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981.
Transition metal complexes of Ni(II) and Pd(II) with ditertiary bis(diphenylphosphinomethyl)amino ligands, (Ph2PCH2)2NC(CH3)3 ( 1 ) and [(Ph2PCH2)Nm‐PhSO3]Na ( 2 ) (Ph = phenyl), have been synthesized in good yields under nitrogen atmosphere by Schlenk technique. All complexes have been characterized using elemental analyses and spectroscopic techniques such as atomic absorption, FT‐IR, and NMR (1H, 31P). Atomic absorption spectroscopic analysis showed that the reactions of ligands 1 and 2 with NiCl2 ⋅ 6H2O and [PdCl2(COD)] occurred in 1:1 molar ratio. The metal complexes [NiCl2(Ph2PCH2)2Nm‐PhSO3Na] ( 4 ) and [PdCl2(Ph2PCH2)2Nm‐PhSO3Na] ( 6 ) were found to be soluble in ethanolic and aqueous solutions, as well as slightly soluble in water. Electrochemical behaviors of complexes were investigated by cyclic voltammetry. Catalytic effects of Pd(II) complexes were tested throughout the hydrogenation of styrene to ethylbenzene. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:113–118, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20384 相似文献
982.
Ali M. Haseeb Mustafa Keskin Ian L. Pegg Paul H. E. Meijer 《Fluid Phase Equilibria》1996,120(1-2):93-105
We describe a method to determine tielines for a mixture with a given volume Vt and a given mole fraction xt at fixed temperature, which is based on the orientation of the tangent plane to the Helmholtz free energy surface. The method works equally well for gas-liquid separation as for liquid-liquid separation. The method is based on a rotation in coordinate space followed by a rotation in function space which establishes the correct direction and the end points of the tieline. The mathematics is described and the general outline of a computer program to implement the method is given. This is followed by an application to a special form of the van der Waals equation, which describes the influence of chain-molecules as proposed by Tompa. The example given shows a three phase separation and the influence of the chain-length thereupon. 相似文献
983.
Mustafa Akgül 《Mathematical Programming》1984,30(1):112-120
McLinden (Mathematical Programming 24 (1982) 162–176) has extended theorems of Tucker (1956) and Williams (1970) on the complementarity
behaviour of feasible and optimal solutions to a pair of canonical linear programs to proper convex polyhedral functions.
He achieved this by heavily using the well-developed machinery of convex analysis. In this note, we prove most of his results
mainly using linear programming theory. 相似文献
984.
Ebtissam Abdel Aziz Hafez Nosrat Mustafa Abed Ibrahim Ahmed Elsakka Mohamed Hilmy Elnagdi 《Journal of heterocyclic chemistry》1983,20(2):285-288
Several new stable azolylhydrazones could be synthesized via coupling of diazotised cycliuc amidines with active methylene reagents. The obtained compounds were utilised for synthesis of several, otherwise not readily accessible fused azoles. 相似文献
985.
Mustafa Akgül 《The Journal of the Operational Research Society》1984,35(5):425-431
Using convex analysis and a characterization of the entire family of optimal solutions to an L.P., we show that in order to obtain shadow prices, one has to solve a much smaller L.P. derived from any optimal tableau. We then show that positive as well as negative shadow prices for any constraint or for any combination of constraints can easily be computed by parametric linear programming. Some examples exhibiting the method are also included. 相似文献
986.
Distribution of eigenvalues for the discontinuous boundary-value problem with functional-manypoint conditions 总被引:2,自引:0,他引:2
O.?Sh.?MukhtarovEmail author Mustafa?Kandemir Nuri?Kuruo?lu 《Israel Journal of Mathematics》2002,129(1):143-156
In this study, we investigate the boundary-value problem with eigenvalue parameter generated by the differential equation
with discontinuous coefficients and boundary conditions which contains not only endpoints of the considered interval, but
also a point of discontinuity, a finite number of internal points and abstract linear functionals. So our problem is not a
pure boundary-value one.
We single out a class of linear functionals and find simple algebraic conditions on the coefficients which guarantee the existence
of an infinite number of eigenvalues. Also, the asymptotic formulas for the eigenvalues are found.
The results obtained in this paper are new, even in the case of boundary conditions either without internal points or without
linear functionals. 相似文献
987.
Mustafa M. El-Abadelah Ali A. Anani Zahida H. Khan A. M. Hassan Ali Katrib 《Journal of heterocyclic chemistry》1980,17(8):1671-1680
Deoxygenation results of some quinoxaline dioxides with phosphorous trichloride are presented and compared with previous deoxygenations with other reagents. Differentiation between isomeric quinoxaline oxides using X-ray photoelectron spectroscopy is also discussed. 相似文献
988.
Mustafa I. Selim Joseph R. Strubinger 《Fresenius' Journal of Analytical Chemistry》1988,330(3):246-249
Summary The mass spectrometric tracer pulse (MSTP) chromatography method was used to measure the amount of supercritical n-pentane dissolved or adsorbed into SE-54 and SE-30 capillary columns. Partition data were measured above the critical point of n-pentane at temperatures from 200 ° to 300 °C and pressures between 35.04 and 54.42 atm. The data obtained provide evidence for mobile fluid solubility or adsorption into the stationary phase under the conditions of supercritical fluid chromatography (SFC). At 220 °C, solubility and/or adsorption of supercritical n-pentane decreases by increasing the pressure and reaches a minimum at approximately 45.00 atm. The effect of mobile-fluid pressure on its solubility or adsorption becomes limited at temperatures over 260 °C. This study demonstrates the unique experimental capabilities of the MSTPC method for quantitative measurement of the physico-chemical interaction of the complex multicomponent system encountered in SFC which is not possible by any other technique. An innovative instrumental design for modification of GC/MS systems for SFC, GC/MS operation is also described.
Verteilung von superkritischem n-Pentan in den stationären Phasen SE-54 und SE-30 bei der Capillar-Chromatographie mit superkritischen fluiden Phasen相似文献
989.
990.
Mustafa Erol 《Czechoslovak Journal of Physics》2000,50(5):665-670
We report electrical transport properties of intentionally and unintentionally doped wurtzite GaN epilayers within the temperature range of 3K up to 340 K. Specifically, temperature dependence of the carrier concentration, mobility and resistivity are investigated. Obtained data could only be explained on the basis of two-band model, namely, high mobility conduction band and low mobility impurity band. The threshold doping concentration for the dominance of the conduction band electrons is estimated to be about 1018 cm–3. 相似文献