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31.
Adolfo Zavelani-Rossi 《Meccanica》1974,9(4):312-324
Summary Limit analysis of plane structures is formulated by applying a finite element linear programming technique that was previously proposed by the same author.Three different element models are considered: the constant stress compatible model, the linear stress equilibrium model, the quadratic stress equilibrium model. Some notes are devoted to the construction of the stress fields with reference to the adopted method.Some suitably chosen numerical applications are then proposed in order to compare the different approaches as far as numerical efficiency and result accuracy are concerned. The possibility of improving the linear programming procedure is also discussed, and in particular a method is proposed to find out an initial feasible vector on the basis of mechanical considerations, in order to overcome the necessity of the so-called M-phase of the simplex method.Numerical results are given together with the comments.
Research supported by the C.N.R. (Italian National Research Council). 相似文献
Sommario Si formula il problema dell'analisi limite di strutture piane secondo un metodo degli elementi finiti già proposto dall'autore.Nel presente lavoro vengono considerati tre diversi modelli di elementi e precisamente: il modello congruente a sforzo costante e quelli equilibrati a campi di sforzo lineare e quadratico. La costruzione dei tre modelli viene presentata in dettaglio nell'ambito del metodo adottato.Vengono quindi presentati alcuni esempi di applicazione opportunamente scelti, con lo scopo di confrontare l'efficienza numerica e l'accuratezza di risultati ottenuti con l'impiego dei tre modelli. Si discute inoltre la possibilità di migliorare l'efficacia dell'algoritmo matematico ed in particolare si suggerisce un metodo che, individuando una soluzione ammissibile di partenza sulla scorta di considerazioni meccaniche, permette di evitare la cosiddetta fase M della programmazione lineare.I commenti sono accompagnati dai risultati numerici.
Research supported by the C.N.R. (Italian National Research Council). 相似文献
32.
Carbone M Li Y Irace C Mollo E Castelluccio F Di Pascale A Cimino G Santamaria R Guo YW Gavagnin M 《Organic letters》2011,13(10):2516-2519
Two indole alkaloids, phidianidines A (1) and B (2), exhibiting an uncommon 1,2,4-oxadiazole ring linked to the indole system, have been isolated from the marine opisthobranch mollusk Phidiana militaris. The structures of the two metabolites have been elucidated by spectroscopic techniques. Phidianidines exhibit high cytotoxicity against tumor and nontumor mammalian cell lines in in vitro assays. 相似文献
33.
Antognazza MR Scotognella F Miszta K Dorfs D Zanella M Zavelani-Rossi M Manna L Lanzani G Tassone F 《Physical chemistry chemical physics : PCCP》2011,13(33):15326-15330
Colloidal branched nanocrystals have been attracting increasing attention due to evidence of an interesting relationship between their complex shape and charge carrier dynamics. Herein, continuous wave photoinduced absorption (CW PIA) measurements of CdSe/CdS octapod-shaped nanocrystals are reported. CW PIA spectra show strong bleaching due to the one-dimensional (1D) CdS pod states (480 nm) and the zero-dimensional (0D) CdSe core states (690 nm). The agreement with previously reported ultrafast pump-probe experiments indicates that this strong bleaching signal may be assigned to state filling. Additional bleaching features at 520 and 560 nm are characterized by a longer lifetime and are thus ascribed to defect states, localized at the pod-core interface of the octapod, showing that some of the initially photogenerated carriers get quickly trapped into these long-lived defect states. However, we remark that a relevant part of electrons remain untrapped: this opens up the opportunity to exploit octapod shaped nanocrystals in photovoltaics applications, as electron acceptor materials, considering that several efficient hole extracting materials are already available for the realization of a composite bulk heterojunction. 相似文献
34.
Bolognesi M Sánchez-Díaz A Ajuria J Pacios R Palomares E 《Physical chemistry chemical physics : PCCP》2011,13(13):6105-6109
Organic polymer solar cells (OPSCs) have been prepared using TiO(x) metal oxides as selective electrodes for electron collection. The interfacial charge transfer reactions, under working conditions, that limit the energy conversion efficiency of these devices have been measured and compared to the standard OPSC geometry which collects the electrons through a low work function metal contact. 相似文献
35.
Francesca Cioffi Paolo Lella Maria Grazia Marinari Margherita Roggero 《Discrete Mathematics》2011,(20):2238
Using results obtained from a study of homogeneous ideals sharing the same initial ideal with respect to some term order, we prove the singularity of the point corresponding to a segment ideal with respect to a degreverse term order (as, for example, the degrevlex order) in the Hilbert scheme of points in Pn. In this context, we look into the properties of several types of “segment” ideals that we define and compare. This study also leads us to focus on the connections between the shape of generators of Borel ideals and the related Hilbert polynomial, thus providing an algorithm for computing all saturated Borel ideals with a given Hilbert polynomial. 相似文献
36.
37.
In this paper we are interested in gaining local stability insights about the interior equilibria of delay models arising in biomathematics. The models share the property that the corresponding characteristic equations involve delay-dependent coefficients. The presence of such dependence requires the use of suitable criteria which usually makes the analytical work harder so that numerical techniques must be used. Most existing methods for studying stability switching of equilibria fail when applied to such a class of delay models. To this aim, an efficient criterion for stability switches was recently introduced in [E. Beretta, Y. Kuang, Geometric stability switch criteria in delay differential systems with delay dependent parameters, SIAM J. Math. Anal. 33 (2002) 1144–1165] and extended [E. Beretta, Y. Tang, Extension of a geometric stability switch criterion, Funkcial Ekvac 46(3) (2003) 337–361]. We describe how to numerically detect the instability regions of positive equilibria by using such a criterion, considering both discrete and distributed delay models. 相似文献
38.
39.
Margherita Barile Gennady Lyubeznik 《Proceedings of the American Mathematical Society》2005,133(11):3199-3209
We describe a class of toric varieties which are set-theoretic complete intersections only over fields of one positive characteristic .
40.
Margherita Albano Emma Barchiesi Roberto Biancardi Marco Dossi Giuliana Geniram Paola Vaccarono 《Macromolecular Symposia》2013,324(1):41-48
Summary: In this work an investigation of the chain end groups produced in the free radical copolymerization of vinilydene fluoride (VDF) and hexafluoropropylene (HFP) is performed. Type and amount of chain end groups are evaluated by a meticulous analytical characterization of VDF/HFP copolymer. At first pulsed gradient spin-echo nuclear magnetic resonance (spin-echo NMR) is used to identify all the chain end groups also at very low concentration (equal to 0.1 mmol · Kg−1). The instrument sensitivity is increased of an order of magnitude in comparison with the traditional NMR. Moreover potentiometric titration and ion chromatography (IC) are also used to study the chain end groups and, as a consequence, the nature and the amount of the acidity showed by the polymer chains. In details two intensity of acidity are detected by potentiometric titration, namely strong and weak. The strong acidity is associated to the presence of residual surfactant and can be removed washing the polymer, while the weak acidity is due to free molecules of fluoride acid (HF). The standard ion chromatography facility is properly modified to quantify the fluoride in the polymer matrix without any pre extraction in water. Thanks to this the HF concentration in the polymer is evaluated with high accuracy. A detailed kinetic scheme for the VDF/HFP polymerization is also proposed taking into account all the findings obtained studying the chain end groups. 相似文献