基于实测地应力深埋巷道塑性区定量分析

深埋巷道大变形、强流变的破坏特征源于其高地应力的作用,准确分析已开掘巷道塑性区分布对巷道围岩变形影响、开掘方案选择及后续类似条件巷道布置意义深远。在围岩力学参数测试、地应力场测试的基础上,采用弹塑性理论、M-C准则、修正的“当量半径”理论简化计算了直墙半圆拱形断面布置下深埋巷道的围岩塑性区大小,分析了巷道围岩塑性区受采动应力、侧压系数单独及耦合作用影响规律。在侧压系数为0.5、垂直压力为35MPa时底板塑性区最大,其值为2.65m,建议加强巷道底板的支护与维护,并给出了塑性区控制方案。研究结果可为后续类似条件下巷道开掘方案优选、支护设计及围岩稳定性判定提供一定的借鉴。     

具有光引发活性腰果酚衍生物的合成及其UV固化

以腰果酚与4-溴甲基二苯甲酮为原料,合成了具有光引发活性的腰果酚衍生物,收率86%。 该衍生物的光引发活性优于普通的二苯甲酮。 在不加其它光引发剂的情况下,UV光照30 s该液体衍生物即可固化。 该衍生物与腰果酚不同比例的混合物,也可进行UV 固化,腰果酚含量越高,所需固化时间越长。膜的硬度为3H-5H,且具有较好的耐溶剂与耐酸碱性能,可望用于防腐漆中。     

A Scheme of Controlled Quantum State Swapping

A scheme for controlled quantum state swapping is presented using maximally entangled five-qubit state, i.e., Alice wants to transmit an entangled state of particle a to Bob and at the same time Bob wants to transmit an entangled state of particle b to Alice via the control of the supervisor Charlie. The operations used in this swapping process including C-not operation and a series of single-qubit measurements performed by Alice, Bob, and Charlie.     

Ultra-narrow bandwidth resonant reflection grating filters using the second diffracted orders

In this paper, we design resonant reflection grating filters employing the second diffracted orders as the leaky modes, then analyze the bandwidth of the reflection peak and the electric field distributions inside the waveguide under resonance. The numeric calculation confirms that ultra-narrow resonant reflection peaks can be observed in these structures. At the same time, strong electric field enhancement appears under resonance. It provides a new approach to diversify the resonant reflection filters and may open a new way to the realization of ultra-narrow bandwidth filters.     

3-[二(羧甲基)氨甲基]-1,2-二羟基蒽醌-3-甲基胺-N,N- 二乙酸与腺嘌呤的分光光度法研究

采用分光光度法对腺嘌呤(Ade)与3-[二(羧甲基)氨甲基]-1,2-二羟基蒽醌3-甲基胺-N,N-二乙酸(AFB)反应体系进行了研究.优化了实验条件,建立了Ade的分析方法.本法测定Ade的检出限为6.54×10-5 mol/L,摩尔吸光系数(ε)为3.2×104L·cm-1·mol-1;初步探讨了反应机理.     

乙二醛在Ti/纳米TiO2-Pt修饰电极上的电催化氧化

采用溶胶-凝胶和电沉积法制备Ti基纳米TiO2-Pt(Ti/纳米TiO2-Pt)修饰电极. X射线衍射(XRD)表明纳米TiO2为锐钛矿型, 扫描电镜(SEM)显示Pt纳米粒子在纳米TiO2多孔膜的表面呈现簇分散状态, 平均粒径约25 nm. 通过循环伏安(CV)和计时电流法研究了Ti/纳米TiO2-Pt修饰电极对乙二醛直接电氧化的电催化活性, 结果表明, 修饰电极对乙二醛的直接电氧化呈现良好的催化活性, 在0.60和1.23 V(vs SCE)出现两个氧化峰, 二者电流密度分别为16 和42 mA·cm-2, 约为纯Pt电极的2倍和1.5倍, 反应过程受浓差扩散控制.     

Nanofabrication and characterization of a grating‐based condenser for uniform illumination with hard X‐rays

In the development of full‐field transmission X‐ray microscopy for basic study in science and technology, a condenser capable of providing intense illumination with high uniformity and stability on tested specimens in order to achieve high‐quality images is essential. The latest design of a square‐shaped condenser based on diffractive gratings has demonstrated promising uniformity in illumination. This paper describes in more detail the development of such a beam shaper for hard X‐rays at 10 keV with regard to its design, manufacture and optical characterization. The effect of the grating profile on the diffracted intensity has been theoretically predicted by numerical simulation using the finite‐difference time‐domain method. Based on this, the limitations of the grating‐based condenser are discussed.     

利用两个EPR态完全隐形传输四粒子W态

为了减少量子隐形传态中的测量次数和运算量,提出了一个利用两个EPR对作为量子信道,实现四粒子W纠缠态的隐形传输的方案.发送者Alice只需利用16个正交完备测量基对要传送的未知四粒子纠缠W态和两个EPR对中属于自己的粒子做一次正交完备基测量,然后将测量所产生的16种塌陷态结果通过经典信道告知接收者,接收者Bob根据这些信息,通过引入两个辅助粒子B3B4,并对手中拥有的粒子做适当的Toffoli门、C-Not门、Pauli-X门、Pauli-Z门变换,就能将16种畸变态全部恢复到发送者Alice欲传送的未知四粒子原始量子态,从而以100%的概率实现四粒子纠缠W态的隐形传输.利用量子力学波函数的叠加原理和变换算符的思想,很容易得出正交完备基测量后的16种塌陷态表达式和接收者Bob所做的由量子门组成的幺正变换的表达式.该方案中由于采用了正交完备基测量的方法,大大减少了发送者所需要做的测量计算,而且整个方案只需要一次正交完备基测量和由各种量子逻辑门组成的简单幺正变换,实现更为容易.     

Graphitic Carbon Nitride Microspheres Supportedα-FeO(OH)Hybrids for Visible Light Photodegradation of MO

Graphitic carbon nitride(g-C3N4)microspheres supported a-FeO(OH)hybrids[α-FeO(OH)/g-C3N4]were prepared by means of a self-assembly method in deionized water.By UV-visible diffiise reflectance spectroscopy,it has been confirmed thatα-FeO(OH)/g-C3N4 has a wider absorption range thanThe feature ofα-FeO(OH)/g-C3N4 can be attributed to the efficient separation of the electron-hole pairs with photoluminescence spectra.The degradation rate of methyl orange(MO)is up to 99%under the optimal conditions of 110 min,initial concentration of 30 mg/L,anα-FeO(OH)/g-C3N4 dosage of 15 mg as well as visible light.The mechanism for this photocatalytic reaction was proposed,with hydroxyl radicals being a major active catalytic species.     

局域热源对磁岛热输运的影响

研究托卡马克等离子体磁岛内的热输运行为.应用局域高斯热源对磁岛加热来模拟电子回旋共振加热.对同时存在背景热源与局域高斯热源的情况,观察局域高斯热源对径向电子温度分布及热输运产生的变化,分析局域高斯热源对温度扰动及磁岛约束能量的影响.