双全纯映射和对称典型域

两个域是否双全纯等价是多复变函数的一个基本问题．证明了对称典型域不能双全纯等价于具光滑边界的有界强拟凸域除非本身是一个具光滑边界的有界强拟凸域．     

化学法修饰碳纳米管

综述了化学法修饰碳纳米管表面反应的研究进展,从酸化及其衍生反应、环加成反应、氟化反应、原子转移自由基聚合反应、卡宾加成反应等几种反应入手着重介绍了碳纳米管表面修饰的方法和研究状况。     

石墨烯及石墨烯/氮化硼的电子结构特性研究

化学气相沉积法生长的单层石墨烯具有卓越的力学、热学和电学特性,成为新一代纳米器件的首选材料。对石墨烯电子特性的理论研究有利于推动纳米器件的发展与应用。本文基于密度泛函理论与非平衡格林函数相结合的方法,系统地研究了石墨烯及石墨烯/氮化硼的电子结构特性。结果表明,在高对称K点,带隙为零。在50~400 K范围内,由于费米面的电声子散射作用,单层石墨烯的迁移率随着温度增加呈现显著下降趋势。此外,通过对不同层间距的石墨烯/氮化硼结构的能带、态密度、电子密度等特性分析,发现随着层间距增加,能带间隙减小,导带与价带间的能量差减小。随着原子个数的增加,石墨烯/氮化硼超胞结构与原胞结构的带隙开度变化规律一致,这对石墨烯基器件的结构设计具有一定的指导意义。     

Enhancing the Performance of Evolutionary Algorithm by Differential Evolution for Optimizing Distillation Sequence

Optimal synthesis of distillation sequence is a complex problem in chemical processes engineering, which involves process structure optimization and operation parameters optimization. The study of the synthesis of distillation sequence is a crucial step toward improving the efficiency of chemical processes and reducing greenhouse gas emissions. This work introduced the concept of binary tree to encode the distillation sequence. The performance of the six evolutionary algorithms was evaluated by solving a 14-component distillation sequence synthesis problem. The best algorithm was used to optimize the operation parameters of a triple-column distillation process. The total annual cost and CO₂ emissions were considered as the metrics to evaluate the performance of triple-column distillation processes. As a result, NSGA-II-DE was found to be the best one of the six tested evolutionary algorithms. Then, NSGA-II-DE was applied to the distillation sequence optimization to find the best operating parameters, which led to a significant reduction in CO₂ emission and total annual costs.     

半微观质子光学势

基于原子核壳模型单体密度矩阵的折叠模型计算光学势的实部,配以唯象光学势虚部,构造半微观光学势.通过拟合质子弹性散射实验数据,得到适用于质量数28~90,能量到200 MeV的半微观质子光学势.该光学势用于质子弹性散射计算分析,在参数大为减少的情况下,计算得到的角分布和分析本领与实验数据的符合程度,总体上好于Koning-Delaroche普适光学势的计算结果.     

Synthesis of Chiral Triarylmethanes Bearing All-Carbon Quaternary Stereocenters: Catalytic Asymmetric Oxidative Cross-Coupling of 2,2-Diarylacetonitriles and (Hetero)arenes

A direct and enantioselective oxidative cross-coupling of racemic 2,2-diarylacetonitriles with electron-rich (hetero)arenes has been described, which allows for efficient construction of triarylmethanes bearing all-carbon quaternary stereocenters with excellent chemo- and enantioselectivity. The reaction has an excellent functional group tolerance, and exhibits a broad scope with respect to both 2,2-diarylacetonitrile and (hetero)arene components. The rich chemistry of the cyano group allows for facile synthesis of other valuable chiral triarylmethanes bearing all-carbon quaternary centers that are otherwise difficult to access.     

原子核壳模型单体密度矩阵的数值计算

提出平均场壳模型下原子核单体密度矩阵的一种计算方法,验证该方法的可靠性.计算双幻核⁴⁰Ca,⁹⁰Zr的单体密度矩阵,利用单体密度矩阵计算核子密度分布和动量分布,并分别与Hartree-Fock-Bogolubov理论结果、定域费米气体模型结果以及实验数据进行比较.     

耐久型超疏水表面:理论模型、制备策略和评价方法

超疏水材料以其独特的润湿性在日常生活和工业领域都展示出广阔的应用前景,但其表面的微纳米结构和低表面能物质易受到机械摩擦或化学侵蚀而失去超疏水性。当前诸多报道都采用微纳结构设计和表面优化来延长超疏水材料的耐久性,以期提升其商业价值。本文先从表面浸润模型出发,包括经典理论、亚稳态理论和接触线理论,梳理了超疏水理论模型的发展脉络,阐明这些理论在超疏水耐久性设计上发挥的关键指导作用。接着对微纳米结构设计、胶黏+涂装、铠装防护、自修复和气膜修补等延长超疏水耐久性的制备策略进行了总结,并对不同制备策略各自的优势和局限性进行简要评述。本综述还从机械稳定性和化学稳定性两方面汇总了超疏水耐久性的快速评价手段,讨论了提升超疏水表面耐久性所遇到的问题,并展望了超疏水材料的发展前景,以期助力长效超疏水材料的研发和应用。     

Multitarget Detection Using a Fringe adjusted and Power Spectrum Subtracted Hybrid Optical Joint Transform Correlator

１ＩｎｔｒｏｄｕｃｔｉｏｎＦｏｒｏｐｔｉｃａｌｐａｔｅｒｎｒｅｃｏｇｎｉｔｉｏｎ,ｔｈｅｊｏｉｎｔｔｒａｎｓｆｏｒｍｃｏｒｅｌａｔｏｒ［１］（ＪＴＣ）ｉｓｍｏｒｅｓｕｉｔａｂｌｅｆｏｒｒｅａｌｔｉｍｅｏｐｔｉｃａｌｐａｔｅｒｎｒｅｃｏｇｎｉｔｉｏｎａ...