多电子原子和离子的等电子系参数的研究(Ⅱ)——跃迁概率与振子强度的计算

应用我们提出的k系数校正方法,使用最弱受约束电子势模型下的简单解析波函数,则等电子系各成员的跃迁结果只随核电荷数Z变化。由此,非常方便地进行了LiI跃迁概率和3电子系振子强度的计算,与量子亏损方法相比,不但能够反映出等电子系跃迁的规律性,而且结果具有相当好的精度。表明结合k系数校正的最弱受约束电子势模型方法,有利于等电子系规律的研究。 关键词：     

Czochralski晶体生长中非定常热对流过程的数值模拟

本文应用有限控制体算法,采用中心差分格式处理具有Boussinesq近似的N-S方程的对流和扩散通量项,计算了无坩埚和籽晶旋转情况下CZ晶体生长中熔体的非定常自然对流。数值计算的结果得到了某些典型时刻的流场结构和温度分布情况。结合计算得到的CZ熔体总动能和总热能随时间变化的规律,分析了流场和温度场的不稳定变化过程。此外,计算结果还给出了在非稳定热对流影响下的晶-液界面热通量的变化。非定常计算的结果对于研究自然对流和CZ单晶生长,具有理论和实际意义。 关键词：     

Hawking效应是坐标尺度变换下的补偿效应

从新的角度尝试发展了Weyl的规范不变理论。黑洞物理学中的Hawking效应普遍可以看作坐标尺度变换下的补偿效应。相应的量子温度是补偿场的纯规范势。 关键词：     

2-(1或2萘基)苯并噁唑的电子结构与光物理性质

本文用PPP-SCF-CI法对2-(1或2萘基)苯并噁唑及其Z、E同分异构体的电子结构及紫外光谱进行了理论研究,讨论了各分子的光谱特性,解析了对应于实验的不同异构体紫外吸收光谱,找到了该分子体系的主要生色团,理论计算与实验结果的偏差约在1%以内。这为深入研究苯并噁唑类分子的光物理性质、进一步预测具有更好性能的新型材料提供了理论依据。     

新型有机电致磷光白光器件的研究

制备了结构为ITO/NPB/TCTA/FIrpic∶TCTA/Ir(MDQ)2(acac)∶TmPyPB/FIrpic∶TmPyPB/TmPyPB/LiF/Al的有机电致磷光发光器件。通过在双蓝光发光层之间插入较薄的红光层Ir(MDQ)2(acac)∶TmPyPB调节载流子、激子在各发光层中的分布,并结合TCTA和TmPyPB对发光层内载流子和激子的有效阻挡作用,混合实现白光发射。研究了红光层在不同厚度、不同掺杂浓度下对器件发光性能的影响。结果表明,红光发光层厚度为2nm、质量浓度为5%时,结合蓝光发光层和红光发光层,实现了色坐标为(0.333,0.333)、最大发光效率为11.50cd/A的白光发射。     

290 AMeV 12C诱发乳胶核反应末态粒子多重数关联

对290 AMeV 12C诱发乳胶核反应末态粒子间的多重数关联进行了研究。实验结果表明:黑径迹粒子、灰径迹粒子、重电离粒子多重数之间存在较强的关联,而且黑径迹粒子和重电离粒子多重数有饱和的趋势,这些特征与高能区实验结果一致;簇射粒子与其他粒子间的关联性较弱,这一特征与高能区实验结果不同,主要归因于弹核能量较低、簇射粒子产额较小;黑径迹粒子、灰径迹粒子在前后半球的平均多重数随靶核的增大而增加;实验结果可用基于碰撞几何的旁观体-反应体模型及级联蒸发模型来解释。We have investigated the multiplicity correlation of particles produced in 12C-emulsion interactions at 290 AMeV. It is found that there is a strong correlation between black track particle, grey track particle and heavily ionized track particle, and finally black track particles and heavily ionized track particles tend to saturation, which is the same as the experimental results observed at high energies. The multiplicity correlation between shower particle and other particles is weaker, which is different from the experimental results observed at high energies. This discriminating character can be explained by the lower energy of projectile. The productivity of shower particle is lower at intermediate energies compared to that at high energies. The forward-backward averaged multiplicity of black track particle and grey track particle increases with the increasing target size.     

氢化物发生-原子荧光光谱法测定铜精矿中的砷、锑和铋

建立了氢化物发生-原子荧光光谱法同时测定铜精矿中砷、锑、铋的方法,采用了主量元素匹配法来消除基体干扰,优化了反应体系的酸度、还原剂浓度等条件进行了优化。砷、锑、铋的浓度在1—200μg·L~(-1)范围内与荧光强度呈线性关系。方法回收率为92%—101%,相对标准偏差为2.7%—5.5%。     

常压MOCVD生长Ga2O3薄膜及其分析

以去离子水(H₂O)和三甲基镓(TMGa)为源材料,用常压MOCVD方法在蓝宝石(0001)面上生长出β-Ga₂O₃薄膜.用原子力显微镜(AFM)、X射线衍射(XRD)以及二次离子质谱(SIMS)实验表征Ga₂O₃外延膜的质量.在X射线衍射谱中有一个强的Ga₂O₃(102)面衍射峰,其半峰全宽(FWHM)为0.25°,表明该Ga₂O₃外延膜是(102)择优取向.在二次离子质谱中除了C、H、O和Ga原子外,没有观测到其他原子.     

Elastic Transfer Reactions of 25MeV/u 6He on 9Be Target

Angular distributions for elastic transfer in the ⁶He+⁹Be system were measured at the incident ⁶He laboratory energy of E=150MeV. From a distorted-wave Born approximation (DWBA) analysis,³He spectroscopic amplitude in ⁹Be were extracted and compared with values obtained by shell model calculations. The result shows that the spectroscopic amplitude is much greater than 0.70.     

高纯锗探测器的广泛应用和自主研制进展

以目前国际上极为活跃开展的暗物质探测、无中微子双 衰变研究为例,评述了高纯锗探测器的重要性及其广泛的应用前景。介绍了己开展的高纯锗单晶、探测器制备的关键技术研究进展:合作单位已研制出了用于高纯锗单晶材料制备的区熔炉、单晶炉;并制备出直径为20  50 cm、纯度为12N(< 41011  atoms/cm3)、位错< 5000 atoms/cm2 的锗单晶;掌握了高纯锗探测器(平面型、同轴型)制备的关键技术,用进口高纯锗单晶材料制备出的同轴型高纯锗探测器对射线的能量分辨率及探测效率均达到进口产品指标,使用自制的12N 高纯锗单晶材料己制备出平面型高纯锗探测器。呼吁加速高纯锗研制的自主创新步伐,尽早实现其国产化目标。The article reviews importance and wide applications of HPGe detector, especially the application on the dark matter search experiment and double beta decay experiment. The research progress on the Highpurity germanium single crystal and HPGe detector in China has been introduced. The cooperation partner developed new type zone-refining furnace and single crystal furnace. The ultra-purity germanium single crystal with 20~50 cm, purity up to 12N(net impurity concentration is less than 41011 atoms/cm3), and dislocation less than 5 000 /cm3 was prepared. The key technologies for preparing planar and coaxial HPGe detector were mastered. The coaxial detector, which has been made of imported ultra-purity germanium single crystal has excellent energy resolution and efficiency as the imported commercial detector. The planar detector using selfmade germanium single crystal was also successfully manufactured. The research group appeals for speeding up the pace of independent innovation on the high-purity germanium, and achieving the high-purity germanium localization as soon as possible.