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11.
In the linear nonlocal elasticity theory, the solution to the boundary-value problem of the crack with a constant stress boundary
condition does not exist. This problem has been studied in this paper. The contents studied contain of examining objectivity
of the energy balance, deducing the constitutive equations of nonlocal thermoelastic bodies, and determining nonlocal force
and the linear nonlocal elasticity theory. Some new results are obtained. Among them, the stress boundary condition derived
from the linear theory not only solves the problem mentioned at the beginning, but also contains the model of molecular cohesive
stress on the sharp crack tip advanced by Barenblatt. 相似文献
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几种对称镍卟啉配合物的合成、表征和电化学性质 总被引:3,自引:0,他引:3
卟啉试剂是一类重要的离子配位显色剂,在生物体中具有重要作用.作为自然界存在的金属卟啉之一,镍卟啉的电化学研究具有化学和生物学意义.四对羟基苯基卟啉合成已有不少报道[1,2],但产率较低,只有10%左右.Lindsey等发现用BF3作催化剂,在CH2C... 相似文献
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铜铁试剂的交流示波极谱滴定法研究 总被引:3,自引:0,他引:3
提出了用交流示波极谱滴定法测定铜合金中的铜和测定铜铁试剂的方法。该法快速、准确、终点直观。测定了铜合金中的铜,变动系数0.07%~0.17%。考察了紫外光照射下铜铁试剂的动力学行为。 相似文献
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钼(Ⅵ)—苦杏仁酸体系的吸附伏安行为 总被引:3,自引:0,他引:3
本文对Mo(Ⅵ)-苦杏仁酸体系的吸附伏安行为做了系统的研究。测定了吸附量与络合物的形成常数,在此基础上建立了钼的吸附溶出伏安法。 相似文献
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本文通过考虑局部化残余力的影响对线性非局部弹性理论进行了修正,由修正后的理论所导出的应力边界条件包含了物体微观结构的长程力的作用,这个结果不仅解释了在裂纹混合边界值问题中线性非局部弹性理论方程的解在常应力边界条件下不存在的问题,而且可以自然地得到裂纹尖端的Barenblatt分子内聚力模型。 相似文献
17.
The Migdal renormalization group(MRG) procedure is applied to the finite temperature SU(2) lattice gauge theory.With its effective action form in terms of the Polyakov Zoop we an-alyse the strong and weak coupling approximations of the evolution of renormalized couplings.The distribution of renormalization group trajectory is obtained and the critical coupling is measured. 相似文献
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应力边界条件的提法是线性非局部弹性理论尚未解决的一个理论问题。文中针对这一问题进行了研究,所导出的应力边界条件包含了物体微观结构的长程相互作用,这个结果不仅解释了在裂纹混合边界值问题中非线性局部弹性理论方程的解在常应力边界条件下不存在的问题,而且可以自然地得到裂纹尖端的分子内聚力模型。 相似文献
19.
石墨炉原子吸收光谱法测定高温合金中镓 总被引:1,自引:0,他引:1
研究了普通石墨管、平台石墨管和涂钼普通石墨管对镓的测定性能.得出涂钼普通石墨管对镓的测定灵敏度和重现性均好于其他石墨管.从而建立了一种更为满意的石墨炉原子吸收测定高温合金中镓的新方法. 相似文献
20.
Guo H Qian H Sun S Sun D Yin H Cai X Liu Z Wu J Jiang T Liu X 《Chemistry Central journal》2011,5(1):1
In this study, hollow mesoporous silica nanoparticles (HMSNs) were synthesized using the sol-gel/emulsion approach and its
potential application in drug delivery was assessed. The HMSNs were characterized, by transmission electron microscopy (TEM),
Scanning Electron Microscopy (SEM), nitrogen adsorption/desorption and Brunauer-Emmett-Teller (BET), to have a mesoporous
layer on its surface, with an average pore diameter of about 2 nm and a surface area of 880 m2/g. Fluorescein isothiocyanate (FITC) loaded into these HMSNs was used as a model platform to assess its efficacy as a drug
delivery tool. Its release kinetic study revealed a sequential release of FITC from the HMSNs for over a period of one week
when soaked in inorganic solution, while a burst release kinetic of the dye was observed just within a few hours of soaking
in organic solution. These FITC-loaded HMSNs was also found capable to be internalized by live human cervical cancer cells
(HeLa), wherein it was quickly released into the cytoplasm within a short period of time after intracellular uptake. We envision
that these HMSNs, with large pores and high efficacy to adsorb chemicals such as the fluorescent dye FITC, could serve as
a delivery vehicle for controlled release of chemicals administered into live cells, opening potential to a diverse range
of applications including drug storage and release as well as metabolic manipulation of cells. 相似文献