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991.
992.
J. Smyrski H.-H. Adam A. Budzanowski E. Czerwiski R. Czyykiewicz D. Gil D. Grzonka M. Janusz L. Jarczyk B. Kamys A. Khoukaz P. Klaja P. Moskal W. Oelert C. Piskor-Ignatowicz J. Przerwa J. Ritman T. Roek T. Sefzick M. Siemaszko A. Tschner P. Winter M. Wolke P. Wüstner W. Zipper 《Nuclear Physics A》2007,790(1-4):438c-441
993.
Lilianna Chciska Lesaw Siero Maria Bukowska‐Strzyewska Zbigniew H. Kudzin Lszl Fbin 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(1):o46-o50
The structures of diphenyl [3‐methyl‐1‐(3‐phenylthioureido)butyl]phosphonate and diphenyl [2‐methyl‐1‐(3‐phenylthioureido)butyl]phosphonate, both C24H27N2O3PS, are reported. In both compounds, the thiourea moiety adopts a syn–syn conformation (i.e. the S—C—N—C torsion angles are synperiplanar), which enables N—H⋯O hydrogen bonds to be formed between centrosymmetrically related molecules. The geometries around the P atoms can be described as distorted tetrahedral. Some of the functional groups in each structure are disordered. The bulk of the different alkyl substituents between the amide and phosphonate groups influences the molecular conformation and crystal packing. Although the structures of these compounds and two related derivatives appear to be similar, they are not isostructural. 相似文献
994.
Main mechanisms of tough response of polymers are described. In heterogeneous polymer systems due to mechanical misfit between heterogeneities and the matrix a high negative pressure (tri-axial stress) is generated. The excessive negative pressure is the main reason of material cavitation. Cavitation appears to be another mechanism of tough response of the material to loading. Cavitation is a massive phenomenon in crystalline polymers and in all filled polymers. Cavitation itself does not consume much energy but allows for further toughening by activating other mechanisms. Examples of polypropylene filled with chalk modified by liquid, rubber and mineral filled polypropylene and syndiotactic polypropylene filled with chalk are described. Modes of deformation with significant compressive component of stress prevents for cavitation. Materials deformed in a cavity-free manner show much higher strength. It is pointed out that high polymer crystal anisotropy is necessary for the formation of a network of easy crystallographic slip in the unusual toughening of highly filled polymers observed recently. An example of syndiotactic polypropylene filled with submicro-chalk particles is presented. 相似文献
995.
Monika Kijewska Dorota Gszczyk Remigiusz Bchor Piotr Stefanowicz Zbigniew Szewczuk 《Molecules (Basel, Switzerland)》2021,26(22)
Peptide modification by a quaternary ammonium group containing a permanent positive charge is a promising method of increasing the ionization efficiency of the analyzed compounds, making ultra-sensitive detection even at the attomolar level possible. Charge-derivatized peptides may undergo both charge remote (ChR) and charge-directed (ChD) fragmentation. A series of model peptide conjugates derivatized with N,N,N-triethyloammonium (TEA), 1-azoniabicyclo[2.2.2]octane (ABCO), 2,4,6-triphenylopyridinium (TPP) and tris(2,4,6-trimetoxyphenylo)phosphonium (TMPP) groups were analyzed by their fragmentation pathways both in collision-induced dissociation (CID) and electron-capture dissociation (ECD) mode. The effect of the fixed-charge tag type and peptide sequence on the fragmentation pathways was investigated. We found that the aspartic acid effect plays a crucial role in the CID fragmentation of TPP and TEA peptide conjugates whereas it was not resolved for the peptides derivatized with the phosphonium group. ECD spectra are mostly dominated by cn ions. ECD fragmentation of TMPP-modified peptides results in the formation of intense fragments derived from this fixed-charge tag, which may serve as reporter ion. 相似文献
996.
997.
Magdalena Szumera Barbara agowska Justyna Suowska Piotr Jele Zbigniew Olejniczak Radosaw Lach Anna Berezicka Agnieszka Kijo-Kleczkowska 《Molecules (Basel, Switzerland)》2022,27(3)
Glasses and devitrificates from the SiO2–B2O3–P2O5–K2O–CaO–MgO system with constant contents of SiO2 and P2O5 network formers, modified by the addition of B2O3, were analyzed. All materials were synthesized by the traditional melt-quenching technique. The glass stability (GS) parameters (Krg, ∆T, KW, KH) were determined. The effect of the addition of B2O3 on the GS, liquation phenomenon, crystallization process, and the type of crystallizing phases were examined using SEM-EDS, DSC, XRD, and Raman spectroscopy imaging methods. It was observed that the addition of B2O3 increased the tendency of the glass to crystallize. Both phosphates (e.g., Ca9MgK(PO4)7, Mg3Ca3(PO4)4), and silicates (e.g., K2Mg5(Si12O30), CaMg(Si2O6), MgSiO3) crystallized in the studied system. The Raman spectrum for the orthophosphate Mg3Ca3(PO4)4 stanfieldite type was obtained. Boron ions were introduced into the structures of crystalline compounds at high crystallization temperatures. The type of crystallizing phases was found to be related to the phenomenon of liquation, and the order of their occurrence was dependent on the Gibbs free enthalpy. 相似文献
998.
The mechanistic aspects of the β-lactones anionic polymerization initiated by both classical initiators, i.e. alkali metal alkoxides, and non-traditional ones, such as supramolecular complexes of alkali metals and alkali metal naphthalenes, are discussed in this paper. 相似文献
999.
Zbigniew J. Jedliski Piotr Kurcok Farhod Nozirow 《Macromolecular rapid communications》1997,18(6):483-490
Structure and properties of poly(methylphenylsilane) synthesized by reductive coupling of silyl halides with alkali metal supramolecular complexes: (Mt+/18-crown-6, Mt−, where Mt = K, Na; 18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane) were investigated. The coupling process yields polymers exhibiting narrow molecular weight distribution and number-average molecular weights up to 8 500, cyclic oligomers being formed along with linear ones. 相似文献
1000.
Aluminoxane catalysts and anionic initiators can polymerize 3-butyrolactone, 3-BL, to high molecular weight stereoregular polymers. With the racemic monomer, [R,S]-3-BL, anionic polymerization with alkali metal complexes can form syndiotactic polymers and aluminoxane catalysts can form either highly isotactic, syndiotactic, or atactic poly-3-butyrolactone, P-3-BL, depending on the composition and method of preparation of the aluminoxane and the conditions of polymerization. 相似文献