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21.
The chemical behavior and some physical properties (dipole moment, IR. vs. Raman spectra) of the titled compound are not fully consistent with a strictly centrosymmetric structure which might be expected for the anti configuration. The carbonyl groups are less reactive toward nucleophilic reagents and sp2 → sp3 transformations as compared to cyclopentanone systems. 相似文献
22.
Recently, unusual giant magnetic properties were found experimentally in some organized organic monolayers adsorbed on solid substrates. A model is presented which explains the observed phenomenon. The model is based on the special properties of electrons transferred from the substrate to the layer as a result of the adsorption process. Triplet pairing of those electrons is forced by the special 2D properties of the organic layer. Such pairs are confined within domains in the organic layer and their quantum statistics provide a model that explains the unique magnetization as well as all other features of the experimental observations. The model suggests the possible existence of Bose-Einstein condensation at room temperature on the scale of the domains. 相似文献
23.
Mauro L. Bonardi Flavia Groppi Simone Manenti Elisa Persico Luigi Gini Kamel Abbas Uwe Holzwarth Federica Simonelli Zeev B. Alfassi 《Journal of Radioanalytical and Nuclear Chemistry》2010,286(1):1-7
Very high specific activity (AS) 186gRe could be produced by either proton or deuteron cyclotron irradiation on highly enriched 186W target in no-carrier-added (NCA) form, leading to a AS very close to the theoretical carrier free (CF) value of 6.88 GBq μg−1. Thick Target Yields (TTYs), obtained irradiating both thick metal W targets of natural isotopic composition and highly enriched
powdered 186W targets, were measured at different particles energies taking into account high accuracy and precision. The evaluation of
radionuclidic purities of 186gRe obtained activating highly enriched 186W by both p and d were also carried out and accurately compared. The thin-target excitation functions for all Re (A = 181,
182, 183, 184, 186 and their metastable levels), and W and Ta coproduced radionuclides will be presented elsewhere in deep
details. 相似文献
24.
The capability to classify, recognize and to identify objects from spatially low resolution images has high significance in security related applications especially in a case that recognition of camouflaged object is required.In this paper we present a novel approach in which the scenery containing obscured objects which we wish to classify, recognize or identify is illuminated by spatially coherent beam (e.g. laser) and therefore secondary speckles pattern is reflected from the objects. By special image processing algorithm developed for this research and which is basically based upon temporal tracking of the random speckle pattern one may extract the temporal signature of the object. And right after, to use it for its classification (e.g. its separation from the other objects in the scenery), its recognition and identification even in a case that the imager provides poor spatial resolution that by itself does not allow doing the specified detection related operations. 相似文献
25.
Given a (directed or undirected) graph with edge costs, the power of a node is the maximum cost of an edge leaving it, and the power of the graph is the sum of the powers of its nodes. Motivated by applications for wireless networks, we present polynomial and improved approximation algorithms, as well as inapproximability results, for some classic network design problems under the power minimization criteria. Our main result is for the problem of finding a min-power subgraph that contains k internally-disjoint vs-paths from every node v to a given node s: we give a polynomial algorithm for directed graphs and a logarithmic approximation algorithm for undirected graphs. In contrast, we will show that the corresponding edge-connectivity problems are unlikely to admit even a polylogarithmic approximation. 相似文献
26.
Mergers are functions that transform k (possibly dependent) random sources (distributions) into a single random source, in a way that ensures that if one of the input sources has min‐entropy rate δ then the output has min‐entropy rate close to δ. Mergers have proven to be a very useful tool in explicit constructions of extractors and condensers, and are also interesting objects in their own right. In this work we give a refined analysis of the merger constructed by [Raz, STOC'05] (based on [Lu, Reingold, Vadhan, and Wigderson, STOC'03 pp. 602–611, 2003]). Our analysis uses min‐entropy instead of Shannon's entropy to derive tighter results than the ones obtained in [Raz STOC'05]. We show that for every constant r and k it is possible to construct a merger that takes as input k strings of length n bits each, and outputs a string of length n/r bits, such that if one of the input sources has min‐entropy b, the output will be close to having min‐entropy b/(r + 1). This merger uses a constant number of additional uniform bits. One advantage of our analysis is that b (the min‐entropy of the “good” source) can be as small as a constant (this constant depends on r and k), while in the analysis given in [Raz STOC'05], b is required to be linear in n. © 2007 Wiley Periodicals, Inc. Random Struct. Alg., 2008 相似文献
27.
Aviram Gur Zeev Zalevsky Vladimir G. Kutchoukov Javier Garcia 《Optics Communications》2011,284(14):3509-3517
We present a novel concept for microscopic imaging. The proposed microscope-like device does not include an objective lens neither a condenser. Instead, a metallic plate of sub-wavelength hole-array with a varying pitch is used to illuminate the inspected object that is mounted very close to it. As a result, the transmitted spectrum through each hole differs from the others and therefore, each spot of the detected object is illuminated with a unique spectrum. By measuring a single spectrum that is the sum of all the spectra that are transmitted through the sample and by using spectral decomposition algorithms, the spatial transmission pattern of the object can be extracted. 相似文献
28.
A dual-Vivaldi nanoantenna is proposed to demonstrate the possibility of wideband operation at IR frequencies. The antenna geometry design is guided by the material properties of metals at IR frequencies. According to our numerical results, this nanoantenna has both high radiation efficiency and good impedance-matching properties over a wide frequency band (more than 122%) in the IR frequency band. The design is based on the well-known Vivaldi antenna placed on quartz substrate but operating as a pair instead of a single element. Such a pair of Vivaldi antennas oriented in opposite directions produces the main lobe in the broadside direction (normal to the axes of the antennas) rather than the usual peak gain along the axis (end fire) of a single Vivaldi antenna. The dual-Vivaldi nanoantenna is easy to fabricate in a conventional electron-beam lithography process, and it provides a large number of degrees of freedom, facilitating design for ultra-wideband operation. 相似文献
29.
Whereas periodic gratings enable us to couple light into a surface plasmon polariton only at a specific angle and wavelength, we show here that quasiperiodic gratings enable the coupling of light at multiple wavelengths and angles. The quasiperiodic grating can be designed in a systematic manner using the dual-grid method, thereby enabling us to control the coupling strength and grating dimensions. We verified the method experimentally by efficiently coupling light into a surface plasmon from several different illumination angles using a single quasiperiodic grating. 相似文献
30.
Philip Rosenau Zeev Schuss 《Physics letters. A》2011,375(5):891-897
The standard derivation of Schrödinger's equation from a Lorentz-invariant Feynman path integral consists in taking first the limit of infinite speed of light and then the limit of short time slice. In this order of limits the light cone of the path integral disappears, giving rise to an instantaneous spread of the wave function to the entire space. We ascribe the failure of the propagation in time according to Schrödinger's equation to retain the light cone of the path integral to the very nature of the limiting process: it is a regular expansion of a singular approximation problem, because the time-dependent boundary conditions of the path integral on the light cone are lost in this limit. We propose a distinguished limit of the time-sliced relativistic path integral, which produces Schrödinger's equation and preserves the zero boundary conditions on and outside the original light cone of the path integral. This produces an intermediate model between non-relativistic and relativistic mechanics of a single particle quantum particle. These boundary conditions relieve the solutions of Schrödinger's equation in the entire space of several annoying, seemingly unrelated unphysical artifacts, including non-analytic wave functions, spontaneous appearance of discontinuities, non-existence of moments when the initial wave function has a jump discontinuity (e.g., a collapsed wave function after a measurement), and so on. The practical implications of the present formulation are yet to be seen. 相似文献