Photophysical and antimicrobial properties of new double-armed benzo-15-crown-5 ligands and complexes

Research on Chemical Intermediates - New double-armed crown ether ligands linked to pyridine derivatives have been synthesized and characterized. These macrocyclic ligands (1–5) have been...     

Raman lasing near 630 nm from stationary glycerol-water microdroplets on a superhydrophobic surface

We demonstrate, for the first time to our knowledge, Raman lasing from stationary microdroplets on a superhydrophobic surface. In the experiments, glycerol-water microdroplets with radii in the 11-15 microm range were pumped at 532 nm with a pulsed, frequency-doubled Nd:YAG laser. Two distinct operation regimes of the microdroplets were observed: cavity-enhanced Raman scattering and Raman lasing. In the latter case, the Raman lasing signal was higher than the background by more than 30 dB. Investigation of the Raman spectra of various glycerol-water mixtures indicates that lasing occurs within the glycerol Raman band. Raman lasing was not sustained; rather, oscillation would occur in temporally separated bursts. Increasing the rate of convective cooling by nitrogen purging improved the lasing performance and reduced the average interburst separation from 2.3 to 0.4 s.     

Synthesis,antimicrobial and thermal studies of nitropyridine-substituted double armed benzo-15-crown-5 ligands; alkali (Na+ and K+) and transition metal (Ag+) complexes; reduction of nitro compounds

Journal of Inclusion Phenomena and Macrocyclic Chemistry - Nitropyridine substituted double-armed benzo 15-crown-5 compounds (1–4) were synthesized by the reactions of...     

TSAI–TOKAD (T–T) Graph: The Combination of Non-oriented and Oriented Graphs for the Kinematics of Articulated Gear Mechanisms

The non-oriented and oriented linear graph techniques are used for the kinematic analysis of bevel-gear trains. In this paper, these two techniques are compared and the weaknesses of each technique are shown. In order to overcome the weaknesses of these techniques a new graphical technique called Tsai–Tokad (T–T) graph is introduced incorporating the important feature of the non-oriented graph which helps to determine the transfer vertex and the oriented graph technique. The theory is demonstrated by the kinematic analysis of articulated robotic mechanism used by Cincinnati Milacron T³     

The effect of nanoparticles on the surface hydrophobicity of polystyrene

The surface hydrophobicity of polystyrene-nanoparticle nanocomposites has been investigated as a function of the nanoparticle content. The addition of hydrophobically coated nanoparticles in polystyrene increased the contact angle θ of a water drop with respect to that on polystyrene surface due to change of surface composition and/or surface roughness. When the nanoparticles dispersed well in the polymer, cos θ decreased linearly with increasing amount of nanoparticles indicating a composite surface consisting of smooth polystyrene regions and rough nanoparticle regions. In case of formation of nanoparticle aggregates in polystyrene, cos θ decreased sharply at a critical concentration of nanoparticles. The observed behaviour was modeled in terms of a transition from Wenzel regime to Cassie-Baxter regime at a critical roughness length scale below which the Laplace pressure prevented the penetration of the water drop into the surface undulations. We argue that multiple length scales are needed below the critical roughness length scale to increase the contact angle further by decreasing the fraction of surface area of solid material (increasing the fraction of surface area of air) underlying the water drop.     

Generation of simulation input scenarios using bootstrap methods

Simulation modellers frequently face a choice between fidelity and variety in their input scenarios. Using an historical trace provides only one realistic scenario. Using the input modelling facilities in commercial simulation software may provide any number of unrealistic scenarios. We ease this dilemma by developing a way to use the moving blocks bootstrap to convert a single trace into an unlimited number of realistic input scenarios. We do this by setting the bootstrap block size to make the bootstrap samples mimic independent realizations in terms of the distribution of distance between pairs of inputs. We measure distance using a new statistic computed from zero crossings. We estimate the best block size by scaling up an estimate computed by analysing subseries of the trace.     

Simple Functors of Admissible Linear Categories

Generalizing an idea used by Bouc, Thévenaz, Webb and others, we introduce the notion of an admissible R-linear category for a commutative unital ring R. Given an R-linear category \(\mathcal {L}\), we define an \(\mathcal {L}\)-functor to be a functor from \(\mathcal {L}\) to the category of R-modules. In the case where \(\mathcal {L}\) is admissible, we establish a bijective correspondence between the isomorphism classes of simple functors and the equivalence classes of pairs (G, V) where G is an object and V is a module of a certain quotient of the endomorphism algebra of G. Here, two pairs (F, U) and (G, V) are equivalent provided there exists an isomorphism F ← G effecting transport to U from V. We apply this to the category of finite abelian p-groups and to a class of subcategories of the biset category.     

Comparative mechanical property characterization of three indirect composite resin materials compared with two direct composites

Various new indirect composite materials have been developed with required advantages. In this study three indirect composite material (Artglass, Belleglass HP, Targis) were tested for flexural strength, fracture toughness, wear resistance and hardness against Filtek P60 and Z‐100. Five specimens of each material were fabricated according to the manufacturer's directions. The flexural strength and fracture toughness was measured using the bending test. The wear test was performed to accelerated wear in a toothbrushing apparatus. Vickers hardness was measured for each of the tested materials. The statistical tests used for flexural strength, fracture toughness, wear and hardness were One‐way ANOVA and Kruskal–Wallis test. The level of statistical significance chosen was p = 0.05. Results of the study showed that Filtek P60 was superior to the other composites in all tests. Significant differences were found among the materials. The differences in flexural strength, fracture toughnes, wear and hardness may have been due to differences in chemistry or method of polymerization of the composites. Copyright © 2003 John Wiley & Sons, Ltd.     

Spatially organized free-standing poly(p-xylylene) nanowires fabricated by vapor deposition

Thin films of poly(chloro-p-xylylene) (PPXC) grown by the pyrolysis and evaporation of chloro-[2.2]paracyclophane in an evacuated chamber contain free-standing, slanted, parallel columns that are 50 mum long and are assemblies of 50- to 100-nm-diameter nanowires, which thus can have an unprecedented aspect ratio as high as 1000:1. The nanostructured thin films organize spatially with a chemical structure similar to that of planar PPXC thin films, but the former also possess nanostructured morphology. Nanostructured thin films of poly(p-xylylene) (PPX) and its derivatives shall be useful as functionalized interfaces for antifouling coatings and biomedical devices.