二氧化钛纤维表面担载Pt纳米结构的原子力显微镜研究

通过原子力显微镜研究了二氧化钛纤维表面担载Pt的表面形貌及其结构.结果表明,TiO2纤维表面担载的Pt具有微米尺度的近似六边形或者近似长方形的结构,与在单晶TiO2(110)表面的Pt纳米簇形貌相似,但尺度较大.TiO2纤维担载的Pt表面明显存在不同高度的台阶结构,台阶高度以2~4倍Pt(111)晶面面间距的高度为主.由Pt在TiO2纤维表面的形貌与纤维的纳米晶粒排布有序性推测可知,Pt与TiO2纤维存在强的相互作用,可能正是这种强相互作用和表面台阶结构才使TiO2表面担载的Pt虽是微米尺寸但仍具有高光催化活性.     

连接基团链长度对季铵盐二聚表面活性剂C12-s-C12·2Br在水溶液中胶团化行为的影响

用电导法、稳态荧光法和粘度法研究了二聚表面活性剂C12-s-C12*2Br分子中的连接基团链长度(s=2, 3, 4, 6)对其在水溶液中聚集行为的影响. 实验发现, C12-s-C12*2Br的胶团生成能力远比其单体C12TABr强得多, 前者cmc值较后者降低一个数量级. 胶团聚集数N随表面活性剂浓度c的增大而增大, 其中当s=2时的N值在c=7.7 mmol/L后开始急剧增大. 计算结果表明, 此时胶团形状发生了明显变化, 形成了椭球形的胶团. 粘度测定结果也证实了这一点.     

[Ni(en)3]4[HVⅣ12VⅤ6O42(PO4)]复合物的合成及晶体结构

A new complex [Ni(en)₃]₄[HV^Ⅳ₁₂V^Ⅴ₆O₄₂(PO₄)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system,space group Im 3m with a=17.4081(2)?, V=5275.38(10)?³, R=0.0420, wR=0.1055, Z=2, D_c=1.663g·cm^-3, μ=2.297mm^-1, F(000)=2636. The crystal structure consists of [Ni(en)₃]²⁺ cations and {HV₁₈O₄₂(PO₄)}^8- cluster anion which construct from 18 {VO₅} square pyramids. The VO₅ pyramids joined each other to form a {V₁₈O₄₂} cage hosting a tetrahedral {PO₄}^3- moiety with disordered oxygen atoms. CCDC: 185574.     

GIF S-亚硝基化的一些见解

Neural growth inhibitory factor （GIF）, a member of metallothionein family （metallothionein-3, MT3）, was well known by its distinct neural growth inhibitory activity, which is not shown by other MT isoforms. However, till now, people still did not know clearly how GIF exerts its biological functions. Since it has been reported that GIF might serve as NO scavenger and was related to the release of zinc, our study was focused on the interaction of GIF and NO. By studying the reactions of human GIF and human MTlg with SNOC-a type of NO donor, it was found that GIF was more reactive than MT-lg toward SNOC. In order to further figure out if the high reactivity of GIF in this reaction resulted from the acid-base catalysis, several mutants were constructed： E23K, E41G/E43A, E23K/E41G/E43A. By studying their basic properties and the reactions toward SNOC, it was found that the S-nitrosylation of GIF was not only related to the acid-base catalysis, but also to the accessibility of metal-thiolate clusters.     

1-(4-硝基苯)-3-(3-甲基吡啶)-三氮烯合成及其与铜的显色反应

报道了新显色剂 1-(4-硝基苯)-3-(3-甲基吡啶)-三氮烯(NPMPDT)的合成及其与铜的显色反应.在OP的存在下,pH 10.5的Na2B4O7-NaOH缓冲溶液中,该试剂能与铜发生显色反应,铜与NPMPDT形成摩尔比为2∶1型的黄色配合物,在460 nm处有一最大正吸收,在535 nm 处有一最大负吸收.以460 nm为参比波长,535 nm为测量波长进行双波长测定,其表观摩尔吸光系数ε＝2.18×105 L·mol-1·cm-1,铜的质量浓度在0～0.48 μg/mL 范围内符合比尔定律,用本法测定大米和面粉中微量的铜,结果满意.     

