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121.
The Influence of Au-Doping on Morphology and Visible-Light Reflectivity of TiN Thin Films Deposited by Direct-Current Reactive Magnetron Sputtering
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Ti, TiN and Au-TiN (Au content: from 0.5%to 7.7%) thin films were deposited on stainless steel substrates by dc reactive magnetron sputtering with a metal Ti target. The crystal structure, surface morphology and visiblelight reflectivity of the films for different film compositions are studied in detail. Distinctly different surface morphologies appear for the Ti, TiN and Au-TiN thin films. It can be observed that the surface morphology of the TiN film is affected by the Au-doping, when the Au content increases from 0% to 7.7%, surface roughness enlarges from 62.4 to 82.8 nm. Moreover, visible-light reflectivity varies significantly with increasing A u contents in the TiN films. However, the rettectivity of the TiN thin film at 550-800 nm is higher than that of the Au-TiN thin film. The present work illustrates the dependence of metal elements on the surface morphology and on the reflectivity of Au-TiN thin films. It is speculated that the addition of Au can suppress the formation and growth of TiN grains so that it changes the surface morphology and the Au-TiN thin film has potential applications in spectral selective coating. 相似文献
122.
CaMoO_4:Tb~(3+)发光材料的制备和发光性质的研究 总被引:1,自引:0,他引:1
用共沉淀法制备了样品CaMoO_4:Tb~(3+)的前驱物,经TG-DTA测试表明:样品在850℃时有能量吸收峰,即达到样品反应的活化点。XRD谱图分析显示,焙烧后样品CaMoO_4:Tb~(3+)为CaMoO_4的白钨矿结构,但峰位发生了右移,说明晶体内部产生了微小的晶体缺陷,推测该缺陷可能是由晶胞内2个Tb~(3+)取代了3个Ca~(2+)形成空穴而引发的。通过对激发谱图的测试发现,此种缺陷结构有利于使MoO_4~(2-)发射特征峰(488 nm)的能量有效地传递给Tb~(3+),使Tb~(3+)的4f电子发生跃迁,特别使Tb~(3+)的~7F_6→~5D_4(488 nm)电子跃迁大大加强,因而在样品CaMoO_4:Tb~(3+)的发射谱图(λ_(ex)=488 nm)中,自激活荧光体MoO_4~(2-)的发射强度被大大减弱,而Tb~(3+)的~5D_4→~7F_5(544 nm)跃迁的绿光发光强度被大大增强,使该材料成为有潜在应用价值的发光材料。 相似文献
123.
提出了一种基于图像特征提取和变换域相关的图像匹配方法。借助提取图像的大边缘信息,以其几何特征构造边缘方向角曲线作为图像匹配的依据。通过对差分的计算,并比较两幅图像边缘方向曲线的相对链码,得到2幅图像之间可能的旋转角度。对旋转矫正后的图像进行2维傅里叶变换,计算频域内2图的相位相关矩阵,并从中找到相关系数最大的位置,这个位置就代表了2图的坐标位移量,通过平移达到图像间的精确匹配。实验表明:该方法匹配准确,速度快,减少了人为因素的干扰,对于图像间存在较小灰度差和噪声情况均有很好的匹配效果。 相似文献
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Rosli AN Zabidi NA Kassim HA Shrivastava KN 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1251-1255
We have calculated the vibrational frequencies of clusters of atoms from the first principles by using the density-functional theory in the local density approximation (LDA). We are also able to calculate the electronic binding energy for all of the clusters of atoms from the optimized structure. We have made clusters of BanOm (n, m=1-6) and have determined the bond lengths, vibrational frequencies as well as intensities in each case. We find that the peroxide cluster BaO2 occurs with the O-O vibrational frequency of 836.3 cm(-1). We also find that a glass network occurs in the material which explains the vibrational frequency of 67 cm(-1). The calculated values agree with those measured from the Raman spectra of barium peroxide and Ba-B-oxide glass. We have calculated the vibrational frequencies of BaO4, GeO4 and SiO4 each in tetrahedral configuration and find that the vibrational frequencies in these systems depend on the inverse square root of the atomic mass. 相似文献
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127.
It is still a matter of debate to understand the equation of state of cold matter with supra-nuclear density in compact stars because of unknown non-perturbative strong interaction between quarks. Nevertheless, it is speculated from an astrophysical view point that quark clusters could form in cold quark matter due to strong coupling at realistic baryon densities. Although it is hard to calculate this conjectured matter from first principles, one can expect that the inter-cluster interaction will share some general features with the nucleon-nucleon interaction successfully depicted by various models. We adopt a two-Gaussian component soft-core potential with these general features and show that quark clusters can form stable simple cubic crystal structure if we assume that the wave function of quark clusters have a Gaussian form. With this parametrization, the Tolman-Oppenheimer-Volkoff equation is solved with reasonably constrained parameter space to give mass-radius relations of crystalline solid quark stars. With baryon number densities truncated at 2n0 at surface and the range of the interaction fixed at 2 fm we can reproduce similar mass-radius relations to that obtained with bag model equations of state. The maximum mass ranges from 0.5M⊙ to 3M⊙. The recently measured high pulsar mass ( 2M⊙) is then used to constrain the parameters of this simple interaction potential. 相似文献
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129.
纳米氢氧化钴原位修饰碳糊电极固-液微萃取及电化学检测辛硫磷 总被引:1,自引:0,他引:1
运用纳米氢氧化钴原位修饰碳糊电极微分脉冲伏安(DPV)法检测了辛硫磷。在外加电位下辛硫磷分子被萃取到电极表面,并与纳米氢氧化钴相互作用形成络合物,在-0.489 V处得到1还原峰,且还原峰电流随扫速线性增长,表明电极上的还原过程受吸附控制。吸附过程满足Temkin等温吸附模型。pH与电位的关系表明辛硫磷的还原过程为1电子1个质子反应。运用交流阻抗方法考察了反应过程,并辅以理论计算,表明反应为自发过程,计算结果与循环伏安法一致。采用该体系检测辛硫磷,其还原峰电流与辛硫磷浓度的对数分别在3.333×10~(-13)~3.333×10~(-8) mol/L和3.333×10~(-8)~3.333×10~(-6) mol/L范围内呈线性关系,检出限(S/N=3)可达3.333×10~(-13) mol/L。该方法具有良好的重现性及选择性,用于菠菜中辛硫磷农药的检测,结果满意。 相似文献
130.