Control of flow separation from a model wing at low Reynolds numbers

The results of an experimental investigation of the structure of the flow separated from the model of a straight wing with point sources of disturbances (bulges) made on its surface are presented. The variations in the three-dimensional flow pattern are analyzed as functions of the bulge shapes and positions. It is found that the flow can be controlled by means of mounting the bulges downstream of the separation line, in the return flow region, since in this case they hinder large-scale vortex formation in the separation zone. The results obtained show that there is an intimate connection between the vortices and the separation zone as a whole. Impeding the vortex structure formation can result in considerable variations in the separation zone structure, up to its complete disappearance.     

Enrofloxacin inclusion complexes with cyclodextrins

Inclusion complexes using α-, β-, γ-, and hydroxypropyl-β-CD (HP-β-CD) were produced with the antibiotic enrofloxacin, with the aim of increasing its solubility by complexation. Phase solubility diagrams were obtained, to confirm the formation of inclusion complexes, and to determine the solubility enhancement and stability constant of each complex. Enrofloxacin inclusion in β-CD showed the highest value of the complex stability constant (35.56?mmol?L^?1), but the greatest increase in solubility was obtained using HP-β-CD reaching a 1258% increase over enrofloxacin solubility in the absence of CD. The order of highest enrofloxacin solubility achieved was: HP-β-CD?>?α-CD?>?γ-CD?>?β-CD. In addition, formation of complexes was confirmed by differential scanning calorimetry and thermogravimetry, applied to the complexes obtained by the kneading technique. The influence of citric acid, alone or as an adjunct of β-CD, on the solubility of enrofloxacin was also determined. A solution of 15?mmol?L^?1 citric acid dissolved 10?g?L^?1 of enrofloxacin, but a gradual increase in β-CD concentration in the presence of citric acid did not increase the degree of solubilization of enrofloxacin.     

Steady Streamwise Structures in the Boundary Layer on a Swept Wing with Elevated Turbulence of the Incoming Flow

Results for a turbulized flow past the windward side of a swept wing model are presented. Origination of steady disturbances in the form of streamwise structures is found. The greatest effect on the formation of these disturbances is exerted by the curvature of the external flow streamlines. The secondary flow in the boundary layer leads to an increase in the characteristic scale of disturbances in the transverse direction, as compared to the flow around the model at a zero yaw angle.     

Bleaching of kraft pulp with commercial xylanases

The perform ance of commercial xylanases in totally chlorine-free bleaching of kraft pulp from conifer was tested with Pulpzyme HC (Novo Nordisk) and Cartazyme NS-10 (Sandoz/Clariant), at 500 U/kg of dry pulp, respectively. The treatment with Pulpzyme (X_p) or Cartazyme (X_c) has been combined with stages of bleaching using: oxygen (O), sulfuric acid (A), and extraction with hydrogen peroxide (E_op). The following sequences have been tested: OXpAE_op, OXcAE_op, XpOAE_op, XcOAE_op and OAE_op, Kraft pulp bleached at the Klabin industrial plant using the sequence, CEH (chlorine, alkaline extreaction, and hypochlorination) was, used for comparison. The following average values were obtained: 1. Kappa number: OX_pAE_op, 4.8; OX_cAE_op, 4.9; XpOAE_op, 5.0; XcOAE_op, 4.9; OAE_op, 5.6, and CEH, 1.9; 2. Brightness (% ISO values): OX_pAE_op, 68.4; OX_cAE_op, 70.1; X_pOAE_op, 67.9; X_cOAE_op, 26.9; X_pOAE_op, 23.4; X_cOAE_op, 23.1; OAE_op, 25.4, and CEH, 25.2. Pulps that were treated with xylanases, before or affer the delignification with oxygen, have shown reduced kappa number and higher brightness than the pulp OAE_op, Enzyme treatment before delignification with oxygen reduces pulp viscosity. Brightness obtained for pulp produced with bleaching sequences containing the enzymatic treatment, when compared with the control, CEH, shows that the xylanases enhance the action of the bleaching agents.     

The analysis of alkyl-capped alcohol ethoxylates and alcohol ethoxycarboxylates from alcohol ethoxylates by atmospheric pressure chemical ionization mass spectrometry

Alcohol ethoxylates (AEs) are nonionic surfactants. They are industrially important compounds that have historically been difficult to analyze, with the best results to date achieved through derivatization (e.g., silylation) followed by analysis by gas chromatography/mass spectrometry (GC/MS). Recently, mass spectrometric techniques such as field desorption (FD), time-of-flight secondary ion mass spectrometry (TOF-SIMS), fast atom bombardment (FAB), electrospray ionization (ESI) and matrix-assisted laser desorption/ionization (MALDI) have been employed to analyze surfynol(R) 4xx. In an effort to produce low-cost alkyl-capped AEs and anionic detergents from AEs, a fast and reliable measure of the product yields and conversions from AEs is required in research. We found that the product yields and conversions from reactions of AEs, obtained by the employment of atmospheric pressure chemical ionization (APCI), were in good agreement with those obtained from proton nuclear magnetic resonance spectroscopy ((1)H-NMR). Therefore, APCI can be used as a validated tool for studying AE reactions. Mixtures that contain either silylated or unsilylated ethoxylates and/or carboxylates yield the same APCI mass spectra. Copyright -Copyright 1999 John Wiley & Sons, Ltd.     

Dielectric properties of porous aluminum oxide with inclusions of triglycine sulphate and Rochelle salt

The dielectric properties of composite structures based on porous aluminum with inclusions of triglycine sulphate and Rochelle salt were investigated. The effect of structured and adsorbed water on the dielectric behavior of the nanocomposite under study was found.     

Initiation of the formation of chiral strings: Dimension of formation domain,microstructure, and nucleation mechanism

The initiation of the formation of strings in low-concentration chiral solutions was experimentally studied. The domains of initiation were classified according to dimensions: (0–3)D. The dipole-dipole mechanism of the formation of anisotropic nucleation in a mesophase was considered. The role of dispersion interactions in the assembly of supramolecular stacks was estimated at ～0.3–0.4 eV. The threshold values of string formation in chiral mixtures were determined. A phenomenon of the formation of paired strings was established and characterized.     

Kinetics and mechanism of the low-temperature chain hydrobromination of ethylene

The rate of chain hydrobromination of ethylene has been determined for ordinary and deuterated compounds between 90 and 40 K and was found to reach a plateau value below ≈70 K. The rate-determining step in the development of chains at low temperatures appears to be the formation of the intermediate radical ?₂H₄Br rather than its subsequent transformation into ethyl bromide via the transfer of hydrogen atoms.