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861.
862.
863.
Three new hetero‐bischelated rhodium (III) complexes of cis‐[Rh(PA)(L)Cl2]Cl (where PA = phenylpyridin‐2‐ylmethylene‐amine; L = 2,2′‐bipyridine, 2,2′‐dipyridylamine and 1,10‐phenanthroline) have been successfully prepared and characterized. Each complex shows high intensity bands in the UV region, and these are assigned to spin‐allowed π‐π* transitions. The medium‐intensity absorption band profile in the lower energy region can be explained by convolution of spin‐allowed CT and d‐d* transitions. The emission spectra at low temperature (77 K) of these complexes in EtOH/MeOH (4:1 v/v) are virtually identical. They all exhibit a broad, symmetric, and structureless red emission with a microsecond lifetime and hence are assigned as the d‐d* phosphorescence. 相似文献
864.
A modified poly(ethylene glycol) (PEG) has been developed as the soluble polymeric supports for liquid phase synthesis of novel thiourea derivatives.In each step of the sequence,the PEG-bound products were precipitated in cold Et2O and the unreacted materials and by-products were removed by simple filtration.The progress of reaction,purity of the isolation and the structure of the PEG-bound products were easily monitored by TLC,IR and ^1H NMR spectra.Representative thiourea derivatives were obtained in moderate yields with excellent purity from this modified PEG-bound product by the cleavage with 50% TFA/H2O. 相似文献
865.
LIN Zhou-Bin HU Zu-Shu ZHANG Li-Zhen WANG Guo-Fu 《结构化学》2002,21(6):637-639
<正>The crystal of Nd0.06Y0.94Sr6Sc(BO3)6 with the dimensions up to 35 mm × 28 mm × 13 mm was grown by a top-seeded solution growth method from Li6B4O9 flux. The grown crystal was characterized by X-ray powder diffraction. The optical absorption of the crystal shows that it has a strong absorption band at 8070 A, and the absorption coefficient is 2.17cm-1 with a FWHM of 41 A, which can match with the wavelength of the diode-laser (LD) and is suitable for the LD pumping. Based on the Judd-Ofelt theory, the three parameters of line oscillator strength Ω(λ) (λ = 2, 4 and 6) of the Nd3+ion in the crystal were calculated as follows: Ω2= 1.194 × 10-20, Ω4= 4.186 × 10-20 and Ω6 = 3.351 × 10-20cm2, which are relatively larger. The results indicate that the crystal Nd0.06Y0.94Sr6Sc(BO3)6 may be a kind of high-efficient laser material for diode-pumped. 相似文献
866.
Qian Yanlong Li Guisheng Chen Weichun Li Bihua Jin Xianglin 《Transition Metal Chemistry》1990,15(6):478-482
Summary A new class of differentially ring-substituted titanocene dichlorides of the type CpCpTiCl2 has been prepared by reacting CpM (M=Li, K; Cp=RC5H4) with CpTiCl3 (Cp=MeOCH2CH2C5H4). The crystal structure of Cp(PhCEt2C5H4)TiCl2, the first example, has been determined by x-ray diffraction and refined to a final R factor of 0.0532 for 2304 reflections. The crystal belongs to the monoclinic space group C
2h
5
–P21/c with unit cell parameters:a 10.205(6),b 13.003(5),c 17.591(9) Å, 101.91(4)°, V=2284 Å3, Z=4 and Dc=1.32 g/cm–3. Replacement of one neomenthyl in bis(neomenthyl-cyclopentadienyl)titanium dichloride by one MeOCH2CH2 — raises the e.e. value from 5.8% to 11.2% in the catalytic asymmetric hydrogenation of 2-phenyl-1-butene. 相似文献
867.
Structural Features of a Polysaccharide from Centella asiatica 总被引:3,自引:0,他引:3
Xue Song WANG Jin You DUAN Ji Nian FANG* Shanghai Institute of Materia Medica Shanghai Institutes for Biological Sciences Chinese Academy of Sciences Shanghai 《中国化学快报》2004,15(2):187-190
Centella asiatica has been used as remedy for sodation, stabilization and against lepra, anabrosis1 in the oriental countries. The low-molecular-weight constituents in Centella asiatica have been investigated1. However, no polysaccharides have been reported. 1BI was the first polysaccharide isolated from C. asiatica, which had immunostimulating activity in vitro. In present study, we report the structural features of 1BI. Experimental Extraction, isolation and purification Dried C.… 相似文献
868.
LLDPE/纳米SiO_2复合材料的力学性能和光学性能研究 总被引:29,自引:0,他引:29
采用熔融共混方法制备了LLDPE 纳米SiO2 复合材料 ,并对该体系的力学性能和光学性能进行了系统研究 .结果表明 ,随着纳米SiO2 的加入 ,复合材料的弹性模量显著提高 ,冲击强度与拉伸强度呈峰形变化 ,且均在SiO2 含量为 3phr左右达到最大值 .加入少量的纳米SiO2 后 ,复合材料薄膜对长波红外线 (7~ 1 1 μm)的吸收能力较LLDPE膜有了显著提高 ,透光率略有下降但雾度提高 ,透光质量得到改善 .同时表明 ,纳米SiO2 的表面处理方法对膜的光学性能有显著影响 相似文献
869.
溶剂对固相反应法制备H7PW12O42掺杂聚苯胺的影响 总被引:6,自引:0,他引:6
利用固相反应法,分别以微量的水和乙腈作为溶剂,制备了磷钨酸(H7PW12O42)掺杂聚苯胺,并以红外光谱(FTIR),电子扫描显微镜(SEM),X射线衍射(XRD),循环伏安(cyclic voltamogram)等测试方法对聚苯胺进行了表征。结果表明,固相反应法合成的聚苯胺分子链排列有序,晶化率较好,并且表现出有较好的电化学稳定性。而以微量的乙腈作为溶剂通过固相反应法得到的磷钨酸掺杂聚苯胺在颗粒形貌、结晶性、导电率等方面均优于相同条件微量的水作为溶剂时的掺杂聚苯胺。 相似文献
870.
Xin Gen Luo Hai Sheng Chen Shuang Liang Mao Huang Wei Dong Xuan Li Jin College of Pharmacy Second Military Medical University Shanghai China Department of Pharmacy Guangzhou Military General Hospital Guangzhou China Center of New Drug Evaluation Institute of Basic Medical Sciences Second Military Medical University Shanghai China 《中国化学快报》2007,18(6):697-699
Six indole alkaloids were isolated from the stems of Ervatamia yunnanensis. Among them, yunnanensine (I) is new. The other five are known alkaloids, namely: 19,20-E-vallesamine (II), 19s-heyneanine (HI), ibogaine (IV), ibogamine (V), coronaridine (VI). The structural elucidation of the alkaloids was based on spectral means. 相似文献