全文获取类型
收费全文 | 527427篇 |
免费 | 4743篇 |
国内免费 | 1276篇 |
专业分类
化学 | 268486篇 |
晶体学 | 7645篇 |
力学 | 25989篇 |
综合类 | 17篇 |
数学 | 67781篇 |
物理学 | 163528篇 |
出版年
2021年 | 5013篇 |
2020年 | 5476篇 |
2019年 | 6221篇 |
2018年 | 8413篇 |
2017年 | 8558篇 |
2016年 | 11624篇 |
2015年 | 6177篇 |
2014年 | 10436篇 |
2013年 | 23485篇 |
2012年 | 18334篇 |
2011年 | 21789篇 |
2010年 | 16420篇 |
2009年 | 16279篇 |
2008年 | 20659篇 |
2007年 | 20508篇 |
2006年 | 18612篇 |
2005年 | 16619篇 |
2004年 | 15468篇 |
2003年 | 13955篇 |
2002年 | 13847篇 |
2001年 | 14729篇 |
2000年 | 11344篇 |
1999年 | 8754篇 |
1998年 | 7602篇 |
1997年 | 7470篇 |
1996年 | 6930篇 |
1995年 | 6260篇 |
1994年 | 6264篇 |
1993年 | 6017篇 |
1992年 | 6375篇 |
1991年 | 6865篇 |
1990年 | 6577篇 |
1989年 | 6486篇 |
1988年 | 6321篇 |
1987年 | 6137篇 |
1986年 | 5872篇 |
1985年 | 7408篇 |
1984年 | 7769篇 |
1983年 | 6532篇 |
1982年 | 6817篇 |
1981年 | 6326篇 |
1980年 | 6003篇 |
1979年 | 6504篇 |
1978年 | 6741篇 |
1977年 | 6629篇 |
1976年 | 6586篇 |
1975年 | 6302篇 |
1974年 | 6129篇 |
1973年 | 6424篇 |
1972年 | 4706篇 |
排序方式: 共有10000条查询结果,搜索用时 500 毫秒
781.
C. M. Silva R. S. Amaral A. Amaral J. A. Santos Júnior D. C. Santos L. E. Lima S. V. Silveira 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(1):237-241
Summary Studies performed by the Brazilian Nuclear Corporation (NUCLEBRAS), in collaboration with the Geological Survey Company of
Brazil (CPRM), identified high levels of natural uranium in the districts of Pedra and Venturosa, in the rural region of the
state of Pernambuco (PE) - Brazil, where the maximum value found in rocks was 22,000 mg. 相似文献
782.
M. R. Allazov Ali Riza Kul A. V. Einullaev M. B. Babanly 《Russian Journal of Inorganic Chemistry》2006,51(4):624-629
Some polythermal sections of the Ni-Bi-Se system have been investigated by DTA, X-ray powder diffraction, microstructural analysis, and microhardness measurements. The liquidus surface has been constructed for this system. The compounds NiBi2Se4 and Ni3Bi2Se2 are formed by dystectic reactions and melt at 1088 and 980 K, respectively. The regions of primary and joint phase crystallization have been determined. A commutation of Bi2Se3-based thermoelements with a metal nickel bus-bar has been proposed. 相似文献
783.
Catalytic properties of silica-supported heteropolyacids (HPA) in a mechanical mixture with reduced Me-Ce oxides (Me = Ni,
Pd) in n-hexane isomerization are studied. The role of each component of the mixed oxides (Ce and, typically, Ni and Pd) and their
optimum content has been illuminated: cerium is not only beneficial for eliminating or preventing coke deposition but is also
effective for maintaining the Keggin structure of the highly-organized HPA during the reaction and probably allows a better
dispersion of the second metal species. Nickel and palladium, present as Ni0 and Pd0, reinforce the activation of the alkane, which is difficult to obtain by means of a direct attack by an acid, and, thus,
enhance noticeably the activity of the catalyst. The best mechanical mixtures are obtained with 30–70 wt % NiCeO-HPW/SiO2 and 50–50 wt % Pd0.1CeO-HPW/SiO2. These mixtures have the highest efficiency for a Ni/(Ni + W) atomic ratio of 0.66 and a Pd/(Pd + W) ratio of 0.40, respectively.
