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排序方式: 共有322条查询结果,搜索用时 15 毫秒
31.
Zeinab Noroozi TissehFereshteh Ahmadi Minoo DabiriHamid Reza Khavasi Ayoob Bazgir 《Tetrahedron letters》2012,53(28):3603-3606
A practical, simple, and efficient method for the synthesis of pyrano-fused spirooxindoles via an organocatalytic three-component reaction of isatins, malononitrile, and dialkyl acetylenedicarboxylate in the presence of 3,4-dimethylaniline as an organocatalyst in ethanol is reported. The structures of these products are confirmed by IR, 1H NMR and 13C NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction studies. 相似文献
32.
Bahareh Sadeghi Mohammad Maleki Zeinab Kamali Homa Almasieh 《Numerical Methods for Partial Differential Equations》2023,39(2):1652-1671
Advection equations with delay are appeared in the modeling of the dynamics of structured cell populations. In this article, we construct an efficient two-dimensional multistep collocation method for the numerical solution of a class of advection equations with delay. Equations with aftereffect and equations with both aftereffect and retardation of a state variable are considered. Computability of the algorithm and convergence properties of the proposed numerical method are analyzed for solutions in appropriate Sobolev spaces, and it is shown that the proposed scheme enjoys the spectral accuracy. Numerical examples are given and comparison with other existing methods in the literature is made to demonstrate the efficiency, superiority and high accuracy of the presented method. 相似文献
33.
This work is an investigation on the roots of chaotic attitudinal motion in a class of asymmetrical gyrostat satellites. The result shows that for a class of Kelvin type gyrostat satellite, there is an equivalent rigid spinning satellite with the same attitude dynamics. Finding some constants of motion and eliminating the cyclic coordinates, the rotational kinetic energy is changed to a quadratic form and using Jordan canonical form of the associated inertia tensor and transforming the coordinate system, the Hamiltonian has been changed to those of a rigid satellite. The Hamiltonian has been split into integrable and non-integrable parts. Using Deprit canonical transformation and Andoyer variables the integrable part has been reduced to a one-dimensional form. The reduced Hamiltonian shows that the regular dynamics of the satellite can be chaotic, under the influence of gravitational effects. To demonstrate various attitudinal dynamics of the satellite, a second-order Poincaré map is employed. This research shows firstly, that the attitudinal dynamics of Kelvin type gyrostat satellites and rigid satellites follow the same dynamical patterns, secondly, for non-linear analysis of dynamics of gyrostat satellite based on the perturbation methods, there is a preferable form for Hamiltonian of the system in the near-integrable fashion and thirdly the chaotic motion is originated from the gravitational field effects that can be suppressed by increasing the attitudinal energy of the satellite in comparison with the translational energy. 相似文献
34.
A novel, cost‐effective, and simple electrocatalyst based on a Pt‐modified glassy carbon electrode (GCE), using cetyltrimethylammonium bromide (CTAB) as a cationic surfactant, is reported. Am‐phiphilic... 相似文献
35.
Zeinab Ansari-Asl Tahereh Sedaghat Abbas Tarassoli Hossein Motamedi Elham Hoveizi 《Phosphorus, sulfur, and silicon and the related elements》2017,192(5):538-543
Three new water-soluble organotin complexes R2Sn(5-BrSalGT)Cl [R = Ph, Me] and Ph2Sn(2-OHNaphGT)Cl have been synthesized by the reaction of R2SnCl2 (R = Ph or Me) with Schiff bases derived from condensation of Girard-T reagent with 5-bromosalicylaldehyde and 2-naphthaldehyde, (5-BrH2SalGT)Cl (1) and (2-OHH2NaphGT)Cl (2). The synthesized compounds have been investigated by elemental analysis, conductometric measurements, IR, 1H NMR, and 119Sn NMR spectroscopy. These data show that the deporotonated ligand is coordinated to Sn(IV) via ONO atoms and six-coordinate zwitterionic complexes are formed. The ligands and their complexes were investigated for their in vitro toxicity against Gram-positive (Bacillus subtilis and Staphylococcus aureus) and Gram-negative (Escherichia coli and Pseudomonas aeruginosa) bacteria. The results show remarkable antibacterial activity against the studied bacteria. All complexes exhibit more inhibitory effects than the parent ligand. The anticancer activity of all compounds were also performed on HN5 cell line and (2-OHH2NaphGT)Cl with concentration of 1 mg mL?1 was found to show higher anticancer activity than other compounds. 相似文献
36.
