PH, PD和PT分子常数理论研究

采用内收缩多参考组态相互作用(MRCI)方法和包含Davidson修正(+Q) 的MRCI方法结合相关一致基aug-cc-pV5Z研究了PH (X³Σ^-, a¹Δ和A³∏)分子的势能曲线. 在同位素质量识别的基础上对势能曲线进行拟合, 得到PH, PD和PT分子各个电子态的光谱常数(T_e, R_e, ω_e, ω_ex_e, α_e和 B_e). 通过与已有实验数据的比较发现, 本文的结果与实验结果非常一致. 对于PH, PD和PT分子的Σ^-电子态, 计算得到了J = 0时的前12个振动态. 对于每一个振动态, 还分别计算了它的振动能级、惯性转动常数和离心畸变常数. 与其他理论结果和实验数据进行比较可知, 本文的结果更精确、更完整. 文中PD和PT分子的光谱常数和分子常数均属首次报导.     

模拟短脉冲激光在介质中传输的扩散综合有限元法

建立有限元模型,通过求解瞬态辐射传输方程模拟短脉冲激光在半透明介质中的传输.针对散射占优性半透明介质内辐射传输求解效率较差的问题,采用扩散综合加速迭代算法,提高计算效率,缩短计算时间.结果表明:采用精确解析式描述脉冲激光散射源项的求解策略可以获得准确的计算结果,精确地模拟快速变化的波前,不会产生数值扩散和数值振荡.此外,扩散综合迭代算法的计算时间仅为源项迭代的50%~60%.     

Cr(Ⅶ)到Cr(Ⅳ)松针吸附转化的紫外-可见光谱

分光光度法研究了强酸性介质中松针对Cr()的吸附与转化过程。探讨了干松针的用量,反应时间,K2Cr2O7浓度对转化率的影响。在优化的条件下,K2Cr2O7溶液经松针处理6h后的转化率为91.96%,转化的表观一级反应速率常数为0.008764min-1,K2Cr2O7的浓度在0.2—0.4mmol/L范围内受吸附控制,0.4—1.5mmol/L转化受化学反应控制。为天然生物质吸附转化Cr()的污染治理提供新途径。     

基于Lissajous图技术的波长移相标定方法

波长移相干涉仪可应用于大口径光学元件的检测。研究了基于Lissajous图技术的波长移相标定方法,实现了干涉图间移相量的计算,解决了在不同干涉腔长下进行测试时移相量需控制成为一个特定值的问题。首先通过模拟仿真,验证了方法的正确性;然后编写程序对已知移相量的实际干涉图进行计算。结果表明,在干涉图对比度较好以及对计算的两点选择恰当的情况下,计算出的相对误差在4%范围内。     

Electromagnetic Transition Rates and Deformation Feature in 130Ce

Lifetimes of the excited states in light rare-earth nucleus ¹³⁰Ce have been measured using heavy ion reaction ¹¹⁶Sn(¹⁶O,2n)¹³⁰Ce at beam energy of 73MeV through analyzing the Doppler-broadened line shapes. The reduced transition probabilities B(E2) are extracted from these measurements. The experimental results show that the previously reported anomalously high B(E2) value has not been observed in the present work. The transition quadrupole moment for the yrast band varies with spin and corresponds to a triaxial deformation with γ≈7°.     

Relative position determination of a lunar rover using high-accuracy multi-frequency same-beam VLBI

Multi-frequency same-beam VLBI means that two explorers with a small separation angle are simultaneously observed with the main beam of receiving antennas. In the same-beam VLBI, the differential phase delay between two explorers and two receiving telescopes can be obtained with a small error of several picoseconds. The differential phase delay, as the observable of the same-beam VLBI, gives the separation angular information of the two explorers in the celestial sphere. The two-dimensional relative position on the plane-of-sky can thus be precisely determined with an error of less than 1 m for a distance of 3.8×105 km far away from the earth, by using the differential phase delay obtained with the four Chinese VLBI stations. The relative position of a lunar rover on the lunar surface can be determined with an error of 10 m by using the differential phase delay data and the range data for the lander when the lunar topography near the rover and the lander can be determined with an error of 10 m.     

应用荧光光谱和径向基函数神经网络定量检测三聚氰胺

实验发现三聚氰胺溶液在紫外光激发下产生较强荧光,测得其荧光峰在310～600 nm之间,荧光峰值波长为420 nm左右,荧光相对强度与三聚氰胺溶液浓度呈现复杂的非线性关系。提出了采用径向基函数神经网络结合荧光光谱对三聚氰胺溶液浓度进行测定的方法。对每个样本选取30个发射波长值所对应的荧光强度作为网络数据,训练、建立了径向基函数神经网络。应用训练好的径向基函数神经网络,对5种三聚氰胺溶液的浓度进行预测,结果相对误差分别为0.93%,0.09%,0.31%,1.55%,4.61%。该方法能快捷、准确地测定三聚氰胺在溶液中的含量,为三聚氰胺检测及食品安全监管提供了一种新方法。     

立体显示中的垂轴放大率

为消除立体影像的畸变需研究拍摄再现立体影像的垂轴放大率。重新推导了立体影像拍摄再现的总垂轴放大率公式,在该公式中增加了一个观看再现放大率系数,立体影像的观看再现垂轴放大率为像距与观看距离之比。实验结果验证了理论的正确性,该公式对于进一步研究再现立体影像的消畸变具有重要作用。     

在不同压力下研究巨磁电阻氧化物的响应特性

本文主要介绍利用自主设计的拉压实验平台对巨磁电阻阻值随外界压力的变化情况进行研究。通过在不同的压力下测量巨磁电阻的伏安特性,得到一些结论,为以后进一步的研究开辟新方法新理念。     

A New Solution to Detectable Byzantine Agreement Problem

We present a new quantum protocol for solving detectable Byzantine agreement problem between three parties by employing one quantum key distribution protocol. The protocol is suggested by a special four-qubit entangled state instead of singlet states, which shows that singlet states are not necessary to achieve detectable Byzantine agreement.