Effect of High Temperature Annealing on Conduction-Type ZnO Films Prepared by Direct-Current Magnetron Sputtering

We experimentally find that the ZnO thin films deposited by dc-magnetron sputtering have different conduction types after annealing at high temperature in different ambient. Hall measurements show that ZnO films annealed at 1100℃ in N2 and in 02 ambient become n-type and p-type, respectiveIy. This is due to the generation of different intrinsic defects by annealing in different ambient. X-ray photoelectron spectroscopy and photolumineseence measurements indicate that zinc interstitial becomes a main defects after annealing at 1100℃ in N2 ambient, and these defects play an important role for n-type conductivity of ZnO. While the ZnO films annealed at 1100℃ in O2 ambient, the oxygen antisite contributes ZnO films to p-type.     

Optimization of Experimental Discharge Parameters to Increase the Arc Efficiency of the Bucket Ion Source

Arc efficiency is a critical criterion for assessing the performance of the ion source. High are efficiency is necessary for a high power ion source, because it can decrease the load of the arc power supply. Thus the relationship between the discharge parameters （gas pressure, arc voltage, filament current, bias resistance connecting between the anode and plasma grid） and the arc efficiency is investigated in experiment especially. It is found that with increasing pressure, the arc efficiency increases fast if the pressure is below 0.4 Pa, but when it is above 0.4 Pa, the arc efficiency remains unchanged or increases slowly. If we increase the arc voltage or filament current, the arc efficiency decreases. The bias resistance also influences the arc efficiency, at the same pressure the arc efficiency increases with resistance.     

SiP化合物结构和电子特性的第一性原理研究

应用第一性原理方法研究了SiP化合物的结构和电子特性,并且将研究推广到其他第四族元素磷化物(IV-P).在研究的各种结构中,SiP单斜晶体结构是能量最低、最稳定的结构.SiP的体弹性模量比CN和CP化合物以及相对应的第三族元素氮化物和磷化物要小.SiP不同的结构间能发生相变,其单斜晶体结构(monoclinic)在压强为6.2 GPa, 15.0 GPa, 19.3 GPa, 20.0 GPa 和 10.3 GPa时分别转变成GeP型结构、Rhom.型结构、β-InS型结构、 CsCl型结构和NaCl型结构.能带计算结果显示SiP单斜晶体结构(monoclinic)和GaSe型结构是间接带隙分别为1.123 eV 和 0.123 eV的半导体,SiP其他结构则显示出金属特性.其他化学比为1:1的第四族元素磷化物(IV-P)具有相同的性质.     

复Finsler子流形的全纯曲率

设M为n维复流形,F为M上的强拟凸的复Finsler度量,M是M的m维复子流形,F是F在M上诱导的复Finsler度量,D为（M,F）上的复Rund联络．本文证明了（1）（M,F）上的诱导复线性联络△↓的全纯曲率与（M,F）上的复Rund联络△↓^＊的全纯曲率相同;（2）联络△↓^＊的全纯曲率不超过联络D的全纯曲率;（3）（M,F）是（M,F）的全测地复Finsler子流形的充分必要条件是（M,F）的第2基本形式B（．,．）的适当形式的缩并为零,即B（x,l）=0．本文的证明主要利用复Finsler子流形（M,F）的Gauss,Codazzi和Ricci方程．     

Three novel zinc(II) sulfonate-phosphonates with tetranuclear or hexanuclear cluster units

Hydrothermal reactions of zinc(II) carbonate with m-sulfophenylphosphonic acid (m-HO3S-Ph-PO3H2) and 1,10-phenanthroline (phen) or 4,4'-bipyridine (bipy) lead to three novel zinc(II) sulfonate-phosphonates, namely, [Zn(phen)3]2[Zn4(m-O3S-Ph-PO3)4(phen)4].20H2O (1), [Zn6(m-O3S-Ph-PO3)4(phen)8].11H2O (2), and [Zn6(m-O3S-Ph-PO3)4(bipy)6(H2O)4].18H2O (3). Compound 1 contains a tetranuclear zinc(II) cluster anion in which four Zn(II) ions are bridged by two tetradentate and two bidentate phosphonate groups, and the four negative charges of the cluster are compensated by two [Zn(phen)3]2+ cations. Compound 2 features a hexanuclear zinc(II) cluster in which the same tetranuclear cluster of 1 is bridged with two additional Zn(II) ions. The structure of 3 features a porous 3D network based on hexanuclear zinc(II) units of [Zn6(m-O3S-Ph-PO3)4] interconnected by 4,4'-bipy ligands. The hexanuclear cluster in 3 is different from that in 2 in that all four phosphonate groups in 3 are tridentate bridging. Compounds 1, 2, and 3 exhibit broad blue fluorescent emission bands at 378, 409, and 381 nm, respectively.     

一类分式线性变换群的有限子群

证明PGL(2,Q)中仅有17个系数形如m n p的分式线性变换有限子群并且决定了它们的构造,其中m,n是整数,p是素数.     

基于溢出效应与平台服务的竞争网络平台的销售模式研究

网络平台竞争与发展成为平台运营理论与实践的关键问题,急需解决。本文应用博弈论研究存在溢出效应和网络平台竞争环境下平台服务内生的网络平台销售模式选择,即网络平台商是允许制造商在其网络平台上直销产品的平台销售模式,还是网络平台商先从制造商购买产品再销售给消费者的转销模式。主要研究竞争网络平台的三种结构模型:双转销模式、双平台销售模式和混合模式。研究结果显示:网络平台商的利润随正溢出效应增加而增加,随负溢出效应增加而减少。当网络平台服务敏感程度较高且网络平台竞争较为激烈时,两个网络平台商均选择平台销售模式,形成占优均衡;此时,网络平台商获得最高利润,而且网络零售价和网络平台服务水平最高。     

混沌时滞随机神经网络同步控制

研究了一类混沌时滞随机神经网络同步控制问题．采用更具一般性的时滞反馈控制器,通过巧妙地构造Lyapunov数,分别得到了均方指数同步和均方渐近同步两个判别准则．仿真例子表明,新准则是有效的．     

S~5上仿Blaschke张量的特征值为常数的超曲面

设x:M→S~(n+1)是(n+1)-维单位球面上不含脐点的超曲面,在S~(n+1)的Moebius变换群下浸入x的四个基本不变量是:一个黎曼度量g称为Moebius度量;一个1-形式Φ称为Moebius形式;一个对称的(0,2)张量A称为Blaschke张量和一个对称的(0,2)张量B称为Moebius第二基本形式.对称的(0,2)张量D=A+λB也是Moebius不变量,其中λ是常数,D称为浸入x的仿Blaschke张量.李海中和王长平研究了满足条件:(i)Φ=0;(ii)A+λB+μg=0的超曲面,其中λ和μ都是函数,他们证明了λ和μ都是常数,并且给出了这类超曲面的分类,也就是在Φ=0的条件下D只有一个互异的特征值的超曲面的分类.本文对S~5上满足如下条件的超曲面进行了完全分类:(i)Φ=0,(ii)对某常数λ,D具有常数特征值.     

Banach代数直和上的乘子及其谱理论

主要讨论了Banach代数A的直和A(?)A上乘子的表示;利用其表示得到A(?)A上乘子的谱理论的系列结果;最后还利用乘子的表示得到关于强不可约算子的一个结论.