Finally, the conversion of n-hexane is in the order HPW > HSiW > HBW, which seems to be consistent with the order of their acid strength as per the literature,
but the isomerization selectivity appears to be slightly higher on HSiW.
Published in Russian in Kinetika i Kataliz, 2006, Vol. 47, No. 1, pp. 24–28.
The text was submitted by the authors in English. 相似文献
784.
785.
786.
787.
788.
789.
Morey Timothy E. Varshney Manoj Flint Jason A. Seubert Christoph N. Smith W. Brit Bjoraker David G. Shah Dinesh O. Dennis Donn M. 《Journal of nanoparticle research》2004,6(2):159-170
Background: Although microemulsion-based nanoparticles (MEs) may be useful for drug delivery or scavenging, these benefits must be balanced against potential nanotoxicological effects in biological tissue (bio-nano interface). We investigated the actions of assembled MEs and their individual components at the bio-nano interface of thrombosis and hemolysis in human blood.
Methods: Oil-in-water MEs were synthesized using ethylbutyrate, sodium caprylate, and pluronic F-68 (ME4) or F-127 (ME6) in 0.9% NaClw/v. The effects of MEs or components on thrombosis were determined using thrombo-elastography, platelet contractile force, clot elastic modulus, and platelet counting. For hemolysis, ME or components were incubated with erythrocytes, centrifuged, and washed for measurement of free hemoglobin by spectroscopy.
Results and conclusions: The mean particle diameters (polydispersity index) for ME6 and ME4 were 23.6 ± 2.5 nm (0.362) and 14.0 ± 1.0 nm (0.008), respectively. MEs (0, 0.03, 0.3, 3 mM) markedly reduced the thromboelastograph maximal amplitude in a concentration-dependent manner (49.0 ± 4.2, 39.0 ± 5.6, 15.0 ± 8.7, 3.8 ± 1.3 mm, respectively), an effect highly correlated (r2 = 0.94) with similar changes caused by pluronic surfactants (48.7 ± 10.9, 30.7 ± 15.8, 20.0 ± 11.3, 2.0 ± 0.5) alone. Neither oil nor sodium caprylate alone affected the thromboelastograph. The clot contractile force was reduced by ME (27.3 ± 11.1–6.7 ± 3.4 kdynes/cm2, P = 0.02, n = 5) whereas the platelet population not affected (175 ± 28–182 ± 23 106/ml, P = 0.12, n = 6). This data suggests that MEs reduced platelet activity due to associated pluronic surfactants, but caused minimal changes in protein function necessary for coagulation. Although pharmacological concentrations of sodium caprylate caused hemolysis (EC50 = 213 mM), MEs and pluronic surfactants did not disrupt erythrocytes. Knowledge of nanoparticle activity and potential associated nanotoxicity at this bio-nano interface enables rational ME design for in vivo applications. 相似文献
790.
Experimental analysis, modeling, and theoretical design of McMaster pore-filled nanofiltration membranes 总被引:1,自引:0,他引:1
A side-by-side comparison of the performance of McMaster pore-filled (MacPF) and commercial nanofiltration (NF) membranes is presented here. The single-salt and multi-component performance of these membranes is studied using experimental data and using a mathematical model. The pseudo two-dimensional model is based on the extended Nernst–Planck equation, a modified Poisson–Boltzmann equation, and hydrodynamic calculations. The model includes four structural properties of the membrane: pore radius, pure water permeability, surface charge density and the ratio of effective membrane thickness to water content. The analysis demonstrates that the rejection and transport mechanisms are the same in the commercial and MacPF membranes with different contributions from each type of mechanism (convection, diffusion and electromigration). Solute rejection in NF membranes is determined primarily by a combination of steric and electrostatic effects. The selectivity of MacPF membranes is primarily determined by electrostatic effects with a significantly smaller contribution of steric effects compared to commercial membranes. Hence, these membranes have the ability to reject ions while remaining highly permeable to low molecular weight organics. Additionally, a new theoretical membrane design approach is presented. This design procedure potentially offers the optimization of NF membrane performance by tailoring the membrane structure and operating variables to the specific process, simultaneously. The procedure is validated at the laboratory scale. 相似文献