, thiophene-2-carbaldehyde, pyridinecarboxaldehyde and aromatic aldehydes react under mild conditions, while 1-methyl-pyrrole-2-carboxaldehyde derivatives and aliphatic aldehydes require more drastic reaction conditions and a longer exposure time to microwave radiation. 相似文献
JPC – Journal of Planar Chromatography – Modern TLC - In a previous paper we discussed the possibility of fractionating the essential oils of different sage species by low-temperature... 相似文献