排序方式： 共有23条查询结果，搜索用时 15 毫秒
21.
Abbott T Akiba Y Alburger D Beavis D Betts RR Birstein L Bloomer MA Bond PD Chasman C Chu YY Cole BA Costales JB Crawford HJ Cumming JB Debbe R Duek E Engelage J Fung SY Grodzins L Gushue S Hamagaki H Hansen O Hayashi S Homma S Huang HZ Ikeda Y Katcoff S Kaufman S Kimura K Kitamura K Kurita K Ledoux RJ Levine MJ Miake Y Morse RJ Nagamiya S Olness J Parsons CG Remsberg LP Sarabura M Shor A Stankus P Steadman SG Stephans GS Sugitate T Tannenbaum MJ Torikoshi M van Dijk JH Videbaek F Vient M 《Physical review letters》1990,64(8):847-850
22.
Synthesis of a novel, stable reagent (1,3-benzothiazol-2-ylsulfonyl)fluoroacetonitrile from readily synthesized ethyl alpha-(1,3-benzothiazol-2-ylsulfanyl)-alpha-fluoroacetate is reported. Aldehydes undergo condensations with (1,3-benzothiazol-2-ylsulfonyl)fluoroacetonitrile in the presence of DBU leading to alpha-fluoro acrylonitriles in high yields and with good Z-stereoselectivity. Lowering of reaction temperature increases the Z selectivity. 相似文献
23.
A mild and efficient synthesis of 1-aryl-1-fluoroethenes from benzothiazolyl (aryl)fluoromethyl sulfones and paraformaldehyde, under DBU- or Cs(2)CO(3)-mediated conditions at room temperature, is described. A comparable diethyl fluoro(naphthalen-2-yl)methylphosphonate reagent does not react with paraformaldehyde under these mild conditions. The utility of the methodology for synthesis of terminal α-fluoroalkenes bearing electron-withdrawing functionalities is also shown. 相似文献