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61.
Li-Xin Li 《General Relativity and Gravitation》1998,30(3):497-507
The effect of the global rotation of the universe on the formation of galaxies is investigated. It is found that the global rotation provides a natural origin for the rotation of galaxies, and the morphology of the objects formed from gravitational instability in a rotating and expanding universe depends on the amplitude of the density fluctuation, different values of the amplitude of the fluctuation lead to the formation of elliptical galaxies, spiral galaxies, and walls. The global rotation gives a natural explanation of the empirical relation between the angular momentum and mass of galaxies: J M5/3. The present angular velocity of the universe is estimated at 10-13rad yr-1. 相似文献
62.
The chiral phosphine-containing palladacycle, synthesized easily from H-MOP, showed its high catalytic activity as well as asymmetric induction ability in ring-opening reaction of oxabicyclic alkenes with arylboronic acids, providing corresponding products in high yields and high ee. 相似文献
63.
On the basis of the reactions of camphor-derived sulfur ylide with alpha-ylidene-beta-diketones, highly efficient and selective synthesis of optically active dihydrofurans has been achieved. 相似文献
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Two new ruthenium(II) polypyridyl complexes
(1) (dtmi = 3-(pyrazin-2-yl)-as-triazino[5,6-f]-5-methoxylisatin) and
(2) (dtni = 3-(pyrazin-2-yl)-as-triazino[5,6-f]-5-nitroisatin) have been synthesized and characterized by elemental analysis,
FAB-MS, ES-MS and 1H-n.m.r. The DNA-binding patterns of complexes were investigated by spectroscopic titration, viscosity measurements and thermal
denaturation. The results indicate that the complexes (1) and (2) interact with calf thymus DNA (CT-DNA) by intercalative mode. Due to the withdrawing electronic substitutent in the intercalative
ligand, ptni, the DNA-binding affinity of the complexes (2) is larger than that complex (1) does. 相似文献
66.
在RHF/6-311G水平优化得到3,4-二硒方酸(3,4-二氢硒基-3-环丁烯-1,2-二酮)3 种平面构象异构体的平衡几何构型。进一步用MP2(full)/6-311G//RHF//6-311G方法计算单点能量,发现ZZ型异构体是能量最低构象,且ZZ和ZE型能量非常接近。用优化的最稳定构象ZZ型异构体在RHF/6-311G//RHF/6-311G、RHF/6-311+ G//RHF/6-311+ G、MP2(full)/6-311+ G//RHF/6-311+ G 和B3LYP/6-311+ G//B3LYP/6-311+ G水平计算其气相酸性(ΔG°)和同键反应芳香性稳定化能(HASE)。用基团加和法(group increm ent ap-proach ) 在 RHF/6-311 + G//RHF/6-311 + G 和 B3LYP/6-311 + G//B3LYP/6-311+ G水平计算其磁化率增量(Λ)。计算结果指出标题化合物的同键反应芳香性稳定化能和磁化率增量均为负值,表明它具有芳香性,实现了标题化合物芳香性的几何、能量和磁性的判定。 相似文献
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Generalized Projective Synchronization between Two Complex Networks with Time-Varying Coupling Delay
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Generalized projective synchronization (GPS) between two complex networks with time-varying coupling delay is investigated. Based on the Lyapunov stability theory, a nonlinear controller and adaptive updated laws are designed. Feasibility of the proposed scheme is proven in theory. Moreover, two numerical examples are presented, using the energy resource system and Lü's system [Physica A 382 (2007) 672] as the nodes of the networks. GPS between two energy resource complex networks with time-varying coupling delay is achieved. This study can widen the application range of the generalized synchronization methods and will be instructive for the demand supply of energy resource in some regions of China. 相似文献