Synthesis and relationships between the structures and properties of monodisperse star-shaped oligofluorenes

[structure: see text] A convenient approach to a series of star-shaped pi-conjugated organic materials with oligofluorenes (OF) as the branches and a benzene ring as the core has been developed. The optical properties of these materials are liable to be tuned by introduction of more fluorene rings. The investigation of the structure-property relationship of these materials has indicated differences between star-shaped oligofluorenes and linear oligofluorenes, as well as polyfluorenes.     

Some Congruences on S (X)

Some congruences on S (X) are investigated in this paper. A unique atom in the sublattice [C(E), C (E)] is determined for some spaces X and S-equivalences E and X.AMS Subject Classification (1991): 20M20 54H15     

Origin of antimony segregation in GaInSb/InAs strained-layer superlattices

We show how cross-sectional scanning tunneling microscopy may be used to reconstruct the Sb segregation profiles in GaInSb /InAs strained-layer superlattices. These profiles are accurately described by a one-dimensional model parametrizing the spatial evolution of an Sb seed at the InAs-on-GaInSb interface in terms of two-anion-layer exchange. We argue that the segregation seed, which decreases from 2 / 3 to 1 / 2 monolayer when growth conditions are made less anion rich, has its origin in the Sb-bilayer reconstruction maintained during GaInSb epitaxy.     

Homoclinic bifurcation in a Hodgkin-Huxley model of thermally sensitive neurons

We study global bifurcations of the chaotic attractor in a modified Hodgkin-Huxley model of thermally sensitive neurons. The control parameter for this model is the temperature. The chaotic behavior is realized over a wide range of temperatures and is visualized using interspike intervals. We observe an abrupt increase of the interspike intervals in a certain temperature region. We identify this as a homoclinic bifurcation of a saddle-focus fixed point which is embedded in the chaotic attractors. The transition is accompanied by intermittency, which obeys a universal scaling law for the average length of trajectory segments exhibiting only short interspike intervals with the distance from the onset of intermittency. We also present experimental results of interspike interval measurements taken from the crayfish caudal photoreceptor, which qualitatively demonstrate the same bifurcation structure. (c) 2000 American Institute of Physics.     

Berry phase and shot noise for spin-polarized and entangled electrons

Shot noise for entangled and spin-polarized states in a four-probe geometric setup has been studied by adding two rotating magnetic fields in an incoming channel. Our results show that the noise power oscillates as the magnetic fields vary. The singlet, entangled triplet and polarized states can be distinguished by adjusting the magnetic fields. The Berry phase can be derived by measuring the shot noise power.     

JLab Hall-A上小角度GDH实验中的粒子鉴别及其效率

在JLab的A大厅上的小角度GDH实验中, 因为散射截面及截面不对称度的测量需要干净的电子样本和足够的事例统计, 径迹在簇射量能器和气体阈契仑柯夫探测器理的信息被用来完成粒子鉴别的任务. 通过优化粒子在两种探测器里的信息筛选条件, 可以得到较高的电子接收效率和π的去除能力. 因为探测器的分辨能力与粒子的动量等运动学参量有关, 所以对于不同的数据的粒子鉴别条件分别进行了优化, 并得到了对应的电子接收效率和π的去除能力.     

Different responses of several kinds of copolymerized polyimide films to ultraviolet irradiation

The surfaces of three kinds of copolymerized polyimide films were irradiated by ultraviolet (UV) light. The chemical composition changes of the films after irradiation were investigated by X-ray photoelectron spectroscopy (XPS), while their topographical changes were studied by atomic force microscopy (AFM). Besides, the surface topographical variation induced changes in friction behavior were recorded on a DF·PM unidirectional friction and wear test rig in a ball on block contact configuration. It was found that photodegradation took place, which induced the chain scission of the polyimide molecules and formation of low molecular weight oxidized material (LMWOM). Due to different photostability of the three kinds of polyimide, different chemical composition changes and forms of “LMWOM” were observed. Also, different friction behavior variations of the three kinds of polyimide films were recorded. It is thought that the polyimide film of PI (PPA + PMDA) with rod-like structures might have stronger photo-resistance, whose form of “LMWOM” was “nodules” and whose friction coefficient increased at 2 h of irradiation possibly due to cross-linking. In the case of PI (OPA + PMDA) and PI (MPA + PMDA) films, they mainly underwent photodegradation, which might soften the surfaces and increased the friction coefficients with increasing irradiation time.     

A sharper uncertainty principle

The work strengthens the result established by L. Cohen on uncertainty principle involving phase derivative. We propose stronger uncertainty principles not only in the classical setting for Fourier transform, but also for self-adjoint operators. We also deduce the conditions that give rise to the equal relation of the uncertainty principle. Examples are provided to show that the new uncertainty principle is truly sharper than the existing ones in literature.     

The origin of the high performance of tungsten carbides/carbon nanotubes supported Pt catalysts for methanol electrooxidation

The Pt supported on WC modified MWCNT catalysts (PtWC/MWCNT) were synthesized by the combination of organic colloidal and intermittent microwave heating (IMH) methods for the first. The results proved the better performance of the PtWC/MWCNT catalyst than that of Pt/C for methanol oxidation in terms of the onset potential and peak current density. The synergistic effect between Pt nanoparticles and WC and the structure effect of the MWCNTs could be the reasons to result in the high activity. The CO stripping test provided the evidence that the onset potential shift for methanol oxidation is consistent with the reduction in the overpotential for the CO oxidation on PtWC/MWCNT catalyst. Therefore, the mechanism of the high performance for methanol oxidation on PtWC/MWCNT catalyst is probably the easier oxidation of CO-like species which cause high overpotential for further oxidation of methanol.