Preparation of PAA/AM/MMT Hybrid by Intercalation Polymerization

Over the last few years, Montmorillonite (MMT) was widely used as a special inorganic material for preparing Polymer/MMT nanocompsites. MMT is a clay imineral consisting of stacked silicate sheets whose thickness is about 10A. Through intercalation a large number of polymer-clay nanocomposites have been prepared such as Nylon-clay hybrid [1], PS-clay hybrid [2], Poly (methyl methacrylate) (PMMA)-clay hybrid [3], etc. In this article, the synthesis and properties of Poly (acrylic acid/acrylamide)/MMT hybrid (PAAAM/MMT) were studied. X-ray diffraction and Transmission electron microscopy were used to characterize the hybrid material. DSC has been used to study its property. Results showed that the intercalating reagents have entered the space of MMT's layers and enlarged them. At the same time, the MMT dispersed homogeneously in acrylic acid and acrylamide monomers that allow MMT to disperse in PAAAM matrix in the monolayer form.     

Estimating statistical distributions using an integral identity

We present an identity for an unbiased estimate of a general statistical distribution. The identity computes the distribution density from dividing a histogram sum over a local window by a correction factor from a mean-force integral, and the mean force can be evaluated as a configuration average. We show that the optimal window size is roughly the inverse of the local mean-force fluctuation. The new identity offers a more robust and precise estimate than a previous one by Adib and Jarzynski [J. Chem. Phys. 122, 014114 (2005)]. It also allows a straightforward generalization to an arbitrary ensemble and a joint distribution of multiple variables. Particularly we derive a mean-force enhanced version of the weighted histogram analysis method. The method can be used to improve distributions computed from molecular simulations. We illustrate the use in computing a potential energy distribution, a volume distribution in a constant-pressure ensemble, a radial distribution function, and a joint distribution of amino acid backbone dihedral angles.     

基于Cluster态和Bell态的任意三粒子态远程制备

本文提出了一个新颖的基于四粒子cluster态和Bell态制备任意三粒子远程制备方案.在发送者(Alice)对自己手中的粒子做正交完备测量,接受者(Bob)对自己手中的粒子做适当的幺正变换后,任意三粒子远程制备成功.对于Alice的两种不同的正交完备基测量的情况,分别计算了远程制备成功的概率.另外,本方案成功制备的概率在一般情况和一些特殊情况下是可以计算的.分析结果表明:在一般情况下,远程态制备可以以1/8的概率实现;但在一些特殊情况下,成功的概率可以提高到1/4、1/2,甚至1.     

3-芳基噻唑烷-4-酮-2-酰胺的合成及其抗肿瘤活性研究

合成了系列新的3-芳基噻唑烷-4-酮-2-酰胺衍生物,并测试了化合物抑制肿瘤细胞增殖活性.部分化合物对A-549和Hela肿瘤细胞有弱的细胞毒性,而对BGC-823没有抑制作用,表现出一定的选择性.其中,化合物7ad对A-549有较强的抑制活性(IC50=21.0μmol·L-1),与阳性对照顺铂的抑制活性(IC50=19.4μmol·L-1)相当.初步的构效关系表明化合物的立体结构可能对其抗肿瘤活性影响较大.     

非线性发展方程混合问题解的爆破性质

讨论了具有第三类非线性边界条件的非线性发展方程的混合问题,并在已知函数满足某些假设的条件下,利用抛物型方程的最大值原理和凸性方法,证明了该问题的解在有限时间内爆破.     

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利用自行设计的快速移动静电探针对大气压下以氩气为工质的大尺度磁分散电弧等离子体进行诊断,分析了探针电压与电流的波形,绘制探针伏安特征曲线(U-I曲线),得到了发生器轴线方向等离子体波动特性以及电子温度沿轴线的变化趋势.发现等离子体发生器中心具有回流区,得到了电弧等离子体的大致体积.     

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在EAST上通过分析剩余环电压与低杂波功率之间的关系,计算得到了低杂波电流驱动效率。采用归一化功率,即功率对等离子体电流、电子密度、等离子体大半径以及有效电荷数归一化,将所有数据绘制在同一曲线中,这样可以得到不同等离子体参数下的低杂波电流驱动效率。实验得到低杂波电流驱动效率η0=(0.5~1.3)×1019 A.m-2.W-1,在等离子体电流Ip=277kA、低杂波功率PLH=681kW条件下,实验得到长达3s的低杂波全波驱动。     

考虑需求率变化与延期支付的临时订货模型

供应商给予临时价格折扣、并针对采购商的临时订货给予优惠的延期支付条件;同时考虑到采购商的自身需求即为终端需求并对价格敏感,由于考虑需求量变化的同时考虑到时间因素,因此需求率实际上发生了改变。在这样的背景下,采购商在价格变化时刻面临两种选择:以低价购进大量货物或者放弃这个机会。本文以EOQ模型单位产品成本为参考,从成本节约最大的角度出发,分析了采购商临时订货量的确定过程,并用数例分析了参数变化对最优订货以及成本节约情况的影响。     

A 60-GHz Wideband Slot Antenna Based on Substrate Integrated Waveguide Cavity

This paper proposes a new wideband W-band substrate integrated waveguide (SIW) cavity-backed slot (CBS) antenna. The SIW cavity suppresses the backward radiation and ensures this antenna have a very low profile (only about 4% of the operating wavelength). Several techniques, such as slot resonator with semicircular end, quarter-wavelength microstrip resonator, are introduced to improve impedance matching. The studied results demonstrate that this antenna has wide operating bandwidth in 54.3–67 GHz (about 20.9% of the fractional bandwidth), unidirectional radiation pattern and good linear polarization characteristic. These properties are very suitable for RF front-end system-on-package (SoP) design in millimeter wave wireless communication systems. This work was supported by the National Nature Science Foundation of China (60501011, 90505001), the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20060614005) and the Creative Research Team Program of UESTC.     

用宇宙线大气簇射Ne-Nμ关系研究“膝”区原初成分

用梁王山宇宙线观测站获得的宇宙线大气簇射μ子数据, 与假设原初分别为质子、氦核、中等核(Z=15)和铁核的Monte-Carlo模拟结果进行比较, 结果显示宇宙线膝区原初成分无明显变化且以轻核为主.