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81.
对给定的简单图$H_1,H_2,\ldots,H_c$, 我们将使完全图$K_n$的任意边分解$\{G_i\}^c_{i=1}$都存在至少一个$G_i$有子图同构于$H_i$的最小正整数$n$称为多染色拉姆齐数 $R(H_1,H_2,\ldots,$ $H_c)$. 对正整数$m,n_1,n_2,\ldots,n_c$, 令$\Sigma=\sum_{i=1}^{c}(n_i-1)$. 在文献中,我们已经获得了$R(K_{1,n_1},\ldots,K_{1,n_c},P_m)$ 的一些界和精确值.Wang推测若$\Sigma\not\equiv 0\pmod{m-1}$且$\Sigma+1\ge (m-3)^2$, 则有$R(K_{1,n_1},\ldots, K_{1,n_c}, P_m)=\Sigma+m-1.$ 本文中, 我们给出了一个新的下界并给出$R(K_{1,n_1},\ldots,K_{1,n_c},P_m)$在$m\leq\Sigma$, $\Sigma\equiv k\pmod{m-1}$且$2\leq k \leq m-2$情况下的部分精确值. 这些结果部分证实了Wang的猜想. 相似文献
82.
83.
Lin Li Hongliang Wang Jun Ye Yankun Chen Renyun Wang Dujia Jin Yuling Liu 《Molecules (Basel, Switzerland)》2022,27(14)
Surface charge polarity and density influence the immune clearance and cellular uptake of intravenously administered lipid nanoparticles (LNPs), thus determining the efficiency of their delivery to the target. Here, we modified the surface charge with ascorbyl palmitate (AsP) used as a negatively charged lipid. AsP-PC-LNPs were prepared by dispersion and ultrasonication of AsP and phosphatidylcholine (PC) composite films at various ratios. AsP inserted into the PC film with its polar head outward. The pKa for AsP was 4.34, and its ion form conferred the LNPs with negative surface charge. Zeta potentials were correlated with the amount and distribution of AsP on the LNPs surface. DSC, Raman and FTIR spectra, and molecular dynamics simulations disclosed that AsP distributed homogeneously in PC at 1–8% (w/w), and there were strong hydrogen bonds between the polar heads of AsP and PC (PO2−), which favored LNPs’ stability. But at AsP:PC > 8% (w/w), the excessive AsP changed the interaction modes between AsP and PC. The AsP–PC composite films became inhomogeneous, and their phase transition behaviors and Raman and FTIR spectra were altered. Our results clarified the mechanism of surface charge modification by AsP and provided a rational use of AsP as a charged lipid to modify LNP surface properties in targeted drug delivery systems. Furthermore, AsP–PC composites were used as phospholipid-based biological membranes to prepare paclitaxel-loaded LNPs, which had stable surface negative charge, better tumor targeting and tumor inhibitory effects. 相似文献
84.
在碱性介质中,Mn(Ⅱ)对催化KIO4氧化镁试剂Ⅰ(对硝基苯偶氮间苯二酚)的褪色反应有显著作用。据此建立了测定痕量Mn(Ⅱ)的流动注射停流-催化光度法。优化了流动注射条件,Mn(Ⅱ)在2~10μg/L,10~160μg/L,160~1000μg/L范围内符合比尔定律,采样频率6样/h,检出限0.12μg/L,相对标准偏差(RSD)4.9%(n=6)。用于环境水样中Mn(Ⅱ)的检测,回收率为95.5%~102%。 相似文献
85.
86.
ZHANG Shun-Li 《理论物理通讯》2006,45(6):969-978
The generalized conditional symmetry is developed to study the variable
separation for equations of type uxt=A(u,ux)uxx+B(u,ux). Complete classification of those equations which admit derivative-dependent functional separable solutions is obtained and some of their
exact separable solutions are constructed. 相似文献
87.
As a key factor leading to the pressure-dependent R1-line-shift reversal and R1-state lifetime, at 10 K, the pressure-dependent variation of mixing-degree of |t22(3T1)e4T2〉
and |t232
E〉base-wavefunctions in the wavefunction of R1 state of
LLGG:Cr3+ has been calculated and analyzed. From this, the physical origin of the pressure-dependent R1-line-shift reversal has been revealed. Furthermore, by using
the pressure-dependent values of the
sum of all square mixing-coefficients
of |t22(3T1)e4T2〉in the wavefunction of R1 state, the lifetimes of R1 state
of LLGG:Cr3+ at various pressures have been calculated, which
are in good agreement with observed results. The quantum anticrossing
effect between
t232E and t22(3T1)e4T2
levels due to both spin-orbital interaction and electron-phonon interaction is remarkable, which is related to the admixture of
|t22(3T1)e4T2〉and |t232
E〉as well as the low-high crystal-field transition. 相似文献
88.
Yang Ye Xiang Qi Bing Xu Ying Lin Huan Xiang Liang Zou Xiang-Yang Ye Tian Xie 《Chemical science》2022,13(23):6959
Herein, we present a facile and efficient allylation method via Ni-catalyzed cross-electrophile coupling of readily available allylic acetates with a variety of substituted alkenyl bromides using zinc as the terminal reductant. This Ni-catalyzed modular approach displays excellent functional group tolerance and a broad substrate scope, which the creation of a series of 1,4-dienes including several structurally complex natural products and pharmaceutical motifs. Moreover, the coupling strategy has the potential to realize enantiomeric control. The practicality of this transformation is demonstrated through the potent modification of the naturally antitumor active molecule β-elemene.Herein, we present a facile and efficient allylation method via Ni-catalyzed cross-electrophile coupling of readily available allylic acetates with a variety of substituted alkenyl bromides using zinc as the terminal reductant. 相似文献
89.
运用第一性原理计算方法研究了过渡族金属TM(TM=Ru、Rh、Pd)掺杂GaSb的电子结构和光学性质,结果表明:TM掺杂GaSb主要以TM替代Ga(TM @Ga)缺陷存在,并可增强GaSb半导体材料对红外光区光子的响应,使体系光学吸收谱的吸收边红移;TM@Ga所引入的杂质能级分布于零点费米能级附近,这极大地增强了体系的介电性能,促进了电子-空穴对的产生和迁移,因而提升了掺杂体系的光电转换效率;Ru 掺杂对GaSb光学性质的改善最为明显,当掺杂浓度为6.25%(原子数分数)且均匀掺杂时,Ru掺杂GaSb体系对红外光区光子的吸收幅度最大,有效提升了GaSb光电转换效率和光催化活性。 相似文献
90.
以处理后的脱硫石膏为原料,在H2SO4-H2O体系中以Cu(NO3)2为晶形控制剂采用水热法制备脱硫石膏晶须,探讨了Cu(NO3)2对脱硫石膏晶须生长的影响机理。结果表明:Cu(NO3)2对脱硫石膏有明显促溶作用,其中Cu2+可减小溶液中各离子的活度系数,使溶液中的Ca2+浓度增大。NO-3通过静电作用在Ca2+周围聚集并对SO2-4产生屏蔽作用,导致脱硫石膏继续溶解并使Ca2+和SO2-4的浓度处于相对稳定状态,有利于半水脱硫石膏晶体的形核与生长。此外,Cu2+还可在晶须的生长过程中选择性吸附在晶须表面,生成CuSO4,促进了脱硫石膏的结晶生长,最终在Cu(NO3)2用量为2.0%(质量分数)时制备的脱硫石膏晶须长径比约为73。 相似文献