Fatemeh Shahangi Shirazi Kamran Akhbari 《Journal of the Iranian Chemical Society》2017,14(7):1519-1525
By considering the structure of one-dimensional pencil-shaped organometallic coordination polymer that was previously reported, we designed and synthesized [Na(μ2-Hdcpa)(μ3-dcpa)] n (1), [Hdcpa = 2,4-dichlorophenoxyacetic acid], which has one-dimensional pencil-shaped structure too. The Na atoms are surrounded with the aromatic phenyl rings of Hdcpa similar to graphite of a pencil. Metalophilic interactions also exists in 1 between Na(I) ions similar to argentophilic interaction in our previous compound which results in formation of chain structure similar to graphite structure of a pencil. Compound 1 nanorods were formed under ultrasonic irradiation and applied as template to fabricate sodium chloride nanorods. The interesting feature of our work is the formation of sodium chloride nanorods from compound 1 nanorods which have one-dimensional structure in the solid state. 相似文献
37.
Olusegun S. Ajala Andrew M. PiggottFabien Plisson Zeinab KhalilXiao-cong Huang Sunday A. AdesegunHerbert A.B. Coker Robert J. Capon 《Tetrahedron letters》2011,52(52):7125-7127
Chemical investigations into samples of Hunteria umbellata (K. Schum) collected in Osun State, Nigeria, led to the discovery of a new indole alkaloid, ikirydinium A, featuring an unprecedented 3-alkylpyridinium-indole-2-carboxylate scaffold. Ikirydinium A was found to exhibit antimicrobial activity (IC50 0.6 μM) against Bacillus subtilis ATCC 6051. The involvement of a common intermediate in the biosynthesis of ikirydinium A and vinblastine is hypothesized. 相似文献
38.
Hosseinidoust Z Van de Ven TG Tufenkji N 《Langmuir : the ACS journal of surfaces and colloids》2011,27(9):5472-5480
The rise of antibiotic-resistant bacteria has directed substantial attention toward the use of bacteriophages as a means to control bacterial populations. It has been proposed that bacteriophages can be applied as a coating on surfaces in healthcare settings or on indwelling medical devices to create an antimicrobial surface. In this study, antimicrobial model surfaces functionalized with five different types of bacteriophage were prepared and characterized with X-ray photoelectron spectroscopy and atomic force microscopy. The bacterial capture efficiency of these functionalized surfaces was studied for two common bacteria, Escherichia coli and Salmonella typhimurium. Binding of the phages to a solid surface affected their biofunctionality as expressed by the capture efficiency and rate of host membrane disruption. Moreover, the size and shape of the bacteriophage and positioning of its specific binding proteins significantly affected its bacterial capture capability in the immobilized state. Symmetric bacteriophages were found to be a better choice for antibacterial surfaces compared to more asymmetric tailed bacteriophages. Immobilized phages were found to disrupt the membranes of attached bacteria and are thus proposed as a candidate for antimicrobial surfaces. 相似文献
39.
NiO nanoparticles with an average size of 15 nm were easily prepared via the thermal decomposition of the tris(ethylenediamine)Ni(II) nitrate complex [Ni(en)3](NO3)2 as a new precursor at low temperature, and the nanoparticles were characterized by thermal analysis (TGA/DTA), X-ray diffraction (XRD), Fourier-transformed infrared spectroscopy (FT-IR), UV-Vis spectroscopy, BET specific surface area measurement, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and magnetic measurements. The magnetic measurements confirm that the product shows a ferromagnetic behavior at room temperature, which may be ascribed to a size confinement effect. The NiO nanoparticles prepared by this method could be an appropriate photocatalytic material due to a strong absorption band at 325 nm. This method is simple, fast, safe, low-cost and also suitable for industrial production of high purity NiO nanoparticles for applied purposes. 相似文献
40.
Copper(II) complex of a Schiff base ligand derived from pyrrolcarbaldehyde and o‐phenylenediamine (H2L) has been synthesized and encapsulated in Y‐zeolite matrix. The hybrid material has been characterized by elemental analysis, IR and UV‐Vis spectroscopic studies as well as X‐ray diffraction (XRD) pattern. The encapsulated copper(II) catalyst is an active catalyst for the oxidation of cyclooctene and cyclohexene using H2O2 as oxidant. Under the optimized reaction conditions 81% conversion of cyclohexene with 65% selectivity for 2‐cyclohexenone formation and 87% conversion of cyclooctene with 46% selectivity for epoxide formation were obtained. 相似文献