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91.
Nu Xu I. G. Bearden H. Bøggild J. Boissevain J. Dodd B. Erazmus S. Esumi C. W. Fabjan D. Ferenc D. E. Fields A. Franz J. Gaardhøje O. Hansen D. Hardtke H. van Hecke E. B. Holzer T. Humanic P. Hummel B. V. Jacak R. Jayanti M. Kaneta M. Kopytine M. Leltchouk T. Ljubicic B. Lörstad N. Maeda A. Medvedev M. Murray S. Nishimura H. Ohnishi G. Paic S. U. Pandey F. Piuz J. Pluta V. Polychronakos M. Potekhin G. Poulard A. Sakaguchi J. Simon-Gillo J. Schmidt-Sørensen W. Sondheim M. Spegel T. Sugitate J. P. Sullivan Y. Sumi W. J. Willis K. Wolf N. Xu D. S. Zachary 《Acta Physica Hungarica A》1996,4(1-4):263-270
We present recent results on single particle transverse momentum distributions of pions, kaons and protons, measured in CERN Experiment NA44, of 200 AGeV/c S+S and 158 AGeV/c Pb+Pb central collisions. By comparing these data with thermal and transport models, freeze-out parameters like the temperatureT fo and the chemical potentials (μ q ,μ s ) are extracted and discussed. 相似文献
92.
93.
94.
Methyl fluorosulphonate and triethyloxonium tetrafluoroborate (which is less reactive) have been found to give four distinct types of reaction with transition metal complexes, viz. (a) halogen abstraction, (b) oxidative-addition, (c) alkylation of the coordinated ligands, and (d) oxidation at the metal atom. 相似文献
95.
Aron ZD Dorrestein PC Blackhall JR Kelleher NL Walsh CT 《Journal of the American Chemical Society》2005,127(43):14986-14987
We report the expression and characterization of a truncated form of MycA from the Mycosubtilin gene cluster from Bacillus subtilis. The MycA fragment contains a new amino transferase (AMT) tailoring domain, allowing the first detailed study of a PLP-dependent enzyme operating in cis within the PKS and NRPS biosynthetic paradigm. As the AMT domain acts on covalently bound beta-ketothioesters, and is therefore a single-turnover system, electrospray ionization-Fourier transform mass spectrometry (ESI-FTMS) was used to observe the amine-transfer reaction both for amine donor substrate specificity and to regiospecifically determine enzyme-bound intermediates. We confirm the function of the AMT domain, dissect the mechanistic steps of amine transfer, identify the preferred amine source, and localize the beta-ketothioester substrate during amine transfer. 相似文献
96.
Harris AL Yang X Hegmans A Povirk L Ryan JJ Kelland L Farrell NP 《Inorganic chemistry》2005,44(26):9598-9600
Charge delocalization (6+ to 8+) in "noncovalent" linear trinuclear platinum complexes produces compounds with cytotoxicity in some cases equivalent to cisplatin. The cellular uptake of a novel 8+ compound is greater than that of neutral cisplatin as well as other multinuclear Pt compounds. 相似文献
97.
Michael FE Duncan AP Sweeney ZK Bergman RG 《Journal of the American Chemical Society》2005,127(6):1752-1764
The mechanisms of the rearrangements and stereoinversion of azametallacyclobutenes generated via [2+2] cycloaddition of allenes and imidozirconium complexes have been studied. Metallacycles derived from allenes bearing beta-hydrogen atoms racemize at room temperature by reversible beta-hydride elimination, a process which is also responsible for their eventual conversion to monoazadiene complexes. Metallacycles derived from diarylallenes racemize by reversible thermal bond homolysis at 95 degrees C; racemization of these metallacycles is also catalyzed by mild oxidants. 相似文献
98.
Nineteen years have elapsed since Baule and McFee1 first recorded a biomagnetic field, that of the human heart. Progress during most of this time has been slow and the overall impact of biomagnetism is still small. However, a number of recent developments have demonstrated a research and clinical potential that has quickened interest in the area. A recent general review2 and a comprehensive volume of research papers3 together provide an excellent overview of the whole field and we shall refer frequently to both of them. A brief introduction should serve to establish the specific focus of the present review. 相似文献
99.
Tepavcevic S Zachary AM Wroble AT Choi Y Hanley L 《The journal of physical chemistry. A》2006,110(4):1618-1624
Conducting polymer films are grown by either mass-selected or non-mass-selected, hyperthermal thiophene ions coincident on a surface with a thermal beam of organic monomers of either alpha-terthiophene (3T) or p-terphenyl (3P) neutrals. Previous experiments verified polymerization of both 3T and 3P by 200 eV C(4)H(4)S(+) during surface polymerization by ion-assisted deposition (SPIAD). A wide variety of structures are observed by scanning electron microscopy to form in the SPIAD polythiophene and polyphenyl films. These structures include microscale islands, lamellar structures, fractal-like growth patterns, and nanoscale crystallites. Some of the deposited films diffract X-rays while others show electron micrographs of crystallites. The variation of these patterns with deposition conditions clearly indicate that ion-induced polymerization mediates film morphology through control of ion energy and ion/neutral ratio. Furthermore, these ion-assisted events mediate important thermal processes such as sublimation. 相似文献
100.
Moiz Ahmad Yinan Liu Zachary W. Slavens Russell Low Elmar Merkle Ken-Pin Hwang Anthony Vu Jingfei Ma 《Magnetic resonance imaging》2010
Sampling water and fat signals symmetrically (i.e., at 0° and 180° relative phase angles) in a dual-echo Dixon technique offers high intrinsic tolerance to phase fluctuations in postprocessing and maximum signal-to-noise performance for the separated water and fat images. However, identification of which image is water and which image is fat after their separation is not possible based on the phase information alone. In this work, we proposed a semiempirical automatic image identification method that is based on the intrinsic asymmetry between the water and fat chemical shift spectra. Specifically, the approximately bimodal feature of the fat spectra and the observation that most in vivo tissues are either predominantly water or predominantly fat are used to construct a spectrum-based algorithm. Additional refinement is accomplished by considering the spatial distribution of the tissues that may have a coexistence of water and fat. The final improved algorithm was tested on a total of 131 three-dimensional patient datasets collected from different scanners and found to yield correct water and fat identification in all datasets. 相似文献