一种溶解氧敏感膜荧光发射效率光谱检测系统的研制

荧光猝灭法是快速测量污水、地表水以及渔业养殖水环境中溶解氧含量的先进技术之一,氧敏感膜是荧光猝灭法检测技术的核心,高荧光发射效率的氧敏感膜具有灵敏度高、特异性强、信噪比高的优点,检测结果更为准确。高效率是优选氧敏感膜的依据,也是溶解氧检测元器件、检测电路和检测光路优化设计的关键。现有溶解氧荧光检测装置中未有对氧敏感膜进行质量评估的标准方法,基于对已有传感器探头光路和电路的研究,该研究分析了全波段的荧光发射效率,选用大功率氙灯作为激发光源,基于连续单波长逐级扫描进行单色分光,构建了氧敏感膜的激发光-荧光光谱扫描装置,然后通过扫描测定氧敏感膜的激发光光谱和荧光光谱,提出并建立了荧光发射效率计算方法,提出的方法能客观地评估荧光发射能力,准确寻找最佳激发波长。为验证该方法的可行性,对来自国内外的多个氧敏感膜样品进行了实验测定,测试结果表明：单张氧敏感膜荧光发射效率随波长变化,呈多峰分布,同一型号的样品荧光效率曲线相似,但荧光发射效率差异较大,同一激发波长下荧光发射效率最大者较最小者高出14.5%,三张氧敏感膜的最大峰值波长均不同,分别为：401,543和435 nm,但发射峰值波长均为650 nm;不同型号的氧敏感膜相比较,最大荧光发射效率可相差1～2个数量级;实测传感器中使用的激发波长,其所选用的激发波长并非最大发射峰值波长,其荧光发射效率仅为最大荧光发射效率的1/2,表明传感器光源可以进一步优化选型。综上所述,本文建立了一种溶解氧敏感膜荧光发射效率检测系统,提出了以荧光发射效率评估氧敏感膜的方法,并开展了相关实验测定。本文工作可望用于新型氧敏感膜材料、工艺的研究及传感器优化设计与制造。     

三维液晶方程一个与水平速度相关的改进正则性准则

根据速度的水平分量$u_h$的垂直导数,本文研究了3维液晶方程的整体正则性,具体地,当速度的水平分量$u_h$的垂直导数满足$\partial_3u_h\in L^p(0,T; R^3), \frac{2}{p}+\frac{3}{q}\le \frac{3}{2}$, $2\le p\le \infty$,则局部强解$(u,d)$可以光滑的延拓出$t=T$.     

带Ivlev反应项的捕食模型的全局分歧

在Dirichlet边界条件下研究一类带Ivlev反应项的捕食模型.利用谱分析和分歧理论的方法,证明了发自半平凡解的局部分歧正解的存在性,同时运用线性特征值扰动理论给出局部分歧解的稳定性.最后将局部分歧延拓为全局分歧,从而得到正解存在的充分条件.     

Geometry and optics calibration of WFCTA prototype telescopes using star light

The Large High Altitude Air Shower Observatory (LHAASO) project is proposed to study high energy gamma ray astronomy (40 GeV--1 PeV) and cosmic ray physics (20 TeV--1 EeV). The wide field of view Cherenkov telescope array, as a component of the LHAASO project, will be used to study the energy spectrum and composition of cosmic rays by measuring the total Cherenkov light generated by air showers and the shower maximum depth. Two prototype telescopes have been in operation since 2008. The pointing accuracy of each telescope is crucial for the direction reconstruction of the primary particles. On the other hand, the primary energy reconstruction relies on the shape of the Cherenkov image on the camera and the unrecorded photons due to the imperfect connections between the photomultiplier tubes. UV bright stars are used as point-like objects to calibrate the pointing and to study the optical properties of the camera, the spot size and the fractions of unrecorded photons in the insensitive areas of the camera.     

关于成本分摊的合作博弈方法

本文首先提出了成本分摊的合作博弈模型,并讨论了合作博弈的Shapley值方法在博弈满足凸性条件下的应用,最后提出了基于可分离及不可分离成本的分配方法及其适用的范围,并进行了算例分析.     

一种新型非肽类血管紧张素Ⅱ受体拮抗剂Candesartan Cilexetil的1H和13C NMR归属

利用超导核磁共振波谱仪，测定了Candesartan Cilexetil的¹H、¹H-¹H COSY、DEPT、HMQC、HMBC等谱，对该化合物的所有化学位移数据进行了归属.     

考虑地基耦合效应含裂纹中厚矩形板的非线性振动分析

基于Reissner板理论和Hamilton变分原理,建立了双参数地基上具有表面横向贯穿裂纹的中厚矩形板的非线性运动控制方程.在周边自由的条件下,提出了一组满足问题全部边界条件和裂纹处连续条件的试函数.且利用Galerkin法和谐波平衡法对方程进行求解,分析了考虑地基耦合效应的中厚矩形裂纹板的非线性振动特性.数值计算中,讨论了不同裂纹位置、裂纹深度、板的结构参数和地基物理参数对弹性地基上具裂纹的四边自由中厚矩形板的非线性幅频响应的影响.     

4,4'-联吡啶桥联的三个铜有机膦酸配合物的合成、结构及磁性

在水热条件下,以N-氧化-2-吡啶膦酸(H₂L)为主配体,4,4’-联吡啶(bpy)为桥联配体,合成了3个铜有机膦酸配合物：{[Cu(L)(bpy)_0.5(H₂O)]·2H₂O}_n(1),{[Cu(HL)₂(bpy)]·4H₂O}_n(2)和{[Cu₂(L)₂(bpy)]·3H₂O}_n(3)。配合物1中,相邻的铜离子由2个膦酸根连成二聚体,二聚体之间通过bpy桥联成一维链。配合物2中,单核[Cu(HL)₂]被bpy连接成一维链。配合物3中,四聚体[Cu₂(L)₂]₂被bpy连接成“砖块状”结构的二维层。磁性研究表明,配合物1和3中铜离子之间存在反铁磁性耦合。     

Simultaneous monitoring of quantum dots and their assembly and disassembly with PreScission protease using capillary electrophoresis with fluorescence detection

A novel assay was developed for the simultaneous monitoring of quantum dots and their assembly and disassembly with PreScission protease using capillary electrophoresis with fluorescence detection. Quantum dots and PreScission protease were injected into a capillary sequentially, then mixed and assembled via a thioether bond upon coupling to glutathione S‐transferase tag inside the capillary. The in‐capillary assembly was influenced by the molar ratio and the time interval of injection. Furthermore, the simultaneous monitoring of quantum dots and their assembly with PreScission protease and glutathione induced disassembly was achieved by adjusting the sampling sequence and the time interval of injection. More importantly, the in‐capillary assay could be also applied to the online detection of glutathione.