Synthesis and Crystal Structure of Organocobalt(III) Complexes with Secondary Alkyls or Bulky Schiff Base Equatorial Ligands

Alkylcobalt(III) Schiff base B(12) model complexes with secondary alkyls or a bulky diamine in the equatorial position were synthesized and characterized. Structures have been first determined by X-ray diffraction analysis for i-C(4)H(9)Co(salen)(gamma-pic) (I), n-C(3)H(7)Co(salen)(gamma-pic) (II) and C(2)H(5)Co(SB) (III), where salen = N,N'-ethylenebis(salicylideneamine) dianion; SB = 1,1,2,2-tetramethyl-N,N'-ethylenebis(salicylideneamine) dianion, gamma-pic = gamma-picoline. Crystal data for I (CoC(26)N(3)O(2)H(30)): space group P2(1)/c with a = 6.661(5) ?, b = 18.612(2) ?, c = 19.533(3) ?, beta = 98.93(1) degrees, V = 2392.10 ?(3), D(calcd) = 1.320 g.cm(-3), Z = 4, and R = 0.048 for 4469 measured reflections. Crystal data for II (CoC(25)N(3)O(2)H(28)): space group P2(1)/c, a = 9.609(6) ?, b = 19.169(8) ?, c = 12.995(9) ?, beta = 106.9(7) degrees, V = 2290.4 ?(3), D(calcd) = 1.332 g.cm(-1), Z = 4, and R = 0.048 for 4358 measured reflections. Crystal data for III (CoC(22)N(2)O(2)H(27)): space group P2(1)/c, a = 8.318(3) ?, b = 21.579(2) ?, c = 11.572(2) ?, beta = 93.35(1) degrees, V = 2073.7 ?(3), D(calcd) = 1.314 g.cm(-1), Z = 4, and R = 0.060 for 3954 measured reflections. The crystal structure data reveal that complexes I and II display six-coordinate octahedral geometry; their Co-C, Co-N bond lengths, as well as the Co-C-C angles, are very close to those in 5'-deoxyadenosylcobalamin. Complex III is one of the very few compounds having five-coordinate square pyramidal geometry and observed instability of the Co-C bond.     

食物中的钼与人体健康

综述了食物中钼与人体健康之间的关系.主要包括常见食物中的钼含量,钼在人体中的代谢,钼的生物学功能以及钼对人体健康的影响等.     

CH2F2…H2O中强π型二级氢键

通过从头计算,用较大基组６－３１１＋Ｇ(２ｄ,２ｐ),在ＭＰ２水平上计算得到ＣＨ２Ｆ２…Ｈ２Ｏ体系的优化几何构型,与实验结构一致．其中∠Ｆ…Ｈ－Ｏ＝１１６．５°,偏离普通氢键之键角达到６３．５°．为探讨产生氢键巨大弯曲的原因,采用点电荷扫描的办法,探测ＣＨ２Ｆ２…Ｈ２Ｏ体系中Ｈ２Ｏ的Ｏ原子上的两对孤电子对的方向,发现了一个强的π型二级氢键相互作用．使用这种新的相互作用方式说明了产生这一巨大氢键弯曲的原因,并且在ＭＰ４水平上使用Ｃｏｕｎｔｅｒｐｏｉｓｅ技术计算了π型二级氢键的稳定化能．     

凝胶渗透色谱法测定聚丙烯腈共聚物分子量中宽分布校正法的应用

应用宽分布校正法对凝胶渗透色谱(GPC)进行了校正，将校正曲线用于聚丙烯腈(PAN)共聚物分子量的计算。对扣除色谱峰扩展效应前后的测试结果与乌氏粘度法测得的数据进行比较。结果表明，应用宽分布校正法时，必须扣除色谱峰扩展效应，才能得到较为准确的测试结果。     

Synthesis of Molecularly Imprinted Polymer Particles by Suspension Polymerization in Silicon Oil

Molecular imprinting is a method to prepare polymers with recognition site of desired and predetermined selectivity1. Molecularly imprinted polymers (MIP) are prepared by copolymerizing functional and cross-linking monomers in the presence of a molecular …