粘弹性胶层中Ⅰ型裂纹的动态扩展

研究粘弹性胶层中Griffith裂纹在Ⅰ型载荷作用下,裂纹尖端动态应力强度因子和能量释放率的时间响应.首先,利用积分变换方法,推导出粘弹性层的控制方程组;其次,引入位错密度函数,并结合边界条件和界面连接条件,导出反映裂纹尖端奇异性的Cauchy型奇异积分方程组,然后,应用Chebyshev正交多项式化奇异积分方程组为代数方程组,并采用Schmidt方法对其数值求解,最后,经过Laplace逆变换,求得动态应力强度因子和能量释放率的时间响应.通过对材料参数的讨论,得到动应力强度因子和能量释放率随剪切松驰参量的减小而增大,随膨胀松弛参量的减小而减小,弹性参数对其影响较小.     

Synthesis of Micro-Mesoporous Ti-MOR/Silica Composite Spheres in Oil-in-Water Microemulsion System

The hierarchically structured micro-mesoporous spheres(MMS) composed of mesoporous silica and Ti-containing mordenite (Ti-MOR) zeolite were self-assembled in an oil-in-water microemulsion system containing tetrabutyl orthosilicate as silica source, cetyltrimethylammonium bromide as template and aluminum sulfate as additive. The composite materials possessed the connatural microporosity of zeolite together with the disordered mesopores(5.41 nm) in silica part. With a special focus on the importance of aluminum sulfate additive, a possible formation mechanism has been proposed, in which double electrostatic interactions played the crucial role of mediating the mesosilica species and zeolite crystals. The obtained MMS materials, with a tunable particle dimension(250-720 μm) and a changeable content of active component Ti-MOR(44%-70%), showed enhanced catalytic activity and lifetime in the liquid-phase ammoximation of cyclohexanone in comparison to the parent Ti-MOR powder.     

一种新的求解线性方程组的外推加速方法

本文提出两种优化模型, 通过在子空间{x^(k),…, x^(k-m)}上寻找最优解, 建立了一种新的外推加速方法. 讨论了该方法的收敛性和收敛速度. 最后, 通过三个数值实例展示了算法是可行的和有效的.     

利用模式识别技术识别鱼肉的鲜度

利用模式识别技术与紫外分光不镀分析法结合，根据鱼肉中的肌苷酸和肌苷的含量对鱼肉鲜度进行了识别，采用人工神经网络法和逐步判别分析法两种模式识别技术，判别结果令人满意。     

高效的CdS/Ti-Fe2O3异质结光阳极:研究Z型电荷迁移机制增强光电化学水氧化活性

近年来以Z型机制为转移的光催化体系成微光电化学分解水领域的研究热点.相比较传统的异质结,Z型异质结能够保留具有高氧化能力与高还原能力的位点,从而提高光电化学效率.其中,证明电荷的Z型迁移机制成为研究人员努力的方向,比较有效的证明方法包括自由基捕获、XPS分析和检测还原位点等.对于Z型异质结,界面电场处电荷的迁移行为是至...     

三重积分变换公式的一个新证法

作为Gauss公式的一个应用,本文将对三重积分变换公式给出一个新的证明方法.     

Fabrication of microrods and microtips of InP by electrochemical etching

Here we presented a simple approach to fabricate the microstructures of InP by electrochemical etching. Microrods were formed while InP etched in 7 M HCl solutions for 30 s, and microtips were obtained while InP etched for 120 s. In addition, with increasing applied potential the surface of the microrods became smoother. The formation mechanism was also discussed in this article.     

氧碘化学激光器故障诊断技术

为了解决氧碘化学激光器通过常规诊断故障定位困难的问题,采用建立的氧碘化学激光器功率失常故障树模型,结合氧碘化学激光器常用的8个监测参数：碘腔压力、碘文氏管压力、p-t曲线、主氦压力、氯气压力、氧发生器压力、上游压力和光腔压力,提出采用故障树和在线监测参数相结合的办法,基于3法则的判断标准对氧碘化学激光器进行故障诊断,故障诊断正确率达到94.5%,并对出现的故障提出了改进措施。     

The rapid determination of artemisinin by post-column derivatization high-performance liquid chromatography using matrix solid-phase dispersion method

Artemisinin (an antimalaric compound) is isolated as the active compound of the medicinal plant Artemisia annua L. A simple, rapid, and high-efficient method of extraction is developed, in which it is extracted by matrix solid-phase dispersion (MSPD) and directly analyzed by post-column derivatization high-performance liquid chromatography (HPLC). The quantitation results from the MSPD method are compared with two conventional liquid solvent extraction processes, Soxhlet and ultrasonic wave by F-test, and the result indicates no significant difference. The production rate of Artemisinin during wild plant growth (tested over two years, acquired from Yunnan, provincial Yuan Yan country) is determined. The recovery range of determination is 88.1-91.2%. The relative standard deviation (RSD) is 4.55-6.43%. The limits of detection are 0.1 microg/mL, and the limits of quantitation are 0.5 microg/mL.     

Ho~(3+)∶La_2CaB_(10)O_(19)晶体生长和光谱性能(英文)

采用顶部籽晶法生长Ho3+∶La2CaB10O19晶体。测试了晶体的X射线衍射谱图以及晶体器件的摇摆曲线,半峰宽为21.6 arcsec,晶体结晶质量良好。在室温下测试了吸收光谱、发射光谱和荧光寿命。应用Judd-Ofelt理论评价了Ho3+∶La2CaB10O19晶体的光谱性能。分别计算了Ho3+的唯象强度、谱线强度、辐射寿命、荧光分支比等参数。