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162.
氢氧化铝镁正电溶胶制备及性能研究 总被引:27,自引:3,他引:27
氢氧化铝镁正电溶胶制备及性能研究侯万国,张春光,孙德军,梁晓丽,王果庭(山东大学胶体与界面化学研究所,济南,250100)关键词混合金属氢氧化物,溶胶,超细颗粒混合金属氢氧化物的合成、组成及结构等已得到广泛研究[1,2].我们也曾用插入法合成了混合金... 相似文献
163.
荧光猝灭法测定人发中微量锰 总被引:3,自引:0,他引:3
张根成 《理化检验(化学分册)》2004,40(12):708-709
异丙肾上腺素在pH9.91的伯瑞坦 罗比森缓冲溶液中被MnO-4氧化,导致其荧光强度显著减弱。最大激发及发射波长为278nm和616nm,MnO-4浓度在0.01~0.64mg·L-1范围内,荧光强度与浓度呈良好线性关系。将其用于人发中微量锰的测定,得到满意的结果。 相似文献
164.
棒状钡铁氧体的反相微乳法制备 总被引:5,自引:0,他引:5
A rodlike barium ferrite precursor with an average size of 0.72~19.6 μm and aspect ratio of 2.6~8.3 has been successfully prepared in an inverse microemulsion consisting of isooctane, cetanyl trimethyl ammonium bromide (CTAB), n-C4H9OH and water with ammonia and ammonium oxalate as precipitants. On sintering at 780(C, the rodlike precursor particles could be transformed into rodlike particles of barium ferrite(BaFe12O19) with the average size and aspect ratio of 0.69~18.2 μm and 2.3~5.8, respectively. The effect of volume ratio of aqueous phase to oleic phase, the starting concentrations of metal ions and the starting concentration ratios of metal ions to precipitants were investigated. 相似文献
165.
LiZHANG NaLI FengLinZHAO KeAnLI 《中国化学快报》2004,15(6):671-674
The interaction between heparin and neutral red was investigated by molecular spectroscopic methods. The change of all spectra suggested that positively charged neutral red had interacted with negatively charged heparin. The study of influence factors indicated that electrostatic force and hydrophobic bond might be involved in the interaction. The total binding number per disaccharide unit and intrinsic binding constant were obtained using Scatchard model. 相似文献
166.
Xin Ying ZHANG Xue Sen FAN Hong Ying NIU Jian Ji WANGSchool of Chemical Environmental Sciences Henan Normal University Key Laboratory ofEnvironmental Science Engineering of Henan Education Department Xinxiang 《中国化学快报》2003,(10)
a, a'-Bis(substituted benzylidene)cycloalkanones were efficiently prepared from cycloalkanones and benzaldehydes in [bmim][BF4] by using iron(III) chloride hexahydrate as a catalyst. It is shown that [bmim][BF4] and iron(III) chloride hexahydrate can be quantitatively recovered and be reused effectively for many times. Compared with the known methods, this novel process has the advantage of being an envkonmentally benign process together with good yields and mild reaction conditions. 相似文献
167.
168.
ZHANG Wei-wei CHEN Yu-chun LUO Zhao-feng WANG Ju-ying MA De-yi 《高等学校化学研究》2007,23(4):404-407
In this study, surface plasmon resonance (SPR) for monitoring 17β-eatradiol (E2) was developed. The small molecule E2 was immobilized on a CM5 sensor chip for an indirect competitive immunoassay to detect E2. The SPR response bahed on the antigen-antibody reaction was measured by injecting the sample solution into the flow system. The limitation of detection was 0.445 μg/L. The developed SPE-SPR system was applied to analyze the seawater samples. Recovery of E2 was 91.6%-93. 1%. Relative standard deviations(RSD) for the E2 assay were between 10.9%-15.1% (n = 3). The range of determination of E2 samples from the sewage in the coastal marine environ-ment was between ND(lower than detection limit) and ca. 11.78 ng/L. 相似文献
169.
An alternative method for anomeric deacetylation of fully acetylated carbohydrates has been developed using imidazole in methanol. 相似文献
170.