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A multiplexing technique, which is based on duty-cycle division, is proposed. The channel multiplexing and demultiplexing are performed electrically at the single user bit rate, which is very economic. In a three-user system (3×10 Gb/s), the simulation results show that the best receiver sensitivity value achieved is −30.1 dBm with an optical signal-to-noise ratio (OSNR) of 22.3 dB, while the chromatic dispersion tolerance ranges from 192 to 280 ps/nm. Migration from 30 to 120 Gb/s is achieved with the penalty of 6.4 and 5.2 dB in the receiver sensitivity and OSNR, respectively, for the worst user. 相似文献
63.
In this note we first define the notions of (weak, strong) implicative hyper K-algebras. Then we show by examples that these notions are different. After that we state and prove some theorems which determine the relationship between these notions and (weak) hyper K-ideals. Also we obtain some relations between these notions and (weak) implicative hyper K-ideals. Finally, we study the implicative hyper K-algebras of order 3, in particular we obtain a relationship between the positive implicative hyper K-algebras and (weak, strong) implicative hyper K-algebras under a simple condition. 相似文献
64.
In this paper, aspects of observable and non-observable based models are discussed. A survey of recent literature was done to show how using non-observable-based language carelessly may cause disagreement, even in professional research programs and incorrect assertions, even in prestigious journals. The relation between physical measurements and observables is discussed and it is shown that, in contrast to general belief, this relation may be complicated and not always straightforward. The decomposition of the system into basic subsystems (physical or conceptual) is traced as the origin of non-observable-based languages. The possibility of defining new quantum mechanical observables for open quantum subsystems and of replacing them with non-observable-based concepts has been mentioned and the AIM theory is explained as an example. An account of some current non-observable-based models for molecular geometry is discussed and it is shown that not all non-observable-based languages possess the same effectiveness. In the end, the need to develop a clear chemical language is stressed. 相似文献
65.
In this work, the effect of solvent (methanol, CH3OH) molecules on proton transfer (PT) between ammonia and hydrogen halides was studied. We performed MP2 and B3LYP calculations on HX–NH3–(CH3OH) n clusters for three hydrogen halides, HF, HCl, and HBr, with the number of methanol molecules varying from none to three (n = 0–3). The results showed that stepwise association of methanol molecules with the gas-phase complex can eventually facilitate ionization within the complex, producing the $ {\text{NH}}_{4}^{ + } {\text{X}}^{ - } - \left( {{\text{CH}}_{ 3} {\text{OH}}} \right)_{\text{n}} $ cluster. We found that PT occurs on addition of from one (for HBr) to three (for HF) methanol molecules. The interaction energy $ E_{\text{int}} $ and $ \Updelta E_{\text{add}} $ for the complexes were calculated and basis set superposition error (BSSE) correction was also performed. Atoms-in-molecule and natural-bond-orbital analysis were used to study the properties of the hydrogen bonds in the complexes. 相似文献
66.
The kinetics of the permanganic oxidation process of L ‐norleucine, L ‐leucine, L ‐iso‐leucine, and L ‐tert‐leucine in strong acid medium has been investigated using a spectrophotometric technique. Conclusive evidences have proven autocatalytic activity of Mn(II) for these reactions in strong acid medium analogous to weak acid medium, but in the former, ratio of Mn(II) to amino acid concentration must reach a certain amount for autocatalytic phenomenon to emerge, which we call “critical ratio.” This critical ratio depends on the nature of the amino acid employed. Thus considering “delayed autocatalytic behavior” of Mn(II) ions, rate equations satisfying observations for both catalytic and noncatalytic routes have been presented. Kinetic data in a noncatalytic pathway have been fitted to a biparametric equation including inductive, steric, and hyperconjugation correction effects, and it is determined that by shifting the side branch on a carbon chain toward an α‐carbon atom (adjacent to amino acid's functional group) and also adding branches to the α‐carbon atom, the reaction rate in the noncatalytic pathway decreases. Inductive and steric hindrance factors in amino acid's carbon chain are effective on processes' rate both in catalytic and noncatalytic pathways. © 2005 Wiley Periodicals, Inc. Int J Chem Kinet 38: 1–11, 2006 相似文献
67.
