全文获取类型
收费全文 | 1754篇 |
免费 | 28篇 |
专业分类
化学 | 965篇 |
晶体学 | 34篇 |
力学 | 12篇 |
数学 | 317篇 |
物理学 | 454篇 |
出版年
2023年 | 7篇 |
2022年 | 12篇 |
2021年 | 18篇 |
2020年 | 11篇 |
2019年 | 25篇 |
2018年 | 51篇 |
2017年 | 41篇 |
2016年 | 71篇 |
2015年 | 54篇 |
2014年 | 65篇 |
2013年 | 161篇 |
2012年 | 62篇 |
2011年 | 91篇 |
2010年 | 64篇 |
2009年 | 72篇 |
2008年 | 83篇 |
2007年 | 68篇 |
2006年 | 64篇 |
2005年 | 55篇 |
2004年 | 54篇 |
2003年 | 59篇 |
2002年 | 42篇 |
2001年 | 46篇 |
2000年 | 28篇 |
1999年 | 26篇 |
1998年 | 30篇 |
1997年 | 24篇 |
1996年 | 17篇 |
1995年 | 21篇 |
1994年 | 18篇 |
1993年 | 17篇 |
1992年 | 20篇 |
1991年 | 12篇 |
1990年 | 18篇 |
1989年 | 15篇 |
1988年 | 13篇 |
1987年 | 24篇 |
1986年 | 12篇 |
1985年 | 13篇 |
1984年 | 18篇 |
1982年 | 19篇 |
1981年 | 17篇 |
1980年 | 17篇 |
1979年 | 17篇 |
1978年 | 10篇 |
1977年 | 11篇 |
1975年 | 8篇 |
1973年 | 7篇 |
1939年 | 7篇 |
1929年 | 6篇 |
排序方式: 共有1782条查询结果,搜索用时 15 毫秒
111.
The paper presents a study of the effect of a constant magnetic field (CMF) on the basic processes of quercetin electrochemical reactions. According to the observation made in previous studies, the presence of a double bond in the C-ring of quercetin enhances the antioxidant properties of that compound, whereas the presence of −OH groups also affects the antioxidant properties. Using cyclic voltammetry it was found that the constant magnetic field improves the efficiency of quercetin electrooxidation, especially of the third stage of the process, i. e. the stage in which the oxidation of the OH groups in the A-ring is the most difficult. The use of HPLC confirmed the electrochemical measurements and the results of cyclic voltammetry studies. The beneficial effect of the magnetic field on the efficiency of quercetin oxidation was confirmed by the results of impedance spectroscopy measurements. 相似文献
112.
Nickel foam and five nickel foam-based composite electrodes were prepared for being used as anode materials for the electrooxidation
of methanol in KOH solution containing 0.1 and 1.0 M of methanol. The layered electrodes composed of nickel foam, platinum
nanoparticles, polyaniline (PANI) and/or porous carbon (C) prepared in various assemblies. As shown by SEM analysis, depending
on the preparation conditions, the electrodes of different morphologies were obtained. Using the cyclic voltammetry method,
the oxidation of methanol on nickel foam electrode was observed in the potential range 0.4 V ↔ 0.7 V, where the Ni(OH)2/NiOOH transformation occurred. The presence of Pt particles in electrode gave rise to the increase in electrocatalytic activity
in this potential range. For electrodes containing dispersed platinum catalyst (Ni/Pt, Ni/PANI/Pt and Ni/C/Pt), the oxidation
of methanol was noted also in the potential range −0.5 V ↔ 0.1 V. The electrocatalytic activities of the examined electrodes
toward methanol oxidation at low potentials were in order Ni/Pt > Ni/C/Pt > Ni/PANI/Pt, whereas at high potentials in order
Ni/PANI/Pt > Ni/Pt> Ni/C/Pt > Ni. Among the examined electrodes, the most resistant to cyclic poisoning appeared to be the
Ni/C/Pt electrode.
Presented at the 4Th Baltic Conference on Electrochemistry, Greifswald, March 13–16, 2005 相似文献
113.
This paper reviews literature information on the behaviour of semivolatile organic compounds (SVOCs) in the indoor environment,
as well as the most likely emission sources. The consecutive stages of analytical procedures used for monitoring SVOCs in
indoor environments are described. The most common approaches used for collecting samples from the gas and particulate phases
are mentioned. The paper discusses and compares various types of sorbents and filters applied in dynamic, passive and denudational
techniques, as well as the techniques used to liberate the SVOCs, including Soxhlet, sonication and microwave extraction.
The main advantages and disadvantages of each technique are discussed, together with possible future trends. The approaches
commonly used during the final determination step, such as gas chromatography and liquid chromatography, are presented together
with their possible drawbacks, and ways of eliminating them are suggested. The review makes brief reference to the effects
of human exposure to SVOCs in house dust and discusses the main aspects of the analytical procedures used to monitor the presence
of SVOCs in this medium. 相似文献
114.
115.
The development of technology of new semiconductor devices requires fundamental studies of a number of phenomena taking place in semiconductors during the doping process or accompanying the doping process. These studies are concerned with the following problems: 1. Diffusion of gold in silicon and the effect of diffusion layers (particularly phosphorus layers) and epitaxial silicon layers on the distribution of gold in thin silicon plates. 2. Distribution of admixtures in silicon introduced with the aid of the ion implantation technique. Our studies concerned with the second of the above mentioned problems comprised an autoradiographic examination of the homogeneity of the beam of phosphorus ions implanted in silicon, and a study of some apparatus factors and of the purity of the basic material on the implantation. 相似文献
116.
117.
D. Kamińska A. Gajos E. Czerwiński D. Alfs T. Bednarski P. Białas C. Curceanu K. Dulski B. Głowacz N. Gupta-Sharma M. Gorgol B. C. Hiesmayr B. Jasińska G. Korcyl P. Kowalski W. Krzemień N. Krawczyk E. Kubicz M. Mohammed Sz. Niedźwiecki M. Pawlik-Niedźwiecka L. Raczyński Z. Rudy M. Silarski A. Wieczorek W. Wiślicki B. Zgardzińska M. Zieliński P. Moskal 《The European Physical Journal C - Particles and Fields》2016,76(8):445
118.
R. Kruszka M. Ekielski K. Gołaszewska K. Korwin-Mikke Z. Sidor M. Wzorek D. Pierścińska R. Sarzała T. Czyszanowski A. Piotrowska 《Opto-Electronics Review》2011,19(1):51-55
The results of modelling of the influence of photonic crystal on the performance of VCSEL-type semiconductor laser structure
are shown and indicate that the use of those structures would significantly improve the working parameters of the devices.
The method of fabrication of photonic crystals in the Bragg mirrors of GaAs/AlGaAs-based VCSELs is presented. 相似文献
119.
Michał Rachwalski Stanisław Leśniak Piotr Kiełbasiński 《Tetrahedron: Asymmetry》2010,21(21-22):2687-2689
Diastereomerically pure tridentate heteroorganic ligands containing hydroxyl, sulfinyl and aziridine moieties as nucleophilic centers, capable of binding to various organometallic reagents, have been proven to be highly efficient catalysts in the enantioselective addition of phenylethynylzinc to aldehydes to give the desired products in very high yields (up to 95%) and with ee’s up to 90%. The influence of the stereogenic centers located on the sulfinyl sulfur atom and in the aziridine moiety on the stereochemical course of the reaction is also discussed. 相似文献
120.
P. T. Jochym K. Parlinski A. M. Oleś 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(2):173-179
The magnetization distribution, its energetic characterization by the
interlayer coupling constants and lattice dynamics of (001)-oriented
Fe/Pt multilayers are investigated using density functional theory
combined with the direct method to determine phonon frequencies.
It is found that ferromagnetic order between consecutive Fe layers is
favoured, with the enhanced magnetic moments at the
interface. The bilinear and biquadratic coupling coefficients between Fe
layers are shown to saturate fast with increasing thickness of
nonmagnetic Pt layers which separate them. The phonon calculations
demonstrate a rather strong dependence of partial iron phonon
densities of states on the actual position of Fe monolayer
in the multilayer structure. 相似文献