Shant Shahbazian Rohoullah Firouzi Mansour Zahedi 《Theoretical chemistry accounts》2007,117(1):153-161
In this study, it has been demonstrated that there are additive rules corresponding to ab initio derived total electronic energies between members of triple sets of some extended sulfur diimides and their mono- and bi-derivatives. It has been shown that the additive rules are insensitive to the combination of methods and basis sets used to derive the total electronic energies. This insensitivity to the level of calculation is demonstrated to be the case for some linear alkanes also. It has been found that the total electronic energies of certain members of extended sulfur diimide sets ((ZZ)k and (EE)k conformers) follow a linear relation although chemical accuracy may be achieved only by excluding the smallest members of these sets. The details of this deviation have been employed to quantify the “Z-effect” proposed previously by the same authors. 相似文献
68.
In the framework of density functional theory (DFT), we calculated the electronic structures and the quadrupole coupling constants (CQ) in the pristine and carbon doped (C-doped) beryllium oxide nanotubes (BeONTs) for the first time. The pristine and C-doped forms of representative (10, 0) zigzag and (5, 5) armchair models of BeONTs were considered in this study. The structures are allowed to relax by performing all atomic optimization. Formation energies indicate that C-doping of Be atom (CBe form) could be more favorable than C-doping of O atom (CO form) in both zigzag and armchair BeONTs. Gap energies and dipole moments detected the effects of dopant in the (5, 5) armchair models; however, those parameters did not detect any significant changes in the C-doped (10, 0) zigzag BeONT models. The calculated nuclear quadrupole coupling constant for the Be and O nuclei reveal that the pristine models can be divided into layers of nuclei with an equivalent electrostatic environment such that those nuclei at the ends of tubes end up in a strong electrostatic environment when compared to the other nuclei along the length of tubes. Comparison with the available data on the pristine BeONTs reveals the influence of C-doping on the CQ parameters of Be and O atoms in the C-doped structures. For most lattice sites, the degree of influence on the CQ parameters of the zigzag model is larger than that of the armchair model. The calculations were performed based on the B3LYP DFT method and 6-31G∗ standard basis sets using the Gaussian 09 program package. 相似文献
69.
In this work, the effect of laser pulse treatment on the optical properties of poly(methyl methacrylate) (PMMA) films has been studied experimentally. The second harmonic of a pulsed Nd:YAG laser at 532 nm and 6 ns pulse width with 10 Hz repetition rate was used to modify the surface of red-BS-dye-doped PMMA films. Samples were ablated with 50 and 100 laser pulses. Optical reflectance and transmittance spectra were obtained in the range of 200–2000 nm. The optical properties of the films were influenced by the pulse number significantly. The oscillator and dispersion energies of the films were determined using the Wemple-Didomenico model. The optical band gap energy was extracted using the Tauc method. Results show that the optical parameters of the films were changed significantly after laser treatment. 相似文献
70.
A. Seif E. Zahedi T. S. Ahmadi 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,82(2):147-152
In the framework of the density functional theory (DFT) calculations, we present a first time investigation of the properties
of four kinds of configurations of carbon nanobuds (CNBs) in which a perfect or defective C60 molecule attaches covalently
on the surface of an armchair single-walled carbon nanotube (SWCNT). Chemical shielding (CS) parameters were calculated for
the optimized structures. Our results indicate that carbon nanobuds have different values of formation energy, band gap energy,
dipole moment, charge transfer and chemical-shielding isotropy (CSI), which result from the many covalent combinations of
the fullerenes with the carbon nanotubes. These calculations were carried out using the Gaussian 09 software package. 